The Ocean Observatories Initiative (OOI) deployed both the In-Situ Ultraviolet Spectrophotometer (ISUS) and Submersible Underwater Nitrate Sensor (SUNA) for continuous, in-situ measurement of nitrate. At the Pioneer-New England Shelf Array (Pioneer-NES), ISUS/SUNA sensors were deployed at 7-meters depth at the Inshore (ISSM), Central (CNSM), and Offshore (OSSM) Surface Mooring locations. The SUNA sensor replaced the ISUS sensors spring 2018. The SUNA was a major improvement in technology, with significant improvements in accuracy and precision. However, it still suffers from calibration drift due to lamp fatigue and biofouling as well as spectral interference due to bromide and fluorometric CDOM. Drift is corrected by application of post-cruise calibrations to recalculate the temperature-and-salinity corrected nitrate concentration following Sakamoto (2009a) and estimating a linear drift between pre-and-post cruise deployments. Validation is performed by comparison with discrete water samples collected during deployment/recovery of the sensors. These datasets include the nitrate data from the Pioneer-NES ISSM (CP03ISSM-RID26-07-NUTNRB000.nc), CNSM (CP01CNSM-RID26-07-NUTNRB000.nc), and OSSM (CP04OSSM-RID26-07-NUTNRB000.nc) SUNA instruments spanning Spring 2018 through Fall 2022. Each dataset contains the measured nitrate, the temperature-salinity corrected nitrate, the drift-corrected nitrate, and the nitrate following validation with bottle samples.
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Reconstructing Missing and Anomalous Data Collected from High-Frequency In-Situ Sensors in Fresh Waters
In situ sensors that collect high-frequency data are used increasingly to monitor aquatic environments. These sensors are prone to technical errors, resulting in unrecorded observations and/or anomalous values that are subsequently removed and create gaps in time series data. We present a framework based on generalized additive and auto-regressive models to recover these missing data. To mimic sporadically missing (i) single observations and (ii) periods of contiguous observations, we randomly removed (i) point data and (ii) day- and week-long sequences of data from a two-year time series of nitrate concentration data collected from Arikaree River, USA, where synoptically collected water temperature, turbidity, conductance, elevation, and dissolved oxygen data were available. In 72% of cases with missing point data, predicted values were within the sensor precision interval of the original value, although predictive ability declined when sequences of missing data occurred. Precision also depended on the availability of other water quality covariates. When covariates were available, even a sudden, event-based peak in nitrate concentration was reconstructed well. By providing a promising method for accurate prediction of missing data, the utility and confidence in summary statistics and statistical trends will increase, thereby assisting the effective monitoring and management of fresh waters and other at-risk ecosystems.
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- Award ID(s):
- 1724433
- PAR ID:
- 10346069
- Date Published:
- Journal Name:
- International Journal of Environmental Research and Public Health
- Volume:
- 18
- Issue:
- 23
- ISSN:
- 1660-4601
- Page Range / eLocation ID:
- 12803
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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