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Aqueous redox flow batteries using low-cost organic and inorganic active materials have received growing interest for sustainable energy storage. In this study, a low-cost, high redox potential (1.08 V vs. NHE) and high capacity ammonium bromide (NH 4 Br, 214.4 A h L −1 ) catholyte was coupled with an organic viologen anolyte to demonstrate 1.51 V high voltage (SPr) 2 V/Br − aqueous redox flow batteries under pH neutral conditions for the first time. Benefitting from the high water solubility of both the NH 4 Br catholyte and (SPr) 2 V anolyte, the newly designed (SPr) 2 V/Br − organic flow battery was operated at up to 1.5 M and an energy density of up to 30.4 W h L −1 . Using multiwall carbon nanotubes as an electrochemical additive for the Br 3 − /Br − redox couple, the highly energy dense (SPr) 2 V/Br − flow battery manifested outstanding current performance, up to 78% energy efficiency at 40 mA cm −2 current density and 227 mW cm −2 power density, the highest power density known for pH neutral organic flow batteries.
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Two‐Dimensional MXene as a Nanofluidic Anolyte Additive for Enhancing Performance of Vanadium Redox Flow Batteries
Abstract In this work, Ti3C2TxMXene was investigated as a nanofluidic anolyte additive in vanadium redox flow batteries to improve the sluggish kinetics of V2+/V3+redox reaction. Numerous electrochemical tests under flow and static conditions were performed to demonstrate the effectiveness of MXenes for VRFB applications. Pressure drop tests and morphology analysis were also conducted to better understand the hydraulic effects of MXene addition into the anolyte. The nanofluidic anolytes with the concentration of 0.10 and 0.15 wt% showed the best electrochemical performance, although the former induced less aggravated hydraulic effects within a reasonable pressure drop range. At a current density of 200 mA cm−2, the nanofluidic analyte containing 0.10 wt% MXene was able to utilize 67 % of the theoretical capacity. Contrarily, with the pristine anolyte, only 10 % of the theoretical capacity could be utilized due to excessive losses. Moreover, the energy efficiency up to 74 % is observed for the nanofluidic electrolyte, which is an increase of 25 % compared to the pristine anolyte. Primarily, the enhanced battery performance was attributed to the improved electrocatalytic activity towards the anodic V2+/V3+redox reaction. Furthermore, a dynamic, web‐like, flowing electrode network is shown to increase the mass transport capacity of porous carbon felt electrodes by creating additional, abundant, and electrochemically active surfaces within the pores.
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- Award ID(s):
- 2034108
- PAR ID:
- 10384621
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Batteries & Supercaps
- Volume:
- 5
- Issue:
- 12
- ISSN:
- 2566-6223
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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