Coordination of the Copper Centers in Particulate Methane Monooxygenase: Comparison between Methanotrophs and Characterization of the Cu C Site by EPR and ENDOR Spectroscopies
- Award ID(s):
- 1908587
- PAR ID:
- 10338438
- Date Published:
- Journal Name:
- Journal of the American Chemical Society
- Volume:
- 143
- Issue:
- 37
- ISSN:
- 0002-7863
- Page Range / eLocation ID:
- 15358 to 15368
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
KBiNb 2 O 7 was prepared from RbBiNb 2 O 7 by a sequence of cation exchange reactions which first convert RbBiNb 2 O 7 to LiBiNb 2 O 7 , before KBiNb 2 O 7 is formed by a further K-for-Li cation exchange. A combination of neutron, synchrotron X-ray and electron diffraction data reveal that KBiNb 2 O 7 adopts a polar, layered, perovskite structure (space group A 11 m ) in which the BiNb 2 O 7 layers are stacked in a (0, ½, z ) arrangement, with the K + cations located in half of the available 10-coordinate interlayer cation sites. The inversion symmetry of the phase is broken by a large displacement of the Bi 3+ cations parallel to the y -axis. HAADF-STEM images reveal that KBiNb 2 O 7 exhibits frequent stacking faults which convert the (0, ½, z ) layer stacking to (½, 0, z ) stacking and vice versa , essentially switching the x - and y -axes of the material. By fitting the complex diffraction peak shape of the SXRD data collected from KBiNb 2 O 7 it is estimated that each layer has approximately a 9% chance of being defective – a high level which is attributed to the lack of cooperative NbO 6 tilting in the material, which limits the lattice strain associated with each fault.more » « less