The ignition of plasmas in liquids has applications from medical instrumentation to manipulation of liquid chemistry. Formation of plasmas directly in a liquid often requires prohibitively large voltages to initiate breakdown. Producing plasma streamers in bubbles submerged in a liquid with higher permittivity can significantly lower the voltage needed to initiate a discharge by reducing the electric field required to produce breakdown. The proximity of the bubble to the electrodes and the shape of the bubbles play critical roles in the manner in which the plasma is produced in, and propagates through, the bubble. In this paper, we discuss results from a three-dimensional direct numerical simulation (DNS) used to investigate the shapes of bubbles formed by injection of air into water. Comparisons are made to results from a companion experiment. A two-dimensional plasma hydrodynamics model was then used to capture the plasma streamer propagation in the bubble using a static bubble geometry generated by the DNS The simulations showed two different modes for streamer formation depending on the bubble shape. In an elliptical bubble, a short electron avalanche triggered a surface ionization wave (SIWs) resulting in plasma propagating along the surface of the bubble. In a circular bubble, an electron avalanche first traveled through the middle of the bubble before two SIWs began to propagate from the point closest to the grounded electrode where a volumetric streamer intersected the surface. In an elliptical bubble approaching a powered electrode in a pin-to-pin configuration, we experimentally observed streamer behavior that qualitatively corresponds with computational results. Optical emission captured over the lifetime of the streamer curve along the path of deformed bubbles, suggesting propagation of the streamer along the liquid/gas boundary interface. Plasma generation supported by the local field enhancement of the deformed bubble surface boundaries is a mechanism that is likely responsible for initiating streamer formation.
Comparing Low-Mach and Fully-Compressible CFD Solvers for Phenomenological Modeling of Nanosecond Pulsed Plasma Discharges with and without Turbulence
This work aims at comparing the accuracy and overall performance of a low-Mach CFD solver and a fully-compressible CFD solver for direct numerical simulation (DNS) of nonequilibrium plasma assisted ignition (PAI) using a phenomenological model described in Castela et al. [1]. The phenomenological model describes the impact of nanosecond pulsed plasma discharges by introducing source terms in the reacting flow equations, instead of solving the detailed plasma kinetics at every time step of the discharge. Ultra-fast gas heating and dissociation ofO2 are attributed to the electronic excitation ofN2 and the subsequent quenching to ground state. This process is highly exothermic, and is responsible for dissociation of O2 to form O radicals; both of which promote faster ignition. Another relatively slower process of gas heating associated with vibrational-to-translational relaxation is also accounted for, by solving an additional vibrational energy transport equation. A fully-compressible CFD solver for high Mach (M>0.2) reacting flows, developed by extending the default rhoCentralFoam solver in OpenFOAM, is used to perform DNS of PAI in a 2D domain representing a cross section of a pin-to-pin plasma discharge configuration. The same case is also simulated using a low-Mach, pressure-based CFD solver, built by extending the default reactingFoam solver. The lack of flow or wave dominated transport after the plasma-induced weak shock wave leaves the domain causes inaccurate computation of all the transport variables, with a rather small time step dictated by the CFL condition, with the fully-compressible solver. These issues are not encountered in the low-Mach solver. Finally, the low-Mach solver is used to perform DNS of PAI in lean, premixed, isotropic turbulent mixtures of CH4-air at two different Reynolds numbers of 44 and 395. Local convection of the radicals and vibrational energy from the discharge domain, and straining of the high temperature reaction zones resulted in slower ignition of the case with the higher Re. A cascade effect of temperature reduction in the more turbulent case also resulted in a five - six times smaller value of the vibrational to translational gas heating source term, which further inhibited ignition. Two pulses were sufficient for ignition of the Re = 44 case, whereas three pulses were required for the Re = 395 case; consistent with the results of Ref. [1].
