Abstract Glacierized coastal catchments of the Gulf of Alaska (GoA) are undergoing rapid hydrologic fluctuations in response to climate change. These catchments deliver dissolved and suspended inorganic and organic matter to nearshore marine environments, however, these glacierized coastal catchments are relatively understudied and little is known about total solute and particulate fluxes to the ocean. We present hydrologic, physical, and geochemical data collected during April–October 2019–2021 from 10 streams along gradients of glacial fed to non‐glacial (i.e., precipitation) fed, in one Southcentral and one Southeast Alaska region. Hydrologic data reveal that glaciers drive the seasonal runoff patterns. The ẟ18O signature and specific conductance show distinctive seasonal variations in stream water sources between the study regions apparently due to the large amounts of rain in Southeast Alaska. Total dissolved solids concentrations and yields were elevated in the Southcentral region, due to lithologic influence on dissolved loads, however, the hydroclimate is the primary driver of the timing of dissolved and suspended yields. We show the yields of dissolved organic carbon is higher and that the δ13CPOCis enriched in the Southeast streams illustrating contrasts in organic carbon export across the GoA. Finally, we illustrate how future yields of solutes and sediments to the GoA may change as watersheds evolve from glacial influenced to precipitation dominated. This integrated analysis provides insights into how watershed characteristics beyond glacier coverage control properties of freshwater inputs to the GoA and the importance of expanding study regions to multiple hydroclimate regimes. 
                        more » 
                        « less   
                    
                            
                            Concentration‐Discharge Patterns Across the Gulf of Alaska Reveal Geomorphological and Glacierization Controls on Stream Water Solute Generation and Export
                        
                    
    
            Abstract High‐latitude glacierized coastal catchments of the Gulf of Alaska (GoA) are undergoing rapid hydrologic changes in response to climate change and glacial recession. These catchments deliver important nutrients in the form of both inorganic and organic matter to the nearshore marine environment, yet are relatively understudied with respect to characterization of the sediment and solute generation processes and total yields. Using multiple linear regression informed by Bayesian Information Criterion analysis we empirically demonstrate how watershed characteristics affect suspended sediment and solute generation as represented by concentration‐discharge relationships. We find that watershed mean slope and relief control solute generation and that solute yields are influenced most by glacier coverage. We contribute a new flux and concentration‐discharge based conceptualization for understanding solute cycles across a hydroclimatic gradient of GoA watersheds that can be used to better understand future watershed responses to rapid hydrologic change. 
        more » 
        « less   
        
    
                            - Award ID(s):
- 1757348
- PAR ID:
- 10385515
- Publisher / Repository:
- DOI PREFIX: 10.1029
- Date Published:
- Journal Name:
- Geophysical Research Letters
- Volume:
- 49
- Issue:
- 1
- ISSN:
- 0094-8276
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
- 
            
