skip to main content

Title: Assessing the sequestration time scales of some ocean-based carbon dioxide reduction strategies
Abstract Ocean-based carbon dioxide (CO 2 ) removal (CDR) strategies are an important part of the portfolio of approaches needed to achieve negative greenhouse gas emissions. Many ocean-based CDR strategies rely on injecting CO 2 or organic carbon (that will eventually become CO 2 ) into the ocean interior, or enhancing the ocean’s biological pump. These approaches will not result in permanent sequestration, because ocean currents will eventually return the injected CO 2 back to the surface, where it will be brought into equilibrium with the atmosphere. Here, a model of steady state global ocean circulation and mixing is used to assess the time scales over which CO 2 injected in the ocean interior remains sequestered from the atmosphere. There will be a distribution of sequestration times for any single discharge location due to the infinite number of pathways connecting a location at depth with the sea surface. The resulting probability distribution is highly skewed with a long tail of very long transit times, making mean sequestration times much longer than typical time scales. Deeper discharge locations will sequester purposefully injected CO 2 much longer than shallower ones and median sequestration times are typically decades to centuries, and approach 1000 more » years in the deep North Pacific. Large differences in sequestration times occur both within and between the major ocean basins, with the Pacific and Indian basins generally having longer sequestration times than the Atlantic and Southern Oceans. Assessments made over a 50 year time horizon illustrates that most of the injected carbon will be retained for injection depths greater than 1000 m, with several geographic exceptions such as the Western North Atlantic. Ocean CDR strategies that increase upper ocean ecosystem productivity with the goal of exporting more carbon to depth will have mainly a short-term influence on atmospheric CO 2 levels because ∼70% will be transported back to the surface ocean within 50 years. The results presented here will help plan appropriate ocean CDR strategies that can help limit climate damage caused by fossil fuel CO 2 emissions. « less
Authors:
; ; ;
Award ID(s):
1948955
Publication Date:
NSF-PAR ID:
10336002
Journal Name:
Environmental Research Letters
Volume:
16
Issue:
10
Page Range or eLocation-ID:
104003
ISSN:
1748-9326
Sponsoring Org:
National Science Foundation
More Like this
  1. The Antarctic Circumpolar Current (ACC) is the world’s strongest zonal current system that connects all three major ocean basins of the global ocean and therefore integrates and responds to global climate variability. Its flow is largely driven by strong westerly winds and constricted to its narrowest extent in the Drake Passage. Transport of fresh and cold surface and intermediate water masses through the Drake Passage (cold-water route) strongly affects the Atlantic Meridional Overturning Circulation together with the inflow of Indian Ocean water masses (warm-water route). Both oceanographic corridors are critical for the South Atlantic contribution to Meridional Overturning Circulation changes. In contrast to the Atlantic and Indian sectors of the ACC, and with the exception of drill cores from the Antarctic continental margin and off New Zealand, the Pacific sector of the ACC lacks information on its Cenozoic paleoceanography from deep-sea drilling records. To advance our knowledge and understanding of Miocene to Holocene atmosphere-ocean-cryosphere dynamics in the Pacific and their implications for regional and global climate and atmospheric CO2, International Ocean Discovery Program (IODP) Expedition 383 recovered sedimentary sequences at (1) three sites located in the central South Pacific (U1539, U1540, and U1541), (2) two sites at the Chile marginmore »(U1542 and U1544), and (3) one site from the pelagic eastern South Pacific (U1543) close to the entrance to the Drake Passage. Because of persistently stormy conditions and the resulting bad weather avoidance, we were not successful in recovering the originally planned Proposed Site CSP-3A in the central South Pacific in the Polar Frontal Zone. The drilled sediments at Sites U1541 and U1543 reach back to the late Miocene, and those at Site U1540 reach back to the early Pliocene. High sedimentary rate Pleistocene sedimentary sequences were drilled both in the central South Pacific (Site U1539) and along the Chile margin. Taken together, the sites represent a depth transect from ~1100 m at the Chile margin site (U1542) to ~4070 m in the central South Pacific (Site U1539) and allow investigation of changes in the vertical structure of the ACC, a key issue for understanding the role of the Southern Ocean in the global carbon cycle. The sites are located at latitudes and water depths where sediments will allow the application of a wide range of siliciclastic-, carbonate-, and opal-based proxies to address our objectives of reconstructing with unprecedented stratigraphic detail surface to deep-ocean variations and their relation to atmosphere and cryosphere changes through stadial to interstadial, glacial to interglacial, and warmer than present time intervals.« less
  2. The Antarctic Circumpolar Current (ACC), the world’s strongest zonal current system, connects all three major ocean basins of the global ocean and therefore integrates and responds to global climate variability. Its flow is largely driven by strong westerly winds and is constricted to its narrowest extent in the Drake Passage. Fresh and cold Pacific surface and intermediate water flowing through the Drake Passage (cold-water route) and warm Indian Ocean water masses flowing through the Agulhas region (warm-water route) are critical for the South Atlantic contribution to Meridional Overturning Circulation changes. Furthermore, physical and biological processes associated with the ACC affect the strength of the ocean carbon pump and therefore are critical to feedbacks linking atmospheric CO2 concentrations, ocean circulation, and climate/cryosphere on a global scale. In contrast to the Atlantic and Indian sectors of the ACC, and with the exception of drill cores from the Antarctic continental margin and off New Zealand, there are no deep-sea drilling paleoceanographic records from the Pacific sector of the ACC. To advance our understanding of Miocene to Holocene atmosphere-ocean-cryosphere dynamics in the Pacific and their implications for regional and global climate and atmospheric CO2, International Ocean Discovery Program Expedition 383 recovered sedimentary sequences atmore »(1) three sites in the central South Pacific (CSP) (U1539, U1540, and U1541), (2) two sites at the Chilean margin (U1542 and U1544), and (3) one site from the pelagic eastern South Pacific (U1543) close to the entrance to the Drake Passage. Because of persistently stormy conditions and the resulting bad weather avoidance, we were not successful in recovering the originally planned Proposed Site CSP-3A in the Polar Frontal Zone of the CSP. The drilled sediments at Sites U1541 and U1543 reach back to the late Miocene, and those at Site U1540 reach back to the early Pliocene. High sedimentation rate sequences reaching back to the early Pleistocene (Site U1539) and the late Pleistocene (Sites U1542 and U1544) were recovered in both the CSP and at the Chilean margin. Taken together, the sites represent a depth transect from ~1100 m at Chilean margin Site U1542 to ~4070 m at CSP Site U1539 and allow investigation of changes in the vertical structure of the ACC, a key issue for understanding the role of the Southern Ocean in the global carbon cycle. The sites are located at latitudes and water depths where sediments will allow the application of a wide range of siliciclastic-, carbonate-, and opal-based proxies to address our objectives of reconstructing, with unprecedented stratigraphic detail, surface to deep-ocean variations and their relation to atmosphere and cryosphere changes.« less
  3. Abstract