more »
« less
- Award ID(s):
- 2002635
- NSF-PAR ID:
- 10387572
- Date Published:
- Journal Name:
- AIAA Scitech 2022 Forum
- Page Range / eLocation ID:
- AIAA 2022-0976
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
more » « less
Abstract -
A robust and efficient framework for simulating NSPD in multiple dimensions is developed. The reactive Navier-Stokes equations are extended to include a drift-diffusion plasma-fluid model with a local field approximation (LFA) in a finite-volume solver, which uses an adaptive mesh refinement (AMR) strategy to address the wide separation of length scales in the problem. A two-way coupling strategy is used whereby the plasma-fluid model and reactive Navier-Stokes equations are integrated simultaneously. The oxidation of ethylene/air mixtures mediated by NSPD is simulated in a pin-to-pin configuration. All phases of the plasma discharge are simulated explicitly (including streamer ignition, propagation, and connection, as well as the subsequent spark phase), along with the evolution of the plasma during the inter-pulse period. Temporally and spatially-resolved results are presented, with an emphasis on the analysis of heating and energy deposition, as well as of the evolution of the concentration of active particles generated during the NSPD and their influence on ignition.more » « less
-
Nanosecond Pulsed High Frequency Discharges (NPHFD) are gaining popularity over conventional spark and arc discharges as they have been shown to increase energy efficiency, enhance ignition probability and sustained kernel growth, and offer more flexibility and control for ignition applications under various conditions. Hence, it is important to determine the impact of different factors such as the optimal pulse energy, background flow conditions, inter-pulse time, mixture equivalence ratio, etc. on the success of ignition of premixed mixtures with NPHFD. This work presents a numerical investigation of the morphology of ignition kernel development with both single-pulse and multiple-pulse discharges. Nanosecond non-equilibrium plasma discharges are modeled between pin-pin electrodes in a subsonic ignition tunnel with quiescent and flowing premixed mixtures of methane and air. Large eddy simulations (LES) are conducted to investigate the reasons for successful and failed ignition in different scenarios. A single pulse discharge in the presence of electrodes, in a quiescent medium, elucidates the gas recirculation pattern caused by the plasma pulse which results in a separated toroidal kernel from the primary ignition kernel between the electrodes. Convection heat loss to the mean flow results in quenching of the high temperature, radical-rich hot-spots creeping on the electrode walls, and leaving only the semi-toroidal kernel to propagate downstream. Finally, simulations with multiple pulses with different inter-pulse times have been conducted to analyze the synergistic effect of overlapping kernels with high temperature and OH concentration, which has been attributed as the primary reason for higher ignition probabilities in the “fully coupled” regime reported in the experiments. Successful ignition kernel formation is reported with 3 pulses at a pulse repetition frequency of 300 kHz in the fully coupled regime. This kernel volume was almost 4 times, and develops in two-thirds the time, compared to the ignition kernel volume formed by the single pulse discharge with the same total energy. Ten pulses with twice as much total energy were deposited at a much lower frequency of 2 kHz, which resulted in disjoint hot-spots that fail to form an ignition kernel in the decoupled regime.more » « less
-
Pepiot, Perrine (Ed.)The Global Pathway Analysis (GPA) algorithm helps analyze the chemical kinetics of complex combustion systems by identifying important global reaction pathways connecting a source species to a sink species through various important intermediate species (i.e., hub species). The present work aims to extend GPA algorithm to plasma-assisted combustion and fuel reforming systems to identify the dominant global pathways in such systems at various conditions. In addition, the present study extends the ability of GPA algorithm to identify reaction cycles involving the excitation of high-concentration species (e.g., O2, N2, and fuel) to their vibrational and electronic states and the subsequent de-excitation to their ground state, based on their significance on the reactivity of plasma-assisted systems in terms of gas heating and radical production. Provisions are made in the GPA algorithm to evaluate the reactivity of identified reaction pathways and cycles based on the element-flux transfer (i.e., dominance), heat release, and radical production rate. The newly developed Plasma-based Global Pathway Analysis (PGPA) algorithm is then used to analyze the plasma-assisted combustion of ammonia and reforming of methane. The PGPA analyses elucidated the significance of vibrational-translational cycles on the reactivity of NH3/air mixtures. Further, analyses on the production of NO ascribed the early reforming of NH3 to N2 and H2 in impeding the production of NO during plasma-assisted NH3 ignition. Lastly, the enhanced reforming of CH4/N2 mixtures using plasma has been attributed to electron impact dissociation of CH4 when compared to thermal reforming. In contrast, conventional path-Flux analysis (PFA) was found to require significant manual effort and pre-analysis intuitions from expert knowledge, making it arduous to provide valuable insights into plasma chemistry. The user-friendly and automated nature of PGPA thus provides a valuable tool for assessing the kinetics of plasma-assisted systems helpful in analyzing and, further, a foundation in reducing plasma-assisted chemistry, without the needs of expert knowledge.more » « less
-
A multi-dimensional model of the spark ignition process for SI engines was developed as a user defined function (UDF) integrated into the commercial engine simulation software CONVERGE CFD. The model simulates spark plasma movement in an inert flow environment without combustion. The UT model results were compared with experiments for arc movement in a crossflow and also compared with calorimeter measurements of thermal energy deposition under quiescent conditions. The arc motion simulation is based on a mean-free-path physical model to predict the arc movement given the contours of the crossflow velocity through the gap and the interaction of the spatially resolved electric field with the electrons making up the arc. A further development is the inclusion of a model for the thermal energy deposition of the arc as it is stretched by the interaction of the flow and the electric field. A novel feature of this model is that the thermal energy delivered to the gap at the start of the simulation is distributed uniformly along the arc rather than at discrete points along the arc, as is the case with the default CONVERGE CFD ignition models. This feature was found to greatly reduce the tendency of the arc to distort its shape and tangle itself in a non-physical way, as is the tendency when discrete energy input is used. It was found that the tangled distortion of the arc when using discrete energy input was due to perturbations along the arc caused by differential expansion of the gas along groups of adjacent mesh cells that either had energy input or did not. The distributed energy feature also gave arc temperature distributions that were more spatially uniform and had steeper temperature gradients, consistent with experimental arc images. The results are compared with experimental high-speed video images of arc movement for a spark plug of similar geometry and taken over a range of pressures and crossflow velocities in a high-pressure constant volume vessel. There is good agreement between the simulations and experimental images for the arc stretch distance in response to a crossflow. The simulations did not display as much lateral arc dispersion as seen in the experimental results, however, that were perhaps associated with flow recirculation zones downstream of the gap, present in the experiments. The influence of the electric field was shown by turning off the electric field effect in the simulations such that the arc movement was influenced by the flow field alone. The effect of the electric field was found to be more pronounced at lower crossflow velocities of 5 m/s and at lower pressures.more » « less
- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Conference Paper:
- https://doi.org/10.2514/6.2022-0976
