In the past decade, Huagapo and Pacupahuain Caves in the Central Peruvian Andes have become sources of speleothem oxygen isotope (δ18O) paleoclimate records. These studies identify the South American Summer Monsoon (SASM) as the main climate system controlling δ18O variability. While this interpretation is verified through inter-proxy record comparisons on millennial scales, interpretation of the high-resolution variability within these records is limited by a lack of modern proxy calibration studies at these sites. Here we present results from a modern cave monitoring study undertaken to address the controls on the δ18O values of precipitation at these sites and how surface and in-cave processes affect the δ18O value of speleothem calcite. Speleothem calcite δ18O values reflect an integrated signal of atmospheric processes (e.g., rainout, Raleigh distillation, upstream moisture recycling, changes in moisture source), evaporation and mixing during infiltration in the soil and epikarst, and in-cave processes such as degassing and evaporation. In consideration of these factors, we compare isotope trends in precipitation, cave drip water and modern farmed calcite from the two cave sites. We find that precipitationδ18O values during peak monsoon activity (January -February) shows considerable inter-annual variation with averages of -16.7‰ for 2020, -18.5‰ for 2021 and -13.8‰ in 2022. We investigate the source of this variability in regional atmospheric circulation patterns using weather station data and back trajectories. The mean annual precipitation (MAP) from outside Huagapo Cave is δ18O = -15.5+/- 6‰, while seasonal samples of drip water δ18O = -14.5+/- 1‰, are offset from MAP possibly due to evaporation during infiltration. Cave drip waterδ18O has low variability over inter-annual and seasonal timescales indicating homogenization in the epikarst. Using geochemical and sensor data (e.g. cave relative humidity, temperature, and drip rate) as inputs for a karst based forward model, we simulate modern speleothem δ18O to quantitatively assess the combined effects of hydroclimate processes integration to the isotope record.
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Rainwater isotopes in central Vietnam controlled by two oceanic moisture sources and rainout effects
Abstract The interpretation of palaeoclimate archives based on oxygen isotopes depends critically on a detailed understanding of processes controlling the isotopic composition of precipitation. In the summer monsoonal realm, like Southeast Asia, seasonally and interannually depleted oxygen isotope ratios in precipitation have been linked to the summer monsoon strength. However, in some regions, such as central Vietnam, the majority of precipitation falls outside the summer monsoon period. We investigate processes controlling stable isotopes in precipitation from central Vietnam by combining moisture uptake calculations with monthly stable isotope data observed over five years. We find that the isotopic seasonal cycle in this region is driven by a shift in moisture source from the Indian Ocean to the South China Sea. This shift is reflected in oxygen isotope ratios with low values (− 8 to − 10‰) during summer and high values during spring/winter (0 to − 3‰), while 70% of the annual rainfall occurs during autumn. Interannual changes in precipitation isotopes in central Vietnam are governed by the timing of the seasonal onset and withdrawal of the Intertropical Convergence Zone, which controls the amount of vapour contributed from each source.
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- Award ID(s):
- 1602947
- PAR ID:
- 10386611
- Date Published:
- Journal Name:
- Scientific Reports
- Volume:
- 10
- Issue:
- 1
- ISSN:
- 2045-2322
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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