skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: NaPON Doping of Na 4 P 2 S 7 Glass and Its Effects on the Structure and Properties of Mixed Oxy-Sulfide-Nitride Phosphate Glass
Award ID(s):
1936913
PAR ID:
10396365
Author(s) / Creator(s):
; ;
Date Published:
Journal Name:
Inorganic Chemistry
Volume:
61
Issue:
44
ISSN:
0020-1669
Page Range / eLocation ID:
17469 to 17484
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. We present a new, to the best of our knowledge, experimental method for assessing sub-micron level subsurface damage (SSD) on optical glass. The method correlates surface characteristics such as the fracture toughness and Young’s modulus via nanoindentation with the penetration depth into the tested surfaces at different overall penetration depths, as revealed by magnetorheological finishing spotting techniques. Our results on ground surfaces suggest that low surface roughness does not necessarily imply the absence of SSD. We also compared SSD on surfaces processed by deterministic microgrinding and femtosecond (fs) laser polishing. The fs-laser polished surfaces revealed no detectable SSD, thus establishing the feasibility of fs-laser polishing for precision optical manufacturing. 
    more » « less
  2. null (Ed.)
  3. Abstract The accuracy of a differential thermal analysis (DTA) technique for predicting the temperature range of significant nucleation is examined in a BaO∙2SiO2glass by iterative numerical calculations. The numerical model takes account of time‐dependent nucleation, finite particle size, size‐dependent crystal growth rates, and surface crystallization. The calculations were made using the classical and, for the first time, the diffuse interface theories of nucleation. The results of the calculations are in agreement with experimental measurements, demonstrating the validity of the DTA technique. They show that this is independent of the DTA scan rate used and that surface crystallization has a negligible effect for the glass particle sizes studied. A breakdown of the Stokes‐Einstein relation between viscosity and the diffusion coefficient is demonstrated for low temperatures, near the maximum nucleation rate. However, it is shown that accurate values for the diffusion coefficient can be obtained from the induction time for nucleation and the growth velocity in this temperature range. 
    more » « less