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1. Water UV-shielding in the Terrestrial Planet-forming Zone: Implications from Water Emission

   https://doi.org/10.3847/2041-8213/ac66ce  

   Bosman, Arthur D. ; Bergin, Edwin A. ; Calahan, Jenny ; Duval, Sara E. ( May 2022 , The Astrophysical Journal Letters)

   Mid-infrared spectroscopy is one of the few ways to observe the composition of the terrestrial planet-forming zone, the inner few astronomical units, of protoplanetary disks. The species currently detected in the disk atmosphere, for example, CO, CO₂, H₂O, and C₂H₂, are theoretically enough to constrain the C/O ratio on the disk surface. However, thermochemical models have difficulties in reproducing the full array of detected species in the mid-infrared simultaneously. In an effort to get closer to the observed spectra, we have included water UV-shielding as well as more efficient chemical heating into the thermochemical code Dust and Lines. We find that both are required to match the observed emission spectrum. Efficient chemical heating, in addition to traditional heating from UV photons, is necessary to elevate the temperature of the water-emitting layer to match the observed excitation temperature of water. We find that water UV-shielding stops UV photons from reaching deep into the disk, cooling down the lower layers with a higher column. These two effects create a hot emitting layer of water with a column of 1–10 × 10¹⁸cm⁻². This is only 1%–10% of the water column above the dustτ= 1 surface at mid-infrared wavelengths in the models andmore »represents <1% of the total water column.

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2. New Constraints on Protoplanetary Disk Gas Masses in Lupus

   https://doi.org/10.3847/1538-4357/ac517e  

   Anderson, Dana E. ; Cleeves, L. Ilsedore ; Blake, Geoffrey A. ; Bergin, Edwin A. ; Zhang, Ke ; Carpenter, John M. ; Schwarz, Kamber R. ( March 2022 , The Astrophysical Journal)

   Gas mass is a fundamental quantity of protoplanetary disks that directly relates to their ability to form planets. Because we are unable to observe the bulk H₂content of disks directly, we rely on indirect tracers to provide quantitative mass estimates. Current estimates for the gas masses of the observed disk population in the Lupus star-forming region are based on measurements of isotopologues of CO. However, without additional constraints, the degeneracy between H₂mass and the elemental composition of the gas leads to large uncertainties in such estimates. Here, we explore the gas compositions of seven disks from the Lupus sample representing a range of CO-to-dust ratios. With Band 6 and 7 ALMA observations, we measure line emission for HCO⁺, HCN, and N₂H⁺. We find a tentative correlation among the line fluxes for these three molecular species across the sample, but no correlation with¹³CO or submillimeter continuum fluxes. For the three disks where N₂H⁺is detected, we find that a combination of high disk gas masses and subinterstellar C/H and O/H are needed to reproduce the observed values. We find increases of ∼10–100× previous mass estimates are required to match the observed line fluxes. This work highlights how multimolecular studies are essentialmore »for constraining the physical and chemical properties of the gas in populations of protoplanetary disks, and that CO isotopologues alone are not sufficient for determining the mass of many observed disks.

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3. The Role of Neutral Hydrogen in Setting the Abundances of Molecular Species in the Milky Way’s Diffuse Interstellar Medium. I. Observational Constraints from ALMA and NOEMA

   https://doi.org/10.3847/1538-4357/ac5035  

   Rybarczyk, Daniel R. ; Stanimirović, Snežana ; Gong, Munan ; Babler, Brian ; Murray, Claire E. ; Gerin, Maryvonne ; Winters, Jan Martin ; Luo, Gan ; Dame, T. M. ; Steffes, Lucille ( March 2022 , The Astrophysical Journal)

   We have complemented existing observations of Hiabsorption with new observations of HCO⁺, C₂H, HCN, and HNC absorption from the Atacama Large Millimeter/submillimeter Array and the Northern Extended Millimeter Array in the directions of 20 background radio continuum sources with 4° ≤ ∣b∣ ≤ 81° to constrain the atomic gas conditions that are suitable for the formation of diffuse molecular gas. We find that these molecular species form along sightlines whereA_V≳ 0.25, consistent with the threshold for the Hi-to-H₂transition at solar metallicity. Moreover, we find that molecular gas is associated only with structures that have an Hioptical depth >0.1, a spin temperature <80 K, and a turbulent Mach number ≳ 2. We also identify a broad, faint component to the HCO⁺absorption in a majority of sightlines. Compared to the velocities where strong, narrow HCO⁺absorption is observed, the Hiat these velocities has a lower cold neutral medium fraction and negligible CO emission. The relative column densities and linewidths of the different molecular species observed here are similar to those observed in previous experiments over a range of Galactic latitudes, suggesting that gas in the solar neighborhood and gas in the Galactic plane are chemically similar. For a select sample of previouslymore »observed sightlines, we show that the absorption line profiles of HCO⁺, HCN, HNC, and C₂H are stable over periods of ∼3 yr and ∼25 yr, likely indicating that molecular gas structures in these directions are at least ≳100 au in size.

