Most ionospheric models cannot sufficiently reproduce the observed electron density profiles in the E‐region ionosphere, since they usually underestimate electron densities and do not match the profile shape. Mitigation of these issues is often addressed by increasing the solar soft X‐ray flux which is ineffective for resolving data‐model discrepancies. We show that low‐resolution cross sections and solar spectral irradiances fail to preserve structure within the data, which considerably impacts radiative processes in the E‐region, and are largely responsible for the discrepancies between observations and simulations. To resolve data‐model inconsistencies, we utilize new high‐resolution (0.001 nm) atomic oxygen (O) and molecular nitrogen (N2) cross sections and solar spectral irradiances, which contain autoionization and narrow rotational lines that allow solar photons to reach lower altitudes and increase the photoelectron flux. This work improves upon Meier et al. (2007,
Recent work has indicated the presence of a nitric oxide (NO) product channel in the reaction between the higher vibrational levels of the first electronically excited state of molecular nitrogen, N2(A
- NSF-PAR ID:
- 10374561
- Publisher / Repository:
- DOI PREFIX: 10.1029
- Date Published:
- Journal Name:
- Journal of Geophysical Research: Space Physics
- Volume:
- 125
- Issue:
- 1
- ISSN:
- 2169-9380
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Abstract https://doi.org/10.1029/2006gl028484 ) by additionally incorporating high‐resolution N2photoionization and photoabsorption cross sections in model calculations. Model results with the new inputs show increased O+production rates of over 500%, larger than those of Meier et al. (2007,https://doi.org/10.1029/2006gl028484 ) and total ion production rates of over 125%, while production rates decrease by ∼15% in the E‐region in comparison to the results obtained using the cross section compilation from Conway (1988,https://apps.dtic.mil/sti/pdfs/ADA193866.pdf ). Low‐resolution molecular oxygen (O2) cross sections from the Conway compilation are utilized for all input cases and indicate that is a dominant contributor to the total ion production rate in the E‐region. Specifically, the photoionization contributed from longer wavelengths is a main contributor at ∼120 km. -
Abstract We have analyzed medium‐resolution (full width at half maximum, FWHM = 1.2 nm), Middle UltraViolet (MUV; 180–280 nm) laboratory emission spectra of carbon monoxide (CO) excited by electron impact at 15, 20, 40, 50, and 100 eV under single‐scattering conditions at 300 K. The MUV emission spectra at 100 eV contain the Cameron Bands (CB) CO(a3Π → X1Σ+), the fourth positive group (4PG) CO(A1Π → X1Σ+), and the first negative group (1NG) CO+(B2Σ+→ X2Σ) from direct excitation and cascading‐induced emission of an optically thin CO gas. We have determined vibrational intensities and emission cross sections for these systems, important for modeling UV observations of the atmospheres of Mars and Venus. We have also measured the CB “glow” profile about the electron beam of the long‐lived CO (a3Π) state and determined its average metastable lifetime of 3 ± 1 ms. Optically allowed cascading from a host of triplet states has been found to be the dominant excitation process contributing to the CB emission cross section at 15 eV, most strongly by the d3Δ and a'3Σ+electronic states. We normalized the CB emission cross section at 15 eV electron impact energy by multilinear regression (MLR) analysis to the blended 15 eV MUV spectrum over the spectral range of 180–280 nm, based on the 4PG emission cross section at 15 eV that we have previously measured (Ajello et al., 2019,
https://doi.org/10.1029/2018ja026308 ). We find the CB total emission cross section at 15 eV to be 7.7 × 10−17 cm2. -
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