skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Evaluation of Geopolymer for Stabilization of Sulfate-Rich Expansive Soils for Supporting Pavement Infrastructure
Stabilization of sulfate-rich expansive subgrade soils is a persistent cause of concern for transportation infrastructure engineers and practitioners. The application of traditional calcium-based stabilizers is generally not recommended for treating such soils because of the formation of deleterious reaction products such as ettringite. Sulfate-induced heaving causes severe structural damage to pavements and accounts for enormous expenditure from routine maintenance and rehabilitation activities. A research study was undertaken to evaluate the feasibility of using a metakaolin-based geopolymer (GP) for the treatment of sulfate-rich expansive soil. Laboratory studies were conducted on natural soil and artificially sulfate-rich soils, when treated with either lime or GP, to evaluate and compare the improvements in the engineering properties, including unconfined compressive strength, swelling and shrinkage, and resilient moduli characteristics over different curing periods. Microstructural studies, such as field emission scanning electron microscopy and X-ray diffraction, were performed on treated soils to detect the formation of reaction products. The engineering studies indicate that GP treatment enhanced strength and resilient moduli while suppressing ettringite formation and the associated swell–shrink potential of the treated soils. The microstructural studies showed that GP gels contribute to the improvement of these engineering properties through the formation of a uniform geopolymer matrix. In addition, the absence of a calcium source suppressed the formation of ettringite in the GP-treated soils. Overall, the findings indicate that GPs could be used as a potential alternative to existing traditional stabilizers for treating sulfate-rich expansive soils.  more » « less
Award ID(s):
2017796
PAR ID:
10380414
Author(s) / Creator(s):
; ; ; ; ;
Date Published:
Journal Name:
Transportation Research Record: Journal of the Transportation Research Board
Volume:
2676
Issue:
9
ISSN:
0361-1981
Page Range / eLocation ID:
230 to 245
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Subgrade treatment has traditionally been achieved using calcium-based cement. However, it does not necessarily enhance sustainable design. Recently, low-carbon alternatives such as portland limestone cement (PLC) have gained attention as substitutes for traditional cement. In addition, recycled concrete aggregate fines (fRCA), a waste product, have shown potential for application in transportation infrastructure because of their enhancements in pavements. This study investigates the effectiveness of PLC and fRCA in improving soil properties under different environmental stressors. Clayey soil was treated with PLC (10% PLC or 10C) and PLC-fRCA mixtures at different ratios (8% PLC/15% fRCA or 8C_15fRCA and 8% PLC/30% fRCA or 8C_30fRCA). Improvements in strength, stiffness, and volumetric changes were evaluated through unconfined compressive strength and repeated load triaxial tests after exposure to various environmental conditioning cycles (0, 6, and 12 cycles of wet–dry or freeze–thaw) in the laboratory. Results indicated that untreated soil collapsed within two cycles of environmental conditioning. In contrast, treated soils exhibited significant improvements in strength and resilience to environmental stressors. Stiffness also improved with treatment, and despite some reduction after exposure to environmental conditioning, treated specimens maintained relatively higher stiffness values. These enhancements are attributed to the formation of strong binding gels from hydration and secondary reactions among PLC, fRCA, and soil, which exhibit strong resistance to moisture intrusion, helping to preserve their engineering properties. Overall, this study provides a comprehensive understanding of the potential of using fRCA as a co-additive to PLC, offering a more sustainable and durable alternative for the long-term performance of transportation infrastructures. 
    more » « less
  2. Biocementation is a biomediated ground improvement method that can improve the engineering behavior of granular soils through the precipitation of calcium carbonate minerals. Although cemented bonds and particle coatings generated from biocementation can enable large increases in soil initial shear stiffness, peak shear strength, and liquefaction resistance; emerging strategies such as soil desaturation have shown the ability of alternative mechanisms to enable large improvements in liquefaction behaviors. This article highlights outcomes from recent experiments which have investigated the potential of novel treatment processes to enable the generation and entrapment of gases within biocementation. We hypothesize that these entrapped gases may provide a secondary mechanism to improve soil undrained shearing behaviors by enabling the release of gases following cemented bond deterioration and related increases in pore fluid compressibility. Our study employs a series of batch experiments to identify new methods to both generate and entrap gasses within an organic polymer layer applied intermittently between biocementation treatments. Biocemented composites resulting from this work may enable large improvements in the environmental and financial efficacy of biocementation and the resilience of treated soils to extreme loading events. 
