Title: Enhanced efficiency of graded-bandgap thin-film solar cells due to concentrated sunlight
A systematic study was performed with a coupled optoelectronic model to examine the effect of the concentration of sunlight on the efficiencies of CIGS, CZTSSe and AlGaAs thin-film solar cells with a graded-bandgap absorber layer. Efficiencies of 34.6% for CIGS thin-film solar cells and 29.9% for CZTSSe thin-film solar cells are predicted with a concentration of 100 suns, the respective one-sun efficiencies being 27.7% and 21.7%. An efficiency of 36.7% is predicted for AlGaAs thin-film solar cells with a concentration of 60 suns, in comparison to 34.5% one-sun efficiency. Sunlight concentration does not affect the per-sun electron–hole-pair (EHP) generation rate but reduces the per-sun EHP recombination rate either near the front and back faces or in the graded-bandgap regions of the absorber layer, depending upon the semiconductor used for that layer, and this is the primary reason for the improvement in efficiency. Other effects include the enhancement of open-circuit voltage, which can be positively correlated to the higher short-circuit current density. Sunlight concentration can therefore play a significant role in enhancing the efficiency of thin-film solar cells. more »« less
Ahmad, Faiz; Civiletti, Benjamin J.; Monk, Peter B.; Lakhtakia, Akhlesh
(, Proc. SPIE 12477, International Workshop on Thin Films for Electronics, Electro-Optics, Energy and Sensors 2022)
Antireflection coatings are vital for reducing loss due to optical reflection in photovoltaic solar cells. A single-layer magnesium fluoride (MgF2) antireflection coating is usually used in thin- film CIGS solar cells. According to optics, this coating can be effective only for a narrow spec- tral regime. Further reduction of reflection loss may require an optimal single-layer or multi-layer coating. Hence, we optimized the refractive indices and thicknesses of single- and double-layer an- tireflection coatings for CIGS solar cells containing a CIGS absorber layer with: (i) homogeneous bandgap, (ii) linearly graded bandgap, or (iii) nonlinearly graded bandgap. A relative enhancement of up to 1.83% is predicted with an optimal double-layer antireflection coating compared to the efficiency with a single-layer antireflection coating.
Ahmad, Faiz; Monk, Peter B.; Lakhtakia, Akhlesh
(, Journal of Physics: Energy)
Abstract The building sector accounts for 36% of energy consumption and 39% of energy-related greenhouse-gas emissions. Integrating bifacial photovoltaic solar cells in buildings could significantly reduce energy consumption and related greenhouse gas emissions. Bifacial solar cells should be flexible, bifacially balanced for electricity production, and perform reasonably well under weak-light conditions. Using rigorous optoelectronic simulation software and the differential evolution algorithm, we optimized symmetric/asymmetric bifacial CIGS solar cells with either (i) homogeneous or (ii) graded-bandgap photon-absorbing layers and a flexible central contact layer of aluminum-doped zinc oxide to harvest light outdoors as well as indoors. Indoor light was modeled as a fraction of the standard sunlight. Also, we computed the weak-light responses of the CIGS solar cells using LED illumination of different light intensities. The optimal bifacial CIGS solar cell with graded-bandgap photon-absorbing layers is predicted to perform with 18%–29% efficiency under 0.01–1.0-Sun illumination; furthermore, efficiencies of 26.08% and 28.30% under weak LED light illumination of 0.0964 mW cm−2and 0.22 mW cm−2intensities, respectively, are predicted.
In Part I [Appl. Opt.59,1018(2020).APOPAI0003-693510.1364/AO.381246], we used a coupled optoelectronic model to optimize a thin-film AlGaAs solar cell with a graded-bandgap photon-absorbing layer and a periodically corrugated Ag backreflector combined with localized ohmic Pd–Ge–Au backcontacts, because both strategies help to improve the performance of AlGaAs solar cells. However, the results in Part I were affected by a normalization error, which came to light when we replaced the hybridizable discontinuous Galerkin scheme for electrical computation by the faster finite-difference scheme. Therefore, we re-optimized the solar cells containing ann-AlGaAs photon-absorbing layer with either a (i) homogeneous, (ii) linearly graded, or (iii) nonlinearly graded bandgap. Another way to improve the power conversion efficiency is by using a surface antireflection texturing on the wavelength scale, so we also optimized four different types of 1D periodic surface texturing: (i) rectangular, (ii) convex hemi-elliptical, (iii) triangular, and (iv) concave hemi-elliptical. Our new results show that the optimal nonlinear bandgap grading enhances the efficiency by as much as 3.31% when then-AlGaAs layer is 400 nm thick and 1.14% when that layer is 2000 nm thick. A hundredfold concentration of sunlight can enhance the efficiency by a factor of 11.6%. Periodic texturing of the front surface on the scale of 0.5–2 free-space wavelengths provides a small relative enhancement in efficiency over the AlGaAs solar cells with a planar front surface; however, the enhancement is lower when then-AlGaAs layer is thicker.
