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1. The Geochemistry of Englacial Brine From Taylor Glacier, Antarctica

   https://doi.org/10.1029/2018JG004411  

   Lyons, W. Berry; Mikucki, Jill A.; German, Laura A.; Welch, Kathleen A.; Welch, Susan A.; Gardner, Christopher B.; Tulaczyk, Slawek M.; Pettit, Erin C.; Kowalski, Julia; Dachwald, Bernd (March 2019, Journal of Geophysical Research: Biogeosciences)

   Abstract Blood Falls is a hypersaline, iron‐rich discharge at the terminus of the Taylor Glacier in the McMurdo Dry Valleys, Antarctica. In November 2014, brine in a conduit within the glacier was penetrated and sampled using clean‐entry techniques and a thermoelectric melting probe called the IceMole. We analyzed the englacial brine sample for filterable iron (fFe), total Fe, major cations and anions, nutrients, organic carbon, and perchlorate. In addition, aliquots were analyzed for minor and trace elements and isotopes including δD and δ¹⁸O of water, δ³⁴S and δ¹⁸O of sulfate,²³⁴U,²³⁸U, δ¹¹B,⁸⁷Sr/⁸⁶Sr, and δ⁸¹Br. These measurements were made in order to (1) determine the source and geochemical evolution of the brine and (2) compare the chemistry of the brine to that of nearby hypersaline lake waters and previous supraglacially sampled collections of Blood Falls outflow that were interpreted asend‐memberbrines. The englacial brine had higher Cl⁻concentrations than the Blood Falls end‐member outflow; however, other constituents were similar. The isotope data indicate that the water in the brine is derived from glacier melt. The H₄SiO₄concentrations and U and Sr isotope suggest a high degree of chemical weathering products. The brine has a low N:P ratio of ~7.2 with most of the dissolved inorganic nitrogen in the form of NH₄⁺. Dissolved organic carbon concentrations are similar to end‐member outflow values. Our results provide strong evidence that the original source of solutes in the brine was ancient seawater, which has been modified with the addition of chemical weathering products. 

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2. Geochemical Evolution of Eocene Lakes in the Nevada Hinterland of the North American Cordillera

   https://doi.org/10.1029/2021GC009863  

   Canada, Andrew S.; Cassel, Elizabeth J.; Smith, M. Elliot (October 2021, Geochemistry, Geophysics, Geosystems)

   Abstract Eocene strata of the Elko Formation record lacustrine deposition within the Nevada hinterland of the North American Cordillera. We present a detailed geochemical stratigraphy enabled by high‐sampling‐resolution geochronology from lacus trine limestone and interbedded volcanic rocks of the Elko Formation. Two intervals of lacustrine deposition, an early Eocene “Lake Adobe” of limited aerial extent and a laterally extensive middle Eocene “Lake Elko,” are separated by ∼5 m.y. of apparent unconformity. Sediments deposited in the apparently short‐lived (49.5–48.5 Ma) early Eocene Lake Adobe exhibit high‐amplitude covariation of δ¹⁸O, δ¹³C and⁸⁷Sr/⁸⁶Sr, which suggests a dynamically changing catchment and precipitation regime. Lake Elko formed during the middle Eocene, and its strata record three geochemically distinct phases, indicating it was a single interconnected water body that became increasingly evaporative over time. The lower Elko Formation (44.0–42.5 Ma) was deposited in a freshwater lake. Middle Elko Formation (42.5–41.2 Ma) lithofacies and geochemistry suggest that an increasingly saline and alkaline Lake Elko experienced salinity stratification‐induced hypolimnion disoxia and burial of¹²C‐rich organic matter. The upper Elko Formation (41.2–40.5 Ma) records a shallow final phase of Lake Elko that experienced short residence times and a breakdown in stratification. A sharp decline of⁸⁷Sr/⁸⁶Sr in the upper Elko Formation reflects an increasing aerial extent of low‐⁸⁷Sr/⁸⁶Sr volcanic deposits from nearby calderas. Middle Eocene strata record ponding of paleodrainage, increasing hydrologic isolation and volcanism, consistent with progressive north to south removal of the Farallon flat slab and/or delamination of the lower lithospheric mantle of the North American plate. 

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3. Testing the Recycled Gabbro Hypothesis for the Origin of “Ghost Plagioclase” Melt Signatures Using ⁸⁷ Sr/ ⁸⁶ Sr of Individual Olivine‐Hosted Melt Inclusions From Hawai'i

   https://doi.org/10.1029/2020GC009260  

   Anderson, O. E.; Jackson, M. G.; Rose‐Koga, E. F.; Marske, J. P.; Peterson, M. E.; Price, A. A.; Byerly, B. L.; Reinhard, A. A. (April 2021, Geochemistry, Geophysics, Geosystems)

