skip to main content


Title: Tungsten Isotope Composition of Archean Crustal Reservoirs and Implications for Terrestrial μ 182 W Evolution
Abstract

The evolution of Earth's major geochemical reservoirs over ~4.5 × 109 years remains a matter of intense study. Geochemical tools in the form of short‐lived radionuclide isotope ratios (142Nd/144Nd and182W/184W) have expanded our understanding of the geochemical variability in both the modern and ancient Earth. Here, we present142Nd/144Nd and182W/184W data from a suite of rocks from the Slave craton that formed over a 1.1 × 109 year time span in the Archean. The rocks have consistently high182W/184W, yet142Nd/144Nd that is lower than bulk mantle and increased over time. The declining variability in142Nd/144Nd with time likely reflects the homogenization of compositional heterogeneities in the silicate Earth that were initially created by differentiation events that occurred prior to 4.2 Ga. The elevated182W/184W recorded in the Slave samples help refine models for the broader W‐isotope evolution of the silicate Earth. Globally, the Archean mantle that formed continental crust was dominated by182W/184W elevated by some 10–15 ppm compared to the value for the modern upper mantle. The Slave craton lacks significant volumes of komatiite yet has elevated182W/184W until 2.9 Ga. This observation, combined with the presence of other komatiite suites that have low182W/184W, suggests that deep‐seated sources contributed low182W/184W in the Archean Earth. The regional variability in182W/184W may be explained by invoking chemical and/or isotopic exchange between a well‐mixed silicate Earth and the core or a portion of the lower mantle whose W‐isotope composition has been influenced by interaction with the core.

 
more » « less
NSF-PAR ID:
10359866
Author(s) / Creator(s):
 ;  ;  ;  ;  ;  
Publisher / Repository:
DOI PREFIX: 10.1029
Date Published:
Journal Name:
Geochemistry, Geophysics, Geosystems
Volume:
21
Issue:
7
ISSN:
1525-2027
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract A viscosity jump of one to two orders of magnitude in the lower mantle of Earth at 800–1,200-km depth is inferred from geoid inversions and slab-subducting speeds. This jump is known as the mid-mantle viscosity jump 1,2 . The mid-mantle viscosity jump is a key component of lower-mantle dynamics and evolution because it decelerates slab subduction 3 , accelerates plume ascent 4 and inhibits chemical mixing 5 . However, because phase transitions of the main lower-mantle minerals do not occur at this depth, the origin of the viscosity jump remains unknown. Here we show that bridgmanite-enriched rocks in the deep lower mantle have a grain size that is more than one order of magnitude larger and a viscosity that is at least one order of magnitude higher than those of the overlying pyrolitic rocks. This contrast is sufficient to explain the mid-mantle viscosity jump 1,2 . The rapid growth in bridgmanite-enriched rocks at the early stage of the history of Earth and the resulting high viscosity account for their preservation against mantle convection 5–7 . The high Mg:Si ratio of the upper mantle relative to chondrites 8 , the anomalous 142 Nd: 144 Nd, 182 W: 184 W and 3 He: 4 He isotopic ratios in hot-spot magmas 9,10 , the plume deflection 4 and slab stagnation in the mid-mantle 3 as well as the sparse observations of seismic anisotropy 11,12 can be explained by the long-term preservation of bridgmanite-enriched rocks in the deep lower mantle as promoted by their fast grain growth. 
    more » « less
  2. The noble gas isotope systematics of ocean island basalts suggest the existence of primordial mantle signatures in the deep mantle. Yet, the isotopic compositions of lithophile elements (Sr, Nd, Hf) in these lavas require derivation from a mantle source that is geochemically depleted by melt extraction rather than primitive. Here, this apparent contradiction is resolved by employing a compilation of the Sr, Nd, and Hf isotope composition of kimberlites—volcanic rocks that originate at great depth beneath continents. This compilation includes kimberlites as old as 2.06 billion years and shows that kimberlites do not derive from a primitive mantle source but sample the same geochemically depleted component (where geochemical depletion refers to ancient melt extraction) common to most oceanic island basalts, previously called PREMA (prevalent mantle) or FOZO (focal zone). Extrapolation of the Nd and Hf isotopic compositions of the kimberlite source to the age of Earth formation yields a143Nd/144Nd-176Hf/177Hf composition within error of chondrite meteorites, which include the likely parent bodies of Earth. This supports a hypothesis where the source of kimberlites and ocean island basalts contains a long-lived component that formed by melt extraction from a domain with chondritic143Nd/144Nd and176Hf/177Hf shortly after Earth accretion. The geographic distribution of kimberlites containing the PREMA component suggests that these remnants of early Earth differentiation are located in large seismically anomalous regions corresponding to thermochemical piles above the core–mantle boundary. PREMA could have been stored in these structures for most of Earth’s history, partially shielded from convective homogenization.