In Part I [Appl. Opt.58,6067(2019)APOPAI003-693510.1364/AO.58.006067], we used a coupled optoelectronic model to optimize a thin-film (CIGS) solar cell with a graded-bandgap photon-absorbing layer and a periodically corrugated backreflector. The increase in efficiency due to the periodic corrugation was found to be tiny and that, too, only for very thin CIGS layers. Also, it was predicted that linear bandgap-grading enhances the efficiency of the CIGS solar cells. However, a significant improvement in solar cell efficiency was found using a nonlinearly (sinusoidally) graded-bandgap CIGS photon-absorbing layer. The optoelectronic model comprised two submodels: optical and electrical. The electrical submodel applied the hybridizable discontinuous Galerkin (HDG) scheme directly to equations for the drift and diffusion of charge carriers. As our HDG scheme sometimes fails due to negative carrier densities arising during the solution process, we devised a new, to the best of our knowledge, computational scheme using the finite-difference method, which also reduces the overall computational cost of optimization. An unfortunate normalization error in the electrical submodel in Part I came to light. This normalization error did not change the overall conclusions reported in Part I; however, some specifics did change. The new algorithm for the electrical submodel is reported here along with updated numerical results. We re-optimized the solar cells containing a CIGS photon-absorbing layer with either (i) a homogeneous bandgap, (ii) a linearly graded bandgap, or (iii) a nonlinearly graded bandgap. Considering the meager increase in efficiency with the periodic corrugation and additional complexity in the fabrication process, we opted for a flat backreflector. The new algorithm is significantly faster than the previous algorithm. Our new results confirm efficiency enhancement of 84% (resp. 63%) when the thickness of the CIGS layer is 600 nm (resp. 2200 nm), similarly to Part I. A hundredfold concentration of sunlight can increase the efficiency by an additional 27%. Finally, the currently used 110-nm-thick layer of performs almost as well as optimal single- and double-layer antireflection coatings.
In Parts I [Appl. Opt.58,6067(2019)APOPAI0003-693510.1364/AO.58.006067] and II [Appl. Opt.61,10049(2022)APOPAI0003-693510.1364/AO.474920], we used a coupled optoelectronic model to optimize a thin-film CIGS solar cell with a graded-bandgap photon-absorbing layer, periodically corrugated backreflector, and multilayered antireflection coatings. Bandgap grading of the CIGS photon-absorbing layer was continuous and either linear or nonlinear, in the thickness direction. Periodic corrugation and multilayered antireflection coatings were found to engender slight improvements in the efficiency. In contrast, bandgap grading of the CIGS photon-absorbing layer leads to significant enhancement of efficiency, especially when the grading is continuous and nonlinear. However, practical implementation of continuous nonlinear grading is challenging compared to piecewise-homogeneous grading. Hence, for this study, we investigated piecewise-homogeneous approximations of the optimal linear and nonlinear grading profiles, and found that an equivalent efficiency is achieved using piecewise-homogeneous grading. An efficiency of 30.15% is predicted with a three-layered piecewise-homogeneous CIGS photon-absorbing layer. The results will help experimentalists to implement optimal designs for highly efficient CIGS thin-film solar cells.
Ahmad, Faiz, Lakhtakia, Akhlesh, and Monk, Peter_B. Enhanced efficiency of graded-bandgap thin-film solar cells due to concentrated sunlight. Applied Optics 60.34 Web. doi:10.1364/AO.442590.
Ahmad, Faiz, Lakhtakia, Akhlesh, and Monk, Peter_B.
"Enhanced efficiency of graded-bandgap thin-film solar cells due to concentrated sunlight". Applied Optics 60 (34). Country unknown/Code not available: Optical Society of America. https://doi.org/10.1364/AO.442590.https://par.nsf.gov/biblio/10369553.
@article{osti_10369553,
place = {Country unknown/Code not available},
title = {Enhanced efficiency of graded-bandgap thin-film solar cells due to concentrated sunlight},
url = {https://par.nsf.gov/biblio/10369553},
DOI = {10.1364/AO.442590},
abstractNote = {A systematic study was performed with a coupled optoelectronic model to examine the effect of the concentration of sunlight on the efficiencies of CIGS, CZTSSe and AlGaAs thin-film solar cells with a graded-bandgap absorber layer. Efficiencies of 34.6% for CIGS thin-film solar cells and 29.9% for CZTSSe thin-film solar cells are predicted with a concentration of 100 suns, the respective one-sun efficiencies being 27.7% and 21.7%. An efficiency of 36.7% is predicted for AlGaAs thin-film solar cells with a concentration of 60 suns, in comparison to 34.5% one-sun efficiency. Sunlight concentration does not affect the per-sun electron–hole-pair (EHP) generation rate but reduces the per-sun EHP recombination rate either near the front and back faces or in the graded-bandgap regions of the absorber layer, depending upon the semiconductor used for that layer, and this is the primary reason for the improvement in efficiency. Other effects include the enhancement of open-circuit voltage, which can be positively correlated to the higher short-circuit current density. Sunlight concentration can therefore play a significant role in enhancing the efficiency of thin-film solar cells.},
journal = {Applied Optics},
volume = {60},
number = {34},
publisher = {Optical Society of America},
author = {Ahmad, Faiz and Lakhtakia, Akhlesh and Monk, Peter_B},
}
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