- 
            Solute concentrations in stream water vary with discharge in patterns that record complex feedbacks between hydrologic and biogeochemical processes. In a comparison of headwater catchments underlain by shale in Pennsylvania, USA (Shale Hills) and Wales, UK (Plynlimon), dissimilar concentration-discharge behaviors are best explained by contrasting landscape distributions of soil solution chemistry – especially dissolved organic carbon (DOC) – that have been established by patterns of vegetation. Specifically, elements that are concentrated in organic-rich soils due to biotic cycling (Mn, Ca, K) or that form strong complexes with DOC (Fe, Al) are spatially heterogeneous in pore waters because organic matter is heterogeneously distributed across the catchments. These solutes exhibit non-chemostatic "bioactive" behavior in the streams, and solute concentrations either decrease (Shale Hills) or increase (Plynlimon) with increasing discharge. In contrast, solutes that are concentrated in soil minerals and form only weak complexes with DOC (Na, Mg, Si) are spatially homogeneous in pore waters across each catchment. These solutes are chemostatic in that their stream concentrations vary little with stream discharge, likely because these solutes are released quickly from exchange sites in the soils during rainfall events. Differences in the hydrologic connectivity of organic-rich soils to the stream drive differences in concentration behavior between catchments. As such, in catchments where soil organic matter (SOM) is dominantly in lowlands (e.g., Shale Hills), bioactive elements are released to the stream early during rainfall events, whereas in catchments where SOM is dominantly in uplands (e.g., Plynlimon), bioactive elements are released later during rainfall events. The distribution of vegetation and SOM across the landscape is thus a key component for predictive models of solute transport in headwater catchments.more » « less
- 
            Abstract. Solute concentrations in stream water vary with discharge in patterns that record complex feedbacks between hydrologic and biogeochemical processes. In a comparison of three shale-underlain headwater catchments located in Pennsylvania, USA (the forested Shale Hills Critical Zone Observatory), and Wales, UK (the peatland-dominated Upper Hafren and forest-dominated Upper Hore catchments in the Plynlimon forest), dissimilar concentration–discharge (C–Q) behaviors are best explained by contrasting landscape distributions of soil solution chemistry – especially dissolved organic carbon (DOC) – that have been established by patterns of vegetation and soil organic matter (SOM). Specifically, elements that are concentrated in organic-rich soils due to biotic cycling (Mn, Ca, K) or that form strong complexes with DOC (Fe, Al) are spatially heterogeneous in pore waters because organic matter is heterogeneously distributed across the catchments. These solutes exhibit non-chemostatic behavior in the streams, and solute concentrations either decrease (Shale Hills) or increase (Plynlimon) with increasing discharge. In contrast, solutes that are concentrated in soil minerals and form only weak complexes with DOC (Na, Mg, Si) are spatially homogeneous in pore waters across each catchment. These solutes are chemostatic in that their stream concentrations vary little with stream discharge, likely because these solutes are released quickly from exchange sites in the soils during rainfall events. Furthermore, concentration–discharge relationships of non-chemostatic solutes changed following tree harvest in the Upper Hore catchment in Plynlimon, while no changes were observed for chemostatic solutes, underscoring the role of vegetation in regulating the concentrations of certain elements in the stream. These results indicate that differences in the hydrologic connectivity of organic-rich soils to the stream drive differences in concentration behavior between catchments. As such, in catchments where SOM is dominantly in lowlands (e.g., Shale Hills), we infer that non-chemostatic elements associated with organic matter are released to the stream early during rainfall events, whereas in catchments where SOM is dominantly in uplands (e.g., Plynlimon), these non-chemostatic elements are released later during rainfall events. The distribution of SOM across the landscape is thus a key component for predictive models of solute transport in headwater catchments.more » « less
- 
            Abstract Climate change is intensifying the Arctic hydrologic cycle, potentially accelerating the release of carbon and nutrients from permafrost landscapes to rivers. However, there are limited riverine flow and solute data of adequate frequency and duration to test how seasonality and catchment landscape characteristics influence production and transport of carbon and nutrients in Arctic river networks. We measured high frequency hydrochemical dynamics at the outlets of three headwater catchments in Arctic Alaska over 3 years. The catchments represent common Arctic landscapes: low‐gradient tundra, low‐gradient and lake‐influenced tundra, and high‐gradient alpine tundra. Using in‐situ spectrophotometers, we measured dissolved organic carbon (DOC) and nitrate (NO3−) concentrations at 15‐min intervals through the flow seasons of 2017, 2018, and 2019. These high‐frequency data allowed us to quantify concentration–discharge (C‐Q) responses during individual storm events across the flow season. Differences in C‐Q responses among catchments indicated strong landscape and seasonal controls on lateral DOC and NO3−flux. For the two low‐gradient tundra catchments, we observed consistent DOC enrichment (transport‐limitation) and NO3−dilution (source‐limitation) during flow events. Conversely, we found consistent NO3−enrichment and DOC dilution in the high‐gradient alpine catchment. Our analysis revealed how high flow events may contribute disproportionately to downstream export in these Arctic streams. Because the duration of the flow season is expected to lengthen and the intensity of Arctic storms are expected to increase, understanding how discharge and solute concentration are coupled is crucial to understanding carbon and nutrient dynamics in rapidly changing permafrost ecosystems.more » « less
- 
            Abstract Rock weathering impacts atmospheric CO2levels with silicate rock dissolution removing CO2,and carbonate dissolution, pyrite oxidation, and organic rock carbon oxidation producing CO2. Glacierization impacts the hydrology and geomorphology of catchments and glacier retreat due to warming can increase runoff and initiate landscape succession. To investigate the impact of these changes on catchment scale weathering CO2balances, we report monthly samples of solute chemistry and continuous discharge records for a sequence of glacierized watersheds draining into Kachemak Bay, Alaska. We partition solute and acid sources and estimate inorganic weathering CO2balances using an inverse geochemical mixing model. Furthermore, we investigated how solutes vary with discharge conditions utilizing a concentration‐runoff framework. We develop an analogous fraction‐runoff framework which allows us to investigate changes in weathering contributions at different flows. Fraction‐runoff relationships suggest kinetic limitations on all reactions in glacierized catchments, and only silicate weathering in less glacierized catchments. Using forest cover as a proxy for landscape age and stability, multiple linear regression shows that faster reactions (pyrite oxidation) contribute less to the solute load with increasing forest cover, whereas silicate weathering (slow reaction kinetics) contributes more. Overall, in glacierized catchments, we find elevated weathering fluxes at high runoff despite significant dilution effects. This makes flux estimates that account for dilution more important in glacierized catchments. Our findings quantify how glaciers modify the inorganic weathering CO2balance of catchments through hydrologic and geomorphic forcings, and support the previous hypothesis that deglaciation will be accompanied by a shift in inorganic weathering CO2balances.more » « less
 An official website of the United States government
An official website of the United States government 
				
			 
					 
					
