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The δ18O of carbonate minerals that formed at Earth’s surface is widely used to investigate paleoclimates and paleo-elevations. However, a multitude of hydrologic processes can affect δ18O values, including mixing, evaporation, distillation of parent waters, and carbonate growth temperatures. We combined traditional carbon and oxygen isotope analyses with clumped (Δ47) and triple oxygen isotopes (Δ′17O) analyses in oyster shells (Acutostrea idriaensis) of the Goler Formation in southern California (USA) to obtain insights into surface temperatures and δ18O values of meteoric waters during the early Eocene hothouse climate. The Δ47-derived temperatures ranged from 9 °C to 20 °C. We found a correlation between the δ18O of growth water (δ18Ogw) (calculated using Δ47 temperatures and δ18O of carbonate) and the δ13C values of shells. The Δ′17O values of shell growth waters (0.006‰–0.013‰ relative to Vienna standard mean ocean water–standard light Antarctic precipitation [VSMOW-SLAP]) calculated from Δ′17O of carbonate (–0.087‰ to –0.078‰ VSMOW-SLAP) were lower than typical meteoric waters. These isotopic compositions are consistent with oyster habitation in an estuary. We present a new triple oxygen isotope mixing model to estimate the δ18O value of freshwater supplying the estuary (δ18Ofw). The reconstructed δ18Ofw of –11.3‰ to –14.7‰ (VSMOW) is significantly lower than the δ18Ogw of –4.4‰ to –9.9‰ that would have been calculated using “only” Δ47 and δ18O values of carbonate. This δ18Ofw estimate supports paleogeographic reconstructions of a Paleogene river fed by high-elevation catchments of the paleo–southern Sierra Nevada. Our study highlights the potential for paired Δ47 and Δ′17O analyses to improve reconstructions of meteoric water δ18O, with implications for understanding ancient climates and elevations.
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This content will become publicly available on June 1, 2026
Stable isotope composition of surface waters across the Pamir, Central Asia: Implications of precipitation seasonality
The Pamir range, located in Central Asia, mainly receives moisture from the mid-latitude westerlies, but its western side (i.e., Tajikistan Pamir) receives much of its precipitation in the winter and spring and its eastern side (i.e., Chinese Pamir) in the summer. Thus, the Pamir provides a natural laboratory to study the distribution of surface water stable isotopes across a large mountain range that ultimately receives moisture from one single source but has different precipitation seasonality regimes between its two sides. In this study, we present stable oxygen (δ18O) and hydrogen (δ2H) isotope data for 113 surface water samples from the Chinese Pamir. Our new data, along with previously published stable isotope data, show that the slope of the Chinese Pamir local meteoric water line is higher than that of the Global Meteoric Water Line (GMWL), and almost all of the data plot above the GMWL, implying that the Chinese Pamir surface waters have not experienced significant isotopic modification by evaporation. The Chinese Pamir surface waters have substantially higher δ18O and d-excess values and a steeper apparent δ18O lapse rate than surface water samples collected from the Tajikistan Pamir. We suggest that this contrast results from the shift in precipitation seasonality across the Pamir, with dominantly winter and springtime precipitation on the Tajikistan side and summertime precipitation on the Chinese side of the Pamir. This predominant summertime precipitation regime results in surface waters with high δ18O values in the Chinese Pamir. Further, this summertime moisture is dominantly convectively recycled moisture, resulting in high d-excess values in surface waters. The percentage of summertime moisture, which has high δ18O values, decreases west and with elevation in the Chinese Pamir, resulting in a steep apparent δ18O lapse rate of − 3.2 ‰/km. The importance of precipitation seasonality in modulating δ18O values across the Pamir suggests that proxy-derived records of past environments in the region must consider the mechanisms that today cause the seasonality contrast.
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- Award ID(s):
- 2316733
- PAR ID:
- 10589166
- Publisher / Repository:
- Elsevier
- Date Published:
- Journal Name:
- Journal of Hydrology
- Volume:
- 653
- Issue:
- C
- ISSN:
- 0022-1694
- Page Range / eLocation ID:
- 132815
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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