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4. CLEAR: High-ionization [Ne v] λ3426 Emission-line Galaxies at 1.4 < z < 2.3

   https://doi.org/10.3847/1538-4357/acc1e6  

   Cleri, Nikko J. ; Yang, Guang ; Papovich, Casey ; Trump, Jonathan R. ; Backhaus, Bren E. ; Estrada-Carpenter, Vicente ; Finkelstein, Steven L. ; Giavalisco, Mauro ; Hutchison, Taylor A. ; Ji, Zhiyuan ; et al ( May 2023 , The Astrophysical Journal)

   We analyze a sample of 25 [Nev] (λ3426) emission-line galaxies at 1.4 <z< 2.3 using Hubble Space Telescope/Wide Field Camera 3 G102 and G141 grism observations from the CANDELS LyαEmission at Reionization (CLEAR) survey. [Nev] emission probes extremely energetic photoionization (creation potential of 97.11 eV) and is often attributed to energetic radiation from active galactic nuclei (AGNs), shocks from supernovae, or an otherwise very hard ionizing spectrum from the stellar continuum. In this work, we use [Nev] in conjunction with other rest-frame UV/optical emission lines ([Oii]λλ3726, 3729, [Neiii]λ3869, Hβ, [Oiii]λλ4959, 5007, Hα+[Nii]λλ6548, 6583, [Sii]λλ6716, 6731), deep (2–7 Ms) X-ray observations (from Chandra), and mid-infrared imaging (from Spitzer) to study the origin of this emission and to place constraints on the nature of the ionizing engine. The majority of the [Nev]-detected galaxies have properties consistent with ionization from AGNs. However, for our [Nev]-selected sample, the X-ray luminosities are consistent with local (z≲ 0.1) X-ray-selected Seyferts, but the [Nev] luminosities are more consistent with those fromz∼ 1 X-ray-selected QSOs. The excess [Nev] emission requires either reduced hard X-rays or a ∼0.1 keV excess. We discuss possible origins of the apparent [Nev] excess, which could be related to the “soft (X-ray) excess”more »observed in some QSOs and Seyferts and/or be a consequence of a complex/anisotropic geometry for the narrow-line region, combined with absorption from a warm, relativistic wind ejected from the accretion disk. We also consider implications for future studies of extreme high-ionization systems in the epoch of reionization (z≳ 6) with the James Webb Space Telescope.

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5. Water Shielding in the Terrestrial Planet-forming Zone: Implication for Inner Disk Organics

   https://doi.org/10.3847/2041-8213/ac822b  

   Duval, Sara E. ; Bosman, Arthur D. ; Bergin, Edwin A. ( July 2022 , The Astrophysical Journal Letters)

   Abstract The chemical composition of the inner region of protoplanetary disks can trace the composition of planetary-building material. The exact elemental composition of the inner disk has not yet been measured and tensions between models and observations still exist. Recent advancements have shown UV shielding to be able to increase the emission of organics. Here, we expand on these models and investigate how UV shielding may impact chemical composition in the inner 5 au. In this work, we use the model from Bosman et al. and expand it with a larger chemical network. We focus on the chemical abundances in the upper disk atmosphere where the effects of water UV shielding are most prominent and molecular lines originate. We find rich carbon and nitrogen chemistry with enhanced abundances of C 2 H 2 , CH 4 , HCN, CH 3 CN, and NH 3 by >3 orders of magnitude. This is caused by the self-shielding of H 2 O, which locks oxygen in water. This subsequently results in a suppression of oxygen-containing species like CO and CO 2 . The increase in C 2 H 2 seen in the model with the inclusion of water UV shielding allows us tomore »explain the observed C 2 H 2 abundance without resorting to elevated C/O ratios as water UV shielding induced an effectively oxygen-poor environment in oxygen-rich gas. Thus, water UV shielding is important for reproducing the observed abundances of hydrocarbons and nitriles. From our model result, species like CH 4 , NH 3 , and NO are expected to be observable with the James Webb Space Telescope (JWST).« less