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Robust earth-abundant transition metal-based photocatalysts are needed for photocatalytic CO2 reduction. A series of six Ni(II) complexes have been synthesized with a tridentate CNC pincer ligand composed of two imidazole or benzimidazole derived N-heterocyclic carbene (NHC) rings and a pyridyl ring with different R substituents (R = OMe, Me, H) para to N of the pyridine ring. These complexes have been characterized using spectroscopic, analytic, and crystallographic methods. The electrochemical properties of all complexes were studied by cyclic voltammetry under N2 and CO2 atmospheres. Photocatalytic reduction of CO2 to CO and HCO2– was analyzed using all the complexes in the presence and absence of an external photosensitizer (PS). All of these complexes are active as photocatalysts for CO2 reduction with and without the presence of an external PS with appreciable turnover numbers (TON) for formate (HCO2–) production and typically lower amounts of CO. Notably, all Ni(II) CNC-pincer complexes in this series are also active as self-sensitized photocatalysts. Complex 4Me with a benzimidazole derived CNC pincer ligand was found to be the most active self-sensitized photocatalyst. Ultrafast transient absorption spectroscopy (TAS) experiments and computational studies were performed to understand the mechanism of these catalysts. Whereas sensitized catalysis involves halide loss to produce more active complexes, self-sensitized catalysis requires some halide to remain coordinated to allow for a favorable electron transfer between the excited nickel complex and the sacrificial electron donor. This then allows the nickel complex to undergo CO2 reduction catalysis via NiI or Ni0 catalytic cycles. The two active species (NiI¬ and Ni0) demonstrate distinct reactivity and selectivity which influences the formation of CO vs. formate as the product.
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Sensitized and Self‐Sensitized Photocatalytic Carbon Dioxide Reduction Under Visible Light with Ruthenium Catalysts Shows Enhancements with More Conjugated Pincer Ligands
Abstract A new method to synthesize complexes of the type [(CNC)RuII(NN)L]n+has been introduced, where CNC is a tridentate pincer composed of two (benz)imidazole derived NHC rings and a pyridyl ring, NN is a bidentate aromatic diimine ligand, L=bromide or acetonitrile, and n=1 or 2. Following this new method a series of six new complexes has been synthesized and characterized by spectroscopic, analytic, crystallographic, and computational methods. Their electrochemical properties have been studiedviacyclic voltammetry under both N2and CO2atmospheres. Photocatalytic reduction of CO2to CO was performed using these complexes both in the presence (sensitized) and absence (self‐sensitized) of an external photosensitizer. This study evaluates the effect of different CNC, NN, and L ligands in sensitized and self‐sensitized photocatalysis. Catalysts bearing the benzimidazole derived CNC pincer show much better activity for both sensitized and self‐sensitized photocatalysis as compared to catalysts bearing the imidazole derived CNC pincer. Furthermore, self‐sensitized photocatalysis requires a diimine ligand for CO2reduction with catalyst2ACNbeing the most active catalyst in this series with TON=85 and TOF=22 h−1with an electron donating 4,4′‐dimethyl‐2,2′‐bipyridyl (dmb) ligand and a benzimidazole derived CNC pincer.
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- PAR ID:
- 10364373
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- European Journal of Inorganic Chemistry
- Volume:
- 2022
- Issue:
- 8
- ISSN:
- 1434-1948
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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