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1. Isotope studies of presolar silicon carbide grains from supernovae: new constraints for hydrogen-ingestion supernova models

   https://doi.org/10.1093/mnras/stae1523  

   Hoppe, Peter; Leitner, Jan; Pignatari, Marco; Amari, Sachiko (June 2024, Monthly Notices of the Royal Astronomical Society)

   ABSTRACT We report isotope data for C, N, Al, Si, and S of 33 presolar SiC and Si3N4 grains (0.3–1.6 $$\mu$$m) of Type X, C, D, and N from the Murchison CM2 meteorite of likely core-collapse supernova (CCSN) origin which we discuss together with data of six SiC X grains from an earlier study. The isotope data are discussed in the context of hydrogen ingestion supernova (SN) models. We have modified previously used ad-hoc mixing schemes in that we considered (i) heterogeneous H ingestion into the He shell of the pre-SN star, (ii) a variable C-N fractionation for the condensation of SiC grains in the SN ejecta, and (iii) smaller mass units for better fine-tuning. With our modified ad-hoc mixing approach over small scales (0.2–0.4 M⊙), with major contributions from the O-rich O/nova zone, we find remarkably good fits (within a few per cent) for 12C/13C, 26Al/27Al, and 29Si/28Si ratios. The 14N/15N ratio of SiC grains can be well matched if variable C-N fractionation is considered. However, the Si3N4 isotope data point to overproduction of 15N in hydrogen ingestion CCSN models and lower C-N fractionation during SiC condensation than applied here. Our ad-hoc mixing approach based on current CCSN models suggests that the O-rich O/nova zone, which uniquely combines explosive H- and He-burning signatures, is favourable for SiC and Si3N4 formation. The effective range of C/O abundance variations in the He shell triggered by H ingestion events in the massive star progenitor is currently not well constrained and needs further investigation. 

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2. New Constraints for Supernova Models from Presolar Silicon Carbide X Grains with Very High ²⁶ Al/ ²⁷ Al Ratios

   https://doi.org/10.3847/2041-8213/acb157  

   Hoppe, Peter; Leitner, Jan; Pignatari, Marco; Amari, Sachiko (February 2023, The Astrophysical Journal Letters)

   Abstract We report C, N, Mg-Al, Si, and S isotope data of six 1–3μm-sized SiC grains of Type X from the Murchison CM2 chondrite, believed to have formed in the ejecta of core-collapse supernova (CCSN) explosions. Their C, N, and Si isotopic compositions are fully compatible with previously studied X grains. Magnesium is essentially monoisotopic²⁶Mg which gives clear evidence for the decay of radioactive²⁶Al. Inferred initial²⁶Al/²⁷Al ratios are between 0.6 and 0.78 which is at the upper end of previously observed ratios of X grains. Contamination with terrestrial or solar system Al apparently is low or absent, which makes the X grains from this study particularly interesting and useful for a quantitative comparison of Al isotope data with predictions from supernova models. The consistently high²⁶Al/²⁷Al ratios observed here may suggest that the lower²⁶Al/²⁷Al ratios of many X grains from the literature are the result of significant Al contamination and in part also of an improper quantification of²⁶Al. The real dispersion of²⁶Al/²⁷Al ratios in X grains needs to be explored by future studies. The high observed²⁶Al/²⁷Al ratios in this work provide a crucial constraint for the production of²⁶Al in CCSN models. We explored different CCSN models, including both “classical” and H ingestion CCSN models. It is found that the classical models cannot account for the high²⁶Al/²⁷Al ratios observed here; in contrast, H ingestion models are able to reproduce the²⁶Al/²⁷Al ratios along with C, N, and Si isotopic ratios reasonably well. 

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3. Chondrules reveal large-scale outward transport of inner Solar System materials in the protoplanetary disk

   https://doi.org/10.1073/pnas.2005235117  

   Williams, Curtis D.; Sanborn, Matthew E.; Defouilloy, Céline; Yin, Qing-Zhu; Kita, Noriko T.; Ebel, Denton S.; Yamakawa, Akane; Yamashita, Katsuyuki (September 2020, Proceedings of the National Academy of Sciences)

   null (Ed.)

   Dynamic models of the protoplanetary disk indicate there should be large-scale material transport in and out of the inner Solar System, but direct evidence for such transport is scarce. Here we show that the ε 50 Ti-ε 54 Cr-Δ 17 O systematics of large individual chondrules, which typically formed 2 to 3 My after the formation of the first solids in the Solar System, indicate certain meteorites (CV and CK chondrites) that formed in the outer Solar System accreted an assortment of both inner and outer Solar System materials, as well as material previously unidentified through the analysis of bulk meteorites. Mixing with primordial refractory components reveals a “missing reservoir” that bridges the gap between inner and outer Solar System materials. We also observe chondrules with positive ε 50 Ti and ε 54 Cr plot with a constant offset below the primitive chondrule mineral line (PCM), indicating that they are on the slope ∼1.0 in the oxygen three-isotope diagram. In contrast, chondrules with negative ε 50 Ti and ε 54 Cr increasingly deviate above from PCM line with increasing δ 18 O, suggesting that they are on a mixing trend with an ordinary chondrite-like isotope reservoir. Furthermore, the Δ 17 O-Mg# systematics of these chondrules indicate they formed in environments characterized by distinct abundances of dust and H 2 O ice. We posit that large-scale outward transport of nominally inner Solar System materials most likely occurred along the midplane associated with a viscously evolving disk and that CV and CK chondrules formed in local regions of enhanced gas pressure and dust density created by the formation of Jupiter. 

