- Award ID(s):
- 1954922
- NSF-PAR ID:
- 10341245
- Date Published:
- Journal Name:
- Cell Reports Physical Science
- Volume:
- 3
- Issue:
- 1
- ISSN:
- 2666-3864
- Page Range / eLocation ID:
- 100701
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Abstract A new method to synthesize complexes of the type [(CNC)RuII(NN)L]n+has been introduced, where CNC is a tridentate pincer composed of two (benz)imidazole derived NHC rings and a pyridyl ring, NN is a bidentate aromatic diimine ligand, L=bromide or acetonitrile, and n=1 or 2. Following this new method a series of six new complexes has been synthesized and characterized by spectroscopic, analytic, crystallographic, and computational methods. Their electrochemical properties have been studied
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