    more » « less
  3. This study reports on the self-healing capability of a strain-hardening fiber reinforced geopolymer composite, named Engineered Geopolymer Composite (EGC). EGC specimens were first uniaxially loaded to a tensile strain of 1%. The cracked specimens were then subjected to three different conditioning regimes: air curing, water curing, and no curing (i.e. reloading right after the preloading). Stiffness reduction was measured for each series by comparing the initial stiffness of intact specimens and the residual stiffness of the cracked specimens. In the water-cured specimens, white precipitates were observed in microcracks formed by preloading. Experimental results of the series showed significant stiffness recovery for low stress levels in the range of 0.5 – 1.0 MPa. Self-healing products observed by using a scanning electron microscope were mostly angular, stone-like substance. An analysis of energy dispersive spectroscopy showed that the healing products were relatively rich in silicon (Si) and aluminium (Al) and had lower concentration of calcium (Ca), compared to the geopolymer matrix phase. This implies that main product of EGC self-healing is unlikely to be either calcite (CaCO3) or salt deposits such as Na2CO3, but rather a formation of some aluminosilicate compounds. This study provides a baseline for further investigations into the development of geopolymer composites with robust self-healing. 
    more » « less
  4. This paper presents a novel laboratory experiment that can be incorporated into introductory soil mechanics courses to introduce students to the field of biogeotechnical engineering and the use of biostimulated microbially induced calcite precipitation (MICP). Applying MICP to granular soils results in an increase in peak strength and shear stiffness of the soil as a result of the precipitation of calcium carbonate on soil particle surfaces and at soil particle contacts. The authors developed protocols to treat small volumes of soil and to test the effectiveness of the treatment using a simple strength test based on ASTM D3967-16. In fall 2020, the experiment was piloted as a four-week, course-based research experience that can be conducted by students remotely or in a traditional laboratory environment. This paper provides an introduction to MICP and describes the protocols for conducting the experiment. The paper also suggests approaches for how the experiment can be incorporated into a traditional introductory soil mechanics course. 
    more » « less
  5. To promote the sustainable development of eco-efficient calcium sulfoaluminate (CSA) cements through the partial replacement of the CSA clinker with supplementary cementitious waste products, the effects of coal fly ashes on the early-age and mature-age properties of a calcium sulfoaluminate (CSA)-based cement paste were investigated. The impacts of both Class C and Class F fly ashes on the rheological properties, hydration kinetics, and compressive strength development of CSA cement paste were studied. Rheology-based workability parameters, representing the rate of loss of flowability, the rate of hardening, and the placement limit, were characterized for the pastes prepared with fixed water-to-cement (w/c) and fixed water-to-binder (w/b) ratios. The results indicate a slight improvement in the workability of the CSA paste by fly ash addition at a fixed w/b ratio. The isothermal calorimetry studies show a higher heat of hydration for the Class C fly ash-modified systems compared to the Class F-modified systems. The results show that fly ash accelerates the hydration of the calcium sulfoaluminate cement pastes, chiefly due to the filler effects, rather than the pozzolanic effects. In general, ettringite is stabilized more by the addition of Class F fly ash than Class C fly ash. Both fly ashes reduced the 1-day compressive strength, but increased the 28-day strength of the CSA cement paste; meanwhile, the Class C modified pastes show a higher strength than Class F, which is attributed to the higher degree of reaction and potentially more cohesive binding C-S-H-based gels formed in the Class C fly ash modified systems. The results provide insights that support that fly ash can be employed to improve the performance of calcium sulfoaluminate cement pastes, while also enhancing cost effectiveness and sustainability. 
    more » « less