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Title: Conformation of Network Strands in Polymer Gels
Small angle neutron scattering was used to measure single chain radii of gyration of end-linked polymer gels before and after cross-linking to calculate the prestrain, which is the ratio of the average chain size in a cross-linked network to that of a free chain in solution. The prestrain increased from 1.06 ± 0.01 to 1.16 ± 0.02 as gel synthesis concentration decreased near the overlap concentration, indicating that the chains are slightly more stretched in the network than in solution. Dilute gels with higher loop fractions were found to be spatially homogeneous. Form factor and volumetric scaling analyses independently confirmed that elastic strands stretch by 2–23% from Gaussian conformations to create a space-spanning network, with increased stretching as network synthesis concentration decreases. Prestrain measurements reported here serve as a point of reference for network theories that rely on this parameter for the calculation of mechanical properties.  more » « less
Award ID(s):
2116298
PAR ID:
10398028
Author(s) / Creator(s):
; ;
Date Published:
Journal Name:
ACS Macro Letters
ISSN:
2161-1653
Page Range / eLocation ID:
325 to 330
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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