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Luminescence and Scintillation of [Nb 2 O 2 F 9 ] 3– -Dimer-Containing Oxide–Fluorides: Cs 10 (Nb 2 O 2 F 9 ) 3 F, Cs 9.4 K 0.6 (Nb 2 O 2 F 9 ) 3 F, and Cs 10 (Nb 2 O 2 F 9 ) 3 Cl
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We report how the binary HNO 3 (H 2 O) interaction is modified upon complexation with a nearby Cs + ion. Isomer-selective IR photodissociation spectra of the D 2 -tagged, ternary Cs + (HNO 3 )H 2 O cation confirms that two structural isomers are generated in the cryogenic ion source. In one of these, both HNO 3 and H 2 O are directly coordinated to the ion, while in the other, the water molecule is attached to the OH group of the acid, which in turn binds to Cs + with its –NO 2 group. The acidic OH stretchingmore »