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Abstract For artificial materials, desired properties often conflict. For example, engineering materials often achieve high energy dissipation by sacrificing resilience and vice versa, or desired auxeticity by losing their isotropy, which limits their performance and applications. To solve these conflicts, a strategy is proposed to create novel mechanical metamaterial via 3D space filling tiles with engaging key‐channel pairs, exemplified via auxetic 3D keyed‐octahedron–cuboctahedron metamaterials. This metamaterial shows high resilience while achieving large mechanical hysteresis synergistically under large compressive strain. Especially, this metamaterial exhibits ideal isotropy approaching the theoretical limit of isotropic Poisson's ratio, ‐1, as rarely seen in existing 3D mechanical metamaterials. In addition, the new class of metamaterials provides wide tunability on mechanical properties and behaviors, including an unusual coupled auxeticity and twisting behavior under normal compression. The designing methodology is illustrated by the integral of numerical modeling, theoretical analysis, and experimental characterization. The new mechanical metamaterials have broad applications in actuators and dampers, soft robotics, biomedical materials, and engineering materials/systems for energy dissipation.
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Multimorphic Materials: Spatially Tailoring Mechanical Properties via Selective Initiation of Interpenetrating Polymer Networks
Abstract Access to multimaterial polymers with spatially localized properties and robust interfaces is anticipated to enable new capabilities in soft robotics, such as smooth actuation for advanced medical and manufacturing technologies. Here, orthogonal initiation is used to create interpenetrating polymer networks (IPNs) with spatial control over morphology and mechanical properties. Base catalyzes the formation of a stiff and strong polyurethane, while blue LEDs initiate the formation of a soft and elastic polyacrylate. IPN morphology is controlled by when the LED is turned “on”, with large phase separation occurring for short time delays (≈1–2 min) and a mixed morphology for longer time delays (>5 min), which is supported by dynamic mechanical analysis, small angle X‐ray scattering, and atomic force microscopy. Through tailoring morphology, tensile moduli and fracture toughness can be tuned across ≈1–2 orders of magnitude. Moreover, a simple spring model is used to explain the observed mechanical behavior. Photopatterning produces “multimorphic” materials, where morphology is spatially localized with fine precision (<100 µm), while maintaining a uniform chemical composition throughout to mitigate interfacial failure. As a final demonstration, the fabrication of hinges represents a possible use case for multimorphic materials in soft robotics.
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- PAR ID:
- 10388756
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Advanced Materials
- Volume:
- 35
- Issue:
- 9
- ISSN:
- 0935-9648
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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