Thermal Conductivity of β-Phase Ga 2 O 3 and (Al x Ga 1– x ) 2 O 3 Heteroepitaxial Thin Films
- Award ID(s):
- 1804840
- PAR ID:
- 10344731
- Author(s) / Creator(s):
- ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; more »
- Date Published:
- Journal Name:
- ACS Applied Materials & Interfaces
- Volume:
- 13
- Issue:
- 32
- ISSN:
- 1944-8244
- Page Range / eLocation ID:
- 38477 to 38490
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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While a number of O-H and O-D vibrational lines have been observed for hydrogen and deuterium in β-Ga 2 O 3 , it has been commonly reported that there is no absorption with a component of the polarization E parallel to the [010], or b, axis. This experimental result has led to O-H defect structures that involve shifted configurations of a vacancy at the tetrahedrally coordinated Ga(1) site [V Ga(1) ] and have ruled out structures that involve a vacancy at the octahedrally coordinated Ga(2) site [V Ga(2) ], because these structures are predicted to show absorption for E//[010]. In this Letter, weak O-D lines at 2475 and 2493 cm −1 with a component of their polarization with E//[010] are reported for β-Ga 2 O 3 that had been annealed in a D 2 ambient. O-D defect structures involving an unshifted V Ga(2) are proposed for these centers. An estimate is made that the concentration of V Ga(2) in a Czochralski-grown sample is 2–3 orders of magnitude lower than that of V Ga(1) from the intensities of the IR absorption lines.more » « less
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