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The temperature and capacity of individual cells affect the current distribution in a battery pack. Non uniform current distribution among parallel-connected cells can lead to capacity imbalance and premature aging. This paper develops models that calculate the current in parallel-connected cells and predict their capacity fade. The model is validated experimentally for a nonuniform battery pack at different temperatures. The paper also proposes and validates the hypothesis that temperature control can reduce capacity mismatch in parallel-connected cells. Three Lithium Iron Phosphate cells, two cells at higher initial capacity than the third cell, are connected in parallel. The pack is cycled for 1500 Hybrid Electric Vehicles cycles with the higher capacity cells regulated at 40C and the lower capacity cell at 20C. As predicted by the model, the higher capacity and temperature cells age faster, reducing the capacity mismatch by 48% over the 1500 cycles. A case study shows that cooling of low capacity cells can reduce capacity mismatch and extend pack life.
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Estimation of Parameter Probability Distributions for Lithium-Ion Battery String Models Using Bayesian Methods
Abstract This paper addresses the parameter estimation problem for lithium-ion battery pack models comprising cells in series. This valuable information can be exploited in fault diagnostics to estimate the number of cells that are exhibiting abnormal behaviour, e.g. large resistances or small capacities. In particular, we use a Bayesian approach to estimate the parameters of a two-cell arrangement modelled using equivalent circuits. Although our modeling framework has been extensively reported in the literature, its structural identifiability properties have not been reported yet to the best of the authors’ knowledge. Moreover, most contributions in the literature tackle the estimation problem through point-wise estimates assuming Gaussian noise using e.g. least-squares methods (maximum likelihood estimation) or Kalman filters (maximum a posteriori estimation). In contrast, we apply methods that are suitable for nonlinear and non-Gaussian estimation problems and estimate the full posterior probability distribution of the parameters. We study how the model structure, available measurements and prior knowledge of the model parameters impact the underlying posterior probability distribution that is recovered for the parameters. For two cells in series, a bimodal distribution is obtained whose modes are centered around the real values of the parameters for each cell. Therefore, bounds on the model parameters for a battery pack can be derived.
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- Award ID(s):
- 1847177
- PAR ID:
- 10334910
- Date Published:
- Journal Name:
- ASME 2020 Dynamic Systems and Control Conference
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Conference Paper:
- https://doi.org/10.1115/DSCC2020-3218
