Abstract The chemical composition of the inner region of protoplanetary disks can trace the composition of planetary-building material. The exact elemental composition of the inner disk has not yet been measured and tensions between models and observations still exist. Recent advancements have shown UV shielding to be able to increase the emission of organics. Here, we expand on these models and investigate how UV shielding may impact chemical composition in the inner 5 au. In this work, we use the model from Bosman et al. and expand it with a larger chemical network. We focus on the chemical abundances in the upper disk atmosphere where the effects of water UV shielding are most prominent and molecular lines originate. We find rich carbon and nitrogen chemistry with enhanced abundances of C2H2, CH4, HCN, CH3CN, and NH3by >3 orders of magnitude. This is caused by the self-shielding of H2O, which locks oxygen in water. This subsequently results in a suppression of oxygen-containing species like CO and CO2. The increase in C2H2seen in the model with the inclusion of water UV shielding allows us to explain the observed C2H2abundance without resorting to elevated C/O ratios as water UV shielding induced an effectively oxygen-poor environment in oxygen-rich gas. Thus, water UV shielding is important for reproducing the observed abundances of hydrocarbons and nitriles. From our model result, species like CH4, NH3, and NO are expected to be observable with the James Webb Space Telescope (JWST).
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Water UV-shielding in the Terrestrial Planet-forming Zone: Implications for Oxygen-18 Isotope Anomalies in H218O Infrared Emission and Meteorites
Abstract An understanding of abundance and distribution of water vapor in the innermost region of protoplanetary disks is key to understanding the origin of habitable worlds and planetary systems. Past observations have shown H 2 O to be abundant and a major carrier of elemental oxygen in disk surface layers that lie within the inner few astronomical units of the disk. The combination of high abundance and strong radiative transitions leads to emission lines that are optically thick across the infrared spectral range. Its rarer isotopologue H 2 18 O traces deeper into this layer and will trace the full content of the planet-forming zone. In this work, we explore the relative distribution of H 2 16 O and H 2 18 O within a model that includes water self-shielding from the destructive effects of ultraviolet radiation. In this Letter we show that there is an enhancement in the relative H 2 18 O abundance high up in the warm molecular layer within 0.1–10 au due to self-shielding of CO, C 18 O, and H 2 O. Most transitions of H 2 18 O that can be observed with JWST will partially emit from this layer, making it essential to take into account how H 2 O self-shielding may effect the H 2 O to H 2 18 O ratio. Additionally, this reservoir of H 2 18 O -enriched gas in combination with the vertical “cold finger” effect might provide a natural mechanism to account for oxygen isotopic anomalies found in meteoritic material in the solar system.
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- Award ID(s):
- 1907653
- PAR ID:
- 10356079
- Date Published:
- Journal Name:
- The Astrophysical Journal Letters
- Volume:
- 934
- Issue:
- 1
- ISSN:
- 2041-8205
- Page Range / eLocation ID:
- L14
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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