The deep ocean has long been recognized as the reservoir that stores the carbon dioxide (CO2) removed from the atmosphere during Pleistocene glacial periods. The removal of glacial atmospheric CO2into the ocean is likely modulated by an increase in the degree of utilization of macronutrients at the sea surface and enhanced storage of respired CO2in the deep ocean, known as enhanced efficiency of the biological pump. Enhanced biological pump efficiency during glacial periods is most easily documented in the deep ocean using proxies for oxygen concentrations, which are directly linked to respiratory CO2levels. We document the enhanced storage of respired CO2during the Last Glacial Maximum (LGM) in the Pacific Southern Ocean and deepest Equatorial Pacific using records of deglacial authigenic manganese, which form as relict peaks during increases in bottom water oxygen (BWO) concentration. These peaks are found at depths and regions where other oxygenation histories have been ambiguous, due to diagenetic alteration of authigenic uranium, another proxy for BWO. Our results require that the entirety of the abyssal Pacific below approximately 1,000 m was enriched in respired CO2and depleted in oxygen during the LGM. The presence of authigenic Mn enrichment in the deep Equatorial Pacific for each of the last five deglaciations suggests that the storage of respired CO2in the deep ocean is a ubiquitous feature of late‐Pleistocene ice ages.
Changes in the circulation of the Southern Ocean are known to have impacted global nutrient, heat, and carbon cycles during the glacial and interglacial periods of the late Pleistocene. Proxy‐based records of these changes deserve continued scrutiny as the implications may be important for constraining future change. A record of authigenic uranium from the South Atlantic has been used to infer changes in deep‐sea oxygenation and organic matter export over the past 0.5 million years. Since sedimentary uranium has the possible complication of remobilization, it is prudent to investigate the behavior of other redox‐sensitive trace metals to confidently interpret temporal changes in oxygenation. Focusing here on the exceptionally long interglacial warm period, Marine Isotope Stage (MIS) 11, we found concurrent authigenic enrichments of uranium (U) and rhenium (Re) throughout MIS 12 to 10, overall supporting prior interpretations of low‐oxygen periods. However, there are differential responses of Re and U to oxygen changes and some evidence of small‐scale Re remobilization, which may involve differences in molecular‐level reduction mechanisms. Peaks in authigenic manganese (Mn) intervening with peaks in Re and U indicate increases in porewater oxygenation which likely relate to increased Antarctic Bottom Water circulation at the onset of MIS11c and during the peak warmth of the interglacial around 400 ka.
more » « less- Award ID(s):
- 1658445
- NSF-PAR ID:
- 10367037
- Publisher / Repository:
- DOI PREFIX: 10.1029
- Date Published:
- Journal Name:
- Geochemistry, Geophysics, Geosystems
- Volume:
- 22
- Issue:
- 8
- ISSN:
- 1525-2027
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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