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Abstract Dwarf galaxies are found to have lost most of their metals via feedback processes; however, there still lacks consistent assessment on the retention rate of metals in their circumgalactic medium (CGM). Here we investigate the metal content in the CGM of 45 isolated dwarf galaxies withM*= 106.5–9.5M⊙(M200m= 1010.0–11.5M⊙) using the Hubble Space Telescope/Cosmic Origins Spectrograph. While Hi(Lyα) is ubiquitously detected (89%) within the CGM, we find low detection rates (≈5%–22%) in Cii, Civ, Siii, Siiii, and Siiv, largely consistent with literature values. Assuming these ions form in the cool (T≈ 104K) CGM with photoionization equilibrium, the observed Hiand metal column density profiles can be best explained by an empirical model with low gas density and high volume filling factor. For a typical galaxy withM200m= 1010.9M⊙(median of the sample), our model predicts a cool gas mass ofMCGM,cool∼ 108.4M⊙, corresponding to ∼2% of the galaxy’s baryonic budget. Assuming a metallicity of 0.3 Z⊙, we estimate that the dwarf galaxy’s cool CGM likely harbors ∼10% of the metals ever produced, with the rest either in more ionized states in the CGM or transported to the intergalactic medium. We further examine the EAGLE simulation and show that Hiand low ions may arise from a dense cool medium, while Civarises from a diffuse warmer medium. Our work provides the community with a uniform data set on dwarf galaxies’ CGM that combines our recent observations, additional archival data and literature compilation, which can be used to test various theoretical models of dwarf galaxies.
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A Sensor Array for the Ultrasensitive Discrimination of Heavy Metal Pollutants in Seawater
Abstract Metal cations are potent environmental pollutants that negatively impact human health and the environment. Despite advancements in sensor design, the simultaneous detection and discrimination of multiple heavy metals at sub‐nanomolar concentrations in complex analytical matrices remain a major technological challenge. Here, the design, synthesis, and analytical performance of three highly emissive conjugated polyelectrolytes (CPEs) functionalized with strong iminodiacetate and iminodipropionate metal chelates that operate in challenging environmental samples such as seawater are demonstrated. When coupled with array‐based sensing methods, these polymeric sensors discriminate among nine divalent metal cations (CuII, CoII, NiII, MnII, FeII, ZnII, CdII, HgII, and PbII). The unusually high and robust luminescence of these CPEs enables unprecedented sensitivity at picomolar concentrations in water. Unlike previous array‐based sensors for heavy metals using CPEs, the incorporation of distinct π‐spacer units within the polymer backbone affords more pronounced differences in each polymer's spectroscopic behavior upon interaction with each metal, ultimately producing better analytical information and improved differentiation. To demonstrate the environmental and biological utility, a simple two‐component sensing array is showcased that can differentiate nine metal cation species down to 500 × 10−12 min aqueous media and to 100 × 10−9 min seawater samples collected from the Gulf of Mexico.
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- Award ID(s):
- 1632825
- PAR ID:
- 10369770
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Advanced Functional Materials
- Volume:
- 32
- Issue:
- 33
- ISSN:
- 1616-301X
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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