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Title: Phase Transition of Enstatite‐Ferrosilite Solid Solutions at High Pressure and High Temperature: Constraints on Metastable Orthopyroxene in Cold Subduction
Abstract

(Mg, Fe)SiO3orthopyroxene is an abundant mineral of oceanic subducting slabs. In‐situ high‐pressure and high‐temperature single‐crystal X‐ray diffraction has been used to investigate the phase transition of orthopyroxene across the enstatite‐ferrosilite (En‐Fs) join (En70Fs30, En55Fs45, En44Fs56and Fs100) up to 24.3 GPa and 800 K, simulating conditions within the coldest part of a subduction zone consisting of an old and rapidly subducting slab. Instead of the orthopyroxene → high‐pressure clinopyroxene transition, the α‐opx → β‐opx and β‐opx → γ‐opx phase transition are observed at 7.2–15.3 and 11.6–21.1 GPa (depending on the Fs content), respectively. This study indicates that the pressure‐induced phase transition of (Mg, Fe)SiO3orthopyroxene under relatively low temperature (<800 K) could be different than those occurring under relatively high temperature (>800 K). Additionally, the α‐opx → β‐opx → γ‐opx phase transition could exist within the center of the extremely cold slabs (like Tonga), where such low temperature persists to ~600‐km depth.

 
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Award ID(s):
1722969
NSF-PAR ID:
10366865
Author(s) / Creator(s):
 ;  ;  ;  ;  ;  
Publisher / Repository:
DOI PREFIX: 10.1029
Date Published:
Journal Name:
Geophysical Research Letters
Volume:
47
Issue:
12
ISSN:
0094-8276
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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