     
    more » « less
  3. Rare high-3He/4He signatures in ocean island basalts (OIB) erupted at volcanic hotspots derive from deep-seated domains preserved in Earth’s interior. Only high-3He/4He OIB exhibit anomalous182W—an isotopic signature inherited during the earliest history of Earth—supporting an ancient origin of high3He/4He. However, it is not understood why some OIB host anomalous182W while others do not. We provide geochemical data for the highest-3He/4He lavas from Iceland (up to 42.9 times atmospheric) with anomalous182W and examine how Sr-Nd-Hf-Pb isotopic variations—useful for tracing subducted, recycled crust—relate to high3He/4He and anomalous182W. These data, together with data on global OIB, show that the highest-3He/4He and the largest-magnitude182W anomalies are found only in geochemically depleted mantle domains—with high143Nd/144Nd and low206Pb/204Pb—lacking strong signatures of recycled materials. In contrast, OIB with the strongest signatures associated with recycled materials have low3He/4He and lack anomalous182W. These observations provide important clues regarding the survival of the ancient He and W signatures in Earth’s mantle. We show that high-3He/4He mantle domains with anomalous182W have low W and4He concentrations compared to recycled materials and are therefore highly susceptible to being overprinted with low3He/4He and normal (not anomalous)182W characteristic of subducted crust. Thus, high3He/4He and anomalous182W are preserved exclusively in mantle domains least modified by recycled crust. This model places the long-term preservation of ancient high3He/4He and anomalous182W in the geodynamic context of crustal subduction and recycling and informs on survival of other early-formed heterogeneities in Earth’s interior.

     
    more » « less
  4. Major and trace element abundances, including highly siderophile elements, and 187Os and 182W isotopic compositions were determined for ca. 89 Ma mafic and ultramafic rocks from the islands of Gorgona (Colombia) and Curaçao (Dutch Caribbean). The volcanic systems of both islands were likely associated with a mantle plume that generated the Caribbean Large Igneous Provence. The major and lithophile trace element characteristics of the rocks examined are consistent with the results of prior studies, and indicate derivation from both a chemically highly-depleted mantle component, and an enriched, or less highly-depleted mantle component. Highly siderophile element abundances for these rocks are generally similar to rocks with comparable MgO globally, indicating that the major source components were not substantially enriched or depleted in these elements. Rhenium-Os isotopic systematics of most rocks of both islands indicate derivation from a mantle source with an initial 187Os/188Os ratio between that of the contemporaneous average depleted mid-ocean ridge mantle and bulk silicate Earth. The composition may reflect either an average lower mantle signature, or global-scale Os isotopic heterogeneity in the upper mantle. Some of the basalts, as well as two of the komatiites, are characterized by calculated initial 187Os/188Os ratios 10-15% higher than the chondritic reference. These more radiogenic Os isotopic compositions do not correlate with major or trace element systematics, and indicate a mantle source component that was most likely produced by either sulfide metasomatism or ancient Re/Os fractionation. Tungsten-182 isotopic compositions measured for rocks from both islands are characterized by variable 182W values ranging from modern bulk silicate Earth-like to strongly negative values. The 182W values do not correlate with major/trace element abundances or initial 187Os/188Os compositions. As with some modern ocean island basalt systems, however, the lowest 182W value (-53) measured, for a Gorgona olivine gabbro, corresponds with the highest 3He/4He previously measured from the suite (15.8 R/RA). Given the lack of correlation with other chemical/isotopic compositions, the mantle component characterized by negative 182W and possibly high 3He/4He is most parsimoniously explained to have formed as a result of isotopic equilibration between the mantle and core at the core-mantle boundary. 
    more » « less
  5. Abstract

    The occurrence of plate tectonic processes on Earth during the Paleoproterozoic is supported by ca. 2.2–1.8 Ga subduction‐collision orogens associated with the assembly of the Columbia‐Nuna supercontinent. Subsequent supercontinent breakup is evidence by global ca. 1.8–1.6 Ga large igneous provinces. The North China craton is notable for containing Paleoproterozoic orogens along its margins, herein named the Northern Margin orogen, yet the nature and timing of orogenic and extensional processes of these orogens and their role in the supercontinent cycle remain unclear. In this contribution, we present new field observations, U‐Pb zircon and baddeleyite geochronology dates, and major/trace‐element and isotope geochemical analyses from the northern margin of the North China craton that detail its Paleoproterozoic tectonic and magmatic history. Specifically, we record the occurrence of ca. 2.2–2.0 Ga magmatic arc rocks, ca. 1.9–1.88 Ga tectonic mélange and mylonitic shear zones, and folded lower Paleoproterozoic strata. These rocks were affected by ca. 1.9–1.8 Ga granulite‐facies metamorphism and ca. 1.87–1.78 Ga post‐collisional, extension‐related magmatism along the cratonal northern margin. We interpret that the generation and emplacement of these rocks, and the coupled metamorphic and magmatic processes, were related to oceanic subduction and subsequent continent‐continent collision during the Paleoproterozoic. The occurrence of ca. 1.77–1.73 Ga mafic dykes and ca. 1.75 Ga mylonitic shear zones along the northern margin of the North China craton may have been related to a regional mantle plume event. Our results are consistent with modern style plate tectonics, including oceanic subduction‐related plate convergence and continent‐continent collision, operating in the Paleoproterozoic.

     
    more » « less