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Coexistence of excitons and free charge carriers can complicate conventional spectroscopic studies of transport mechanisms in layered perovskite solar cells. Because of their large concentrations and absorbance cross sections, excitons tend to dominate spectroscopic signals and obscure observations of free charges in this class of systems. To investigate the effects of interstitial organic molecules on charge transport in photovoltaic devices, we apply a newly developed four-pulse transient grating method with photocurrent detection to layered perovskites possessing a range of quantum well thicknesses. In this method, a phase-stabilized “pump” pulse-pair photoexcites a carrier density grating in the active layer of a photovoltaic cell, whereas transport is time-resolved using the carrier density grating generated by a subsequent “probe” pulse-pair. Carrier diffusion mechanisms are revealed by measuring the recombination-induced nonlinear response of the device while varying the delay between pulse-pairs and phase difference between density gratings. Like drift velocity dispersion, our data suggest that encounters with inorganic–organic interfaces broaden the range of diffusivities in addition to skewing the distributions toward slower transit times. Rather than tunneling through the potential energy barriers associated with the organic material, the experimental measurements support a physical picture in which the photoexcited carriers traverse circuitous paths through the active layer while occupying the phases of the thickest quantum wells.
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Origin of layered perovskite device efficiencies revealed by multidimensional time-of-flight spectroscopy
Mixtures of layered perovskite quantum wells with different sizes form prototypical light-harvesting antenna structures in solution-processed films. Gradients in the bandgaps and energy levels are established by concentrating the smallest and largest quantum wells near opposing electrodes in photovoltaic devices. Whereas short-range energy and charge carrier funneling behaviors have been observed in layered perovskites, our recent work suggests that such light-harvesting processes do not assist long-range charge transport due to carrier trapping at interfaces between quantum wells and interstitial organic spacer molecules. Here, we apply a two-pulse time-of-flight technique to a family of layered perovskite systems to explore the effects that interstitial organic molecules have on charge carrier dynamics. In these experiments, the first laser pulse initiates carrier drift within the active layer of a photovoltaic device, whereas the second pulse probes the transient concentrations of photoexcited carriers as they approach the electrodes. The instantaneous drift velocities determined with this method suggest that the rates of trap-induced carrier deceleration increase with the concentrations of organic spacer cations. Overall, our experimental results and model calculations suggest that the layered perovskite device efficiencies primarily reflect the dynamics of carrier trapping at interfaces between quantum wells and interstitial organic phases.
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- Award ID(s):
- 1763207
- PAR ID:
- 10363156
- Publisher / Repository:
- American Institute of Physics
- Date Published:
- Journal Name:
- The Journal of Chemical Physics
- Volume:
- 156
- Issue:
- 8
- ISSN:
- 0021-9606
- Page Range / eLocation ID:
- Article No. 084202
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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