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1. Synthesis of Unsaturated Silyl Heterocycles via an Intramolecular Silyl-Heck Reaction

   https://doi.org/10.1021/acs.organomet.9b00498  

   Reid, William B.; McAtee, Jesse R.; Watson, Donald A. (September 2019, Organometallics)
2. Lewis Acid-Activated Reactions of Silyl Ketenes for the Preparation of α-Silyl Carbonyl Compounds

   https://doi.org/10.1021/acs.joc.9b01859  

   Mitchell, Sarah M.; Xiang, Yuanhui; Matthews, Rachael; Amburgey, Alexis M.; Pentzer, Emily B. (September 2019, The Journal of Organic Chemistry)
3. Electrophilic heterocycles: Functionalization with enol silyl ethers

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   Holmin, Grant P.; Hood, Jacob C.; Xue, Hongfang; Klumpp, Douglas A. (August 2023, Tetrahedron)
4. Degradable Melamine-Based Adhesives Using Dynamic Silyl Ether Bonds

   https://doi.org/10.1021/acsapm.4c01247  

   Pierce, Ian C; Barroso, Jorge; Ko, Joanne B; Vlaisavljevich, Bess; Kalow, Julia A (July 2024, ACS Applied Polymer Materials)

   Materials made from covalently cross-linked polymer networks are ubiquitous in everyday life but are difficult to process at the end of their life cycle. Therefore, it is essential to design materials with sustainability in mind to reduce the detrimental effects of plastic waste buildup. Functionalized triazines such as 1,3,5-triazine-2,4,6-triamine (melamine), hexamethylolmelamine (HMM), and hexakis(methoxymethyl)melamine (HMMM) are key components of robust thermosets, adhesives, and coatings. We combine HMM and HMMM with an alkoxysilane to produce transparent thermosets with remarkable glass adhesion. The dynamicity of silyl ether bonds in the network makes the materials susceptible to methanolysis, enabling the recovery of HMMM and the substrate. A combination of solution- and solid-phase techniques is used to elucidate both gelation and degradation pathways. 

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5. Silyl Transfer Pathway to a Ce(IV) Imido Complex

   https://doi.org/10.1021/acs.organomet.8b00366  

   Cheisson, Thibault; Solola, Lukman A.; Gau, Michael R.; Carroll, Patrick J.; Schelter, Eric J. (September 2018, Organometallics)