The asymmetric unit in the title salt, (C8H20N)2[SnCl4(C7H4Cl2F3)2], features a di-isobutylammonium cation in a general position and a diorganotin tetrachloride dianion,i.e. tetrachloridobis(3-trifuoromethylphenyl)stannate(IV), located on a centre of inversion; the SnIVatom is octahedrally coordinated. In the crystal, charge-assisted N+—H...Cl hydrogen bonds along with C—H...F contacts occur within supramolecular layers that interdigitate along thea-axis direction.
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Synthesis of (((1R,3S,3'S)-3,3'-Diethyl-3H,3'H-1,1'-spirobi[isobenzofuran]-7,7'-diyl)bis(oxy))bis(diphenylphosphane)
- Award ID(s):
- 1955069
- PAR ID:
- 10356722
- Date Published:
- Journal Name:
- Organic Syntheses
- Volume:
- 99
- ISSN:
- 2333-3553
- Page Range / eLocation ID:
- 190 to 214
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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In the title double proton-transfer salt, C 12 H 12 N 2 2+ ·2C 8 H 7 O 4 − , consisting of a 1:2 ratio of 4,4'-(ethene-1,2-diyl)dipyridinium cations ( trans bipyridinium ethylene) to 2-hydroxy-3-methoxybenzoate anions ( o -vanillate), the complete cation is generated by crystallographic inversion symmetry and it is linked to adjacent o -vanillate anions by N—H...O hydrogen bonds, forming trimolecular assemblies. The trimers are linked by C—H...O hydrogen bonds as well as aromatic π–π stacking interactions into a three-dimensional network. The anion features an intramolecular O—H...O hydrogen bond.more » « less
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