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Title: Hemicubane topological analogs of the oxygen-evolving complex of photosystem II mediating water-assisted propylene carbonate oxidation
A series of Ca–Mn clusters with the ligand 2-pyridinemethoxide (Py-CH 2 O) have been prepared with varying degrees of topological similarity to the biological oxygen-evolving complex. These clusters activate water as a substrate in the oxidative degradation of propylene carbonate, with activity correlated with topological similarity to the OEC, lowering the onset potential of the oxidation by as much as 700 mV.  more » « less
Award ID(s):
1800105
PAR ID:
10388493
Author(s) / Creator(s):
; ; ; ;
Date Published:
Journal Name:
Chemical Communications
Volume:
58
Issue:
15
ISSN:
1359-7345
Page Range / eLocation ID:
2532 to 2535
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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