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Abstract The isotopic composition of precipitation is used to trace water cycling and climate change, but interpretations of the environmental information recorded in central Andean precipitation isotope ratios are hindered by a lack of multi‐year records, poor spatial distribution of observations, and a predominant focus on Rayleigh distillation. To better understand isotopic variability in central Andean precipitation, we present a three‐year record of semimonthly δ18Opand δ2Hpvalues from 15 stations in southern Peru and triple oxygen isotope data, expressed as ∆′17Op, from 32 precipitation samples. Consistent with previous work, we find that elevation correlates negatively with δ18Opand that seasonal δ18Opvariations are related to upstream rainout and local convection. Spatial δ18Opvariations and atmospheric back trajectories show that both eastern‐ and western‐derived air masses bring precipitation to southern Peru. Seasonal d‐excesspcycles record moisture recycling and relative humidity at remote moisture sources, and both d‐excesspand ∆′17Opclearly differentiate evaporated and non‐evaporated samples. These results begin to establish the natural range of unevaporated ∆′17Opvalues in the central Andes and set the foundation for future paleoclimate and paleoaltimetry studies in the region. This study highlights the hydrologic understanding that comes from a combination of δ18Op, d‐excessp, and ∆′17Opdata and helps identify the evaporation, recycling, and rainout processes that drive water cycling in the central Andes.
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Mixed Signals From the Stable Isotope Composition of Precipitation and Plant Waxes in the Northern Tropical Andes
Abstract We evaluate the efficacy of the stable isotope composition of precipitation and plant waxes as proxies for paleoaltimetry and paleohydrology in the northern tropical Andes. We report monthly hydrogen (δ2Hp) and oxygen (δ18Op) isotope values of precipitation for an annual cycle, and hydrogen isotope values of plant waxes (δ2Hwax) obtained from modern soils along the eastern and western flanks of the Eastern Cordillera of Colombia. δ2Hp, δ18Op, as well as the unweighted mean δ2Hwaxvalues ofn‐C29,n‐C31, andn‐C33n‐alkanes in the eastern flank show a dependence on elevation (R2 = 0.90, 0.82, and 0.65, respectively). In stark contrast, the stable isotope compositions of neither precipitation nor plant waxes from the western flank correlate with elevation (R2 < 0.23), on top of a negligible (p‐value >0.05) correlation between δ2Hwaxand δ2Hp. In general, δ2Hwaxvalues along the eastern flank of the Eastern Cordillera seem to follow the trend of a simple Rayleigh distillation process that is consistent with studies elsewhere on the eