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Title: Formation of Zirconium Chloride Guanidinate Complexes from the Reaction of Their Amide Analog with CCl4
Reaction of CCl4 with zirconium amide guanidinate Zr(NMe2)2[iPrNC(NMe2)NiPr]2 (1) has been found to give ZrCl(NMe2)[iPrNC(NMe2)NiPr]2 (2) as an intermediate and later ZrCl2[iPrNC(NMe2)NiPr]2 (3). The reaction is likely radical in nature. Complex 2 has been independently prepared from the reaction of ZrCl(NMe2)3 with 2 equiv of diisopropylcarbodiimide, iPr-N=C=N-iPr, and characterized by NMR and elemental analysis.  more » « less
Award ID(s):
1900296
PAR ID:
10347761
Author(s) / Creator(s):
Date Published:
Journal Name:
Wuji huaxue xuebao
Volume:
36
Issue:
6
ISSN:
1001-4861
Page Range / eLocation ID:
1157-1162
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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