   Abstract Melt inclusions with large, positive Sr anomalies have been described in multiple tectonic settings, and the origins of this unusual geochemical feature are debated. Three origins have been proposed, all involving plagioclase as the source of the elevated Sr: (i) direct assimilation of plagioclase‐rich lithologies, (ii) recycled lower oceanic gabbro in the mantle source, and (iii) shallow‐level diffusive interaction between present day lower oceanic crust (i.e., plagioclase‐bearing lithologies) and the percolating melt. A “ghost plagioclase” signature (i.e., a large, positive Sr anomaly without associated high Al₂O₃) is present in melt inclusions from Mauna Loa. We present new⁸⁷Sr/⁸⁶Sr measurements of individual olivine‐hosted melt inclusions from three Hawaiian volcanoes, Mauna Loa, Loihi, and Koolau. The data set includes a Mauna Loa melt inclusion with the highest reported Sr anomaly (or highest (Sr/Ce)_N, which is 7.2) for Hawai'i. All melt inclusions have⁸⁷Sr/⁸⁶Sr values within the range reported previously for the lavas from each volcano. Critically, the⁸⁷Sr/⁸⁶Sr of the high (Sr/Ce)_Nmelt inclusion lies within the narrow range of⁸⁷Sr/⁸⁶Sr for Mauna Loa melts that lack high (Sr/Ce)_Nsignatures. Therefore, to explain the high (Sr/Ce)_Nratio of the ghost plagioclase signature using an ancient recycled gabbro, the gabbro‐infused mantle source would have had to evolve, by chance, to have the same⁸⁷Sr/⁸⁶Sr as the source of the Mauna Loa melts that lack a recycled gabbro (ghost plagioclase) signature. Alternatively, shallow‐level diffusive interactions between Mauna Loa plagioclase‐rich cumulates and a percolating mantle‐derived melt provides a simpler explanation for the presence of the high (Sr/Ce)_NMauna Loa melts. 

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4. A stalagmite test of North Atlantic SST and Iberian hydroclimate linkages over the last two glacial cycles

   https://doi.org/10.5194/cp-14-1893-2018  

   Denniston, Rhawn F.; Houts, Amanda N.; Asmerom, Yemane; Wanamaker Jr., Alan D.; Haws, Jonathan A.; Polyak, Victor J.; Thatcher, Diana L.; Altan-Ochir, Setsen; Borowske, Alyssa C.; Breitenbach, Sebastian F.; et al (January 2018, Climate of the Past)

   Abstract. Close coupling of Iberian hydroclimate and North Atlantic seasurface temperature (SST) during recent glacial periods has been identifiedthrough the analysis of marine sediment and pollen grains co-deposited on thePortuguese continental margin. While offering precisely correlatable records,these time series have lacked a directly dated, site-specific record ofcontinental Iberian climate spanning multiple glacial cycles as a point ofcomparison. Here we present a high-resolution, multi-proxy (growth dynamicsandδ¹³C, δ¹⁸O, and δ²³⁴Uvalues) composite stalagmite record of hydroclimate from two caves in westernPortugal across the majority of the last two glacial cycles (∼220ka).At orbital and millennial scales, stalagmite-based proxies for hydroclimateproxies covaried with SST, with elevated δ¹³C,δ¹⁸O, and δ²³⁴U values and/or growth hiatusesindicating reduced effective moisture coincident with periods of lowered SSTduring major ice-rafted debris events, in agreement with changes inpalynological reconstructions of continental climate. While in many cases thePortuguese stalagmite record can be scaled to SST, in some intervals themagnitudes of stalagmite isotopic shifts, and possibly hydroclimate, appearto have been somewhat decoupled from SST. 

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5. Origin of blocky aragonite cement in Cenozoic glaciomarine sediments, McMurdo Sound, Antarctica

   https://doi.org/10.1111/sed.12690  

   Yang, Mingyu; Frank, Tracy D.; Fielding, Christopher R.; Smith, Megan E.; Swart, Peter K.; Reijmer, ed., John (December 2019, Sedimentology)

   Abstract Inorganic aragonite occurs in a wide spectrum of depositional environments and its precipitation is controlled by complex physio‐chemical factors. This study investigates diagenetic conditions that led to aragonite cement precipitation in Cenozoic glaciomarine deposits of McMurdo Sound, Antarctica. A total of 42 sandstones that host intergranular cement were collected from theCIROS‐1 core, located proximal to the terminus of Ferrar Glacier. Standard petrography, Raman spectroscopy and electron microprobe analysis reveal a prominent aragonite cement phase that occurs as a pore‐filling blocky fabric throughout the core. Oxygen isotope compositions (δ¹⁸O = −30·0 to −8·6‰ Vienna Pee‐Dee Belemnite) and clumped isotope temperatures (TΔ₄₇ = 13·1 to 31·5°C) determined from the aragonite cements provide precise constraints on isotopic compositions (δ¹⁸O_w) of the parent fluid, which mostly range from −10·8 to −7·2‰ Vienna Standard Mean Ocean Water. The fluidδ¹⁸O_wvalues are consistent with those of pore water, previously identified as cryogenic brine in the nearbyAND‐2A core. Petrographic and geochemical data suggest that aragonite cement in theCIROS‐1 core precipitated from a similar brine. The brine likely formed and infiltrated sediments in flooded glacial valleys along the western margin of McMurdo Sound during the middle Miocene Climatic Transition, and subsequently flowed basinward in the subsurface. Consequently, the brine forms as a longstanding subsurface fluid that has saturated Cenozoic sediments below southern McMurdo Sound since at least the middle Miocene. Aragonite cementation in theCIROS‐1 core is interpreted to reflect its proximal position to sites of brine formation and greater likelihood of experiencing brines with sustained high carbonate saturation states and Mg/Ca ratios. This unusual occurrence expands the range of known natural occurrences of aragonite cement. Given the potential for cryogenic brine formation in glaciomarine settings, blocky aragonite, as the end member of the spectrum of aragonite cement morphology, may be more widespread in glaciomarine sediments than currently thought. 

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