    We examine the distribution of aerosol optical depth (AOD) across 27,707 northern hemisphere (NH) midlatitude cyclones for 2005–2018 using retrievals from the Moderate Resolution Spectroradiometer (MODIS) sensor on the Aqua satellite. Cyclone‐centered composites show AOD enhancements of 20%–45% relative to background conditions in the warm conveyor belt (WCB) airstream. Fine mode AOD accounts for 68% of this enhancement annually. Relative to background conditions, coarse mode AOD is enhanced by more than a factor of two near the center of the composite cyclone, co‐located with high surface wind speeds. Within the WCB, MODIS AOD maximizes in spring, with a secondary maximum in summer. Cyclone‐centered composites of AOD from the Modern Era Retrospective analysis for Research and Applications, version 2 Global Modeling Initiative (M2GMI) simulation reproduce the magnitude and seasonality of the MODIS AOD composites and enhancements. M2GMI simulations show that the AOD enhancement in the WCB is dominated by sulfate (37%) and organic aerosol (25%), with dust and sea salt each accounting for 15%. MODIS and M2GMI AOD are 60% larger in North Pacific WCBs compared to North Atlantic WCBs and show a strong relationship with anthropogenic pollution. We infer that NH midlatitude cyclones account for 355 Tg yr−1of sea salt aerosolmore »emissions annually, or 60% of the 30–80°N total. We find that deposition within WCBs is responsible for up to 35% of the total aerosol deposition over the NH ocean basins. Furthermore, the cloudy environment of WCBs leads to efficient secondary sulfate production.

    « less
  4. Abstract

    Atmospheric hydroperoxides are a significant component of the atmosphere's oxidizing capacity. Two of the most abundant hydroperoxides, hydrogen peroxide (H2O2) and methyl hydroperoxide (MHP, CH3OOH), were measured in the remote atmosphere using chemical ionization mass spectrometry aboard the NASA DC‐8 aircraft during the Atmospheric Tomography Mission. These measurements present a seasonal investigation into the global distribution of these two hydroperoxides, with near pole‐to‐pole coverage across the Pacific and Atlantic Ocean basins and from the marine boundary layer to the upper troposphere and lower stratosphere. H2O2mixing ratios are highest between 2 and 4 km altitude in the equatorial region of the Atlantic Ocean basin, where they reach global maximums of 3.6–6.5 ppbv depending on season. MHP mixing ratios reach global maximums of 4.3–8.6 ppbv and are highest between 1 and 3 km altitude, but peak in different regions depending on season. A major factor contributing to the global H2O2distribution is the influence of biomass burning emissions in the Atlantic Ocean basin, encountered in all four seasons, where the highest H2O2mixing ratios were found to correlate strongly with increased mixing ratios of the biomass burning tracers hydrogen cyanide (HCN) and carbon monoxide (CO). This biomass burning enhanced H2O2by a factor of 1.3–2.2, onmore »average, in the Atlantic compared with the Pacific Ocean basin.

    « less
  5. Abstract

    Lower atmospheric CO2concentrations during the Last Glacial Maximum (LGM; 23.0–18.0 ka) have been attributed to the sequestration of respired carbon in the ocean interior, yet the mechanism responsible for the release of this CO2during the deglaciation remains uncertain. Here we present calculations of vertical differences in oxygen and carbon isotopes (∆δ18O and ∆δ13C, respectively) from a depth transect of southwest Pacific Ocean sediment cores to reconstruct changes in water mass structure and CO2storage. During the Last Glacial Maximum, ∆δ18O indicates a more homogenous deep Pacific below 1,100 m, whereas regional ∆δ13C elucidates greater sequestration of CO2in two distinct layers: enhanced CO2storage at intermediate depths between ~940 and 1,400 m, and significantly more CO2at 1,600 m and below. This highlights an isolated glacial intermediate water mass and places the main geochemical divide at least 500 m shallower than the Holocene. During the initial stages of the deglaciation in Heinrich Stadial 1 (17.5–14.5 ka), restructuring of the upper ~2,000 m of the southwest Pacific water column coincided with sea‐ice retreat and rapid CO2release from intermediate depths, while CO2release from the deep ocean was earlier and more gradual than waters above it. These changes suggest that sea‐ice retreat and shifts in Southern Ocean frontal locations contributed to rapid CO2ventilation frommore »the Southern Ocean's intermediate depths and gradual ventilation from the deep ocean during the early deglaciation.

    « less