In this work, we examine the use of competitive 13 C kinetic isotope effects ( 13 C KIEs) on CO 2 reduction reactions that produce CO and formic acid as a means to formulate reaction mechanisms. The findings reported here mark a further advancement in the combined 13 C KIE measurements and theoretical calculations methodology for probing CO 2 conversion reactions.
Reconfiguring Organic Color Centers on the sp 2 Carbon Lattice of Single-Walled Carbon Nanotubes
- Award ID(s):
- 1904488
- Publication Date:
- NSF-PAR ID:
- 10352924
- Journal Name:
- ACS Nano
- Volume:
- 16
- Issue:
- 2
- Page Range or eLocation-ID:
- 2077 to 2087
- ISSN:
- 1936-0851
- Sponsoring Org:
- National Science Foundation