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4. Detrital Chromite from Jack Hills, Western Australia: Signatures of Metamorphism and Constraints on Provenance

   https://doi.org/10.1093/petrology/egab052  

   Staddon, Leanne G; Parkinson, Ian J; Cavosie, Aaron J; Elliott, Tim; Valley, John W; Fournelle, John; Kemp, Anthony I; Shirey, Steven B (December 2021, Journal of Petrology)

   Abstract Detrital chromites are commonly reported within Archean metasedimentary rocks, but have thus far garnered little attention for use in provenance studies. Systematic variations of Cr–Fe spinel mineral chemistry with changing tectonic setting have resulted in the extensive use of chromite as a petrogenetic indicator, and so detrital chromites represent good candidates to investigate the petrogenesis of eroded Archean mafic and ultramafic crust. Here, we report the compositions of detrital chromites within fuchsitic (Cr-muscovite rich) metasedimentary rocks from the Jack Hills, situated within the Narryer Terrane, Yilgarn Craton, Western Australia, which are geologically renowned for hosting Hadean (>4000 Ma) zircons. We highlight signatures of metamorphism, including highly elevated ZnO and MnO, coupled with lowered Mg# in comparison with magmatic chromites, development of pitted domains, and replacement of primary inclusions by phases that are part of the metamorphic assemblages within host metasedimentary rocks. Oxygen isotope compositions of detrital chromites record variable exchange with host metasedimentary rocks. The variability of metamorphic signatures between chromites sampled only meters apart further indicates that modification occurred in situ by interaction of detrital chromites with metamorphic fluids and secondary mineral assemblages. Alteration probably occurred during upper greenschist to lower amphibolite facies metamorphism and deformation of host metasedimentary rocks at ∼2650 Ma. Regardless of metamorphic signatures, sampling location or grain shape, chromite cores yield a consistent range in Cr#. Although other key petrogenetic indices, such as Fe2O3 and TiO2 contents, are complicated in Jack Hills chromites by mineral non-stoichiometry and secondary mobility within metasedimentary rocks, we demonstrate that the Cr# of chromite yields significant insights into their provenance. Importantly, moderate Cr# (typically 55–70) precludes a komatiitic origin for the bulk of chromites, reflecting a dearth of komatiites and intrusive equivalents within the erosional catchment of the Jack Hills metasedimentary units. We suggest that the Cr# of Jack Hills chromite fits well with chromites derived from layered intrusions, and that a single layered intrusion may account for the observed chemical compositions of Jack Hills detrital chromites. Where detailed characterization of key metamorphic signatures is undertaken, detrital chromites preserved within Archean metasedimentary rocks may therefore yield valuable information on the petrogenesis and geodynamic setting of poorly preserved mafic and ultramafic crust. 

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5. Linking ammonium nitrate‐aluminum ( AN‐AL ) post‐blast residues to pre‐blast explosive materials using isotope ratio and trace elemental analysis for source attribution

   https://doi.org/10.1111/1556-4029.15190  

   Ippoliti, Paul; Werlich, Jeffrey; Fuglsby, Cami; Yarnes, Chris; Saunders, Christopher P.; Dettman, Josh (March 2023, Journal of Forensic Sciences)

   Abstract Forensic science practitioners are often called upon to attribute crimes using trace evidence, such as explosive remnants, with the ultimate goal of associating a crime with a suspect or suspects in order to prevent further attacks. The explosive charge is an attractive component for attribution in crimes involving explosives as there are limited pathways for acquisition. However, there is currently no capability to link an explosive charge to its source via post‐blast trace residues using isotope ratios or trace elements. Here, we sought to determine if pre‐blast attribution signatures are preserved after detonation and can be subsequently recovered and detected. A field study was conducted to recover samples of post‐blast explosives from controlled detonations of ammonium nitrate‐aluminum (AN‐Al), which were then analyzed via isotope ratio mass spectrometry (IRMS) and inductively coupled plasma‐mass spectrometry (ICP‐MS) for quantitation and profiling of isotopes ratio and trace element signatures, respectively. Oxygen and nitrogen isotope ratios from AN‐Al yielded some of the most promising results with considerable overlap within one standard deviation of the reference between the spreads of pre‐ and post‐blast data. Trace element results from AN‐Al support the findings in the isotope ratio data, with 26 elements detected in both pre‐ and post‐blast samples, and several elements including B, Cd, Cr, Ni, Sn, V, and Zn showing considerable overlap. These preliminary results provide a proof‐of‐concept for the development of forensic examinations that can attribute signatures from post‐blast debris to signatures in pre‐blast explosive materials for use in future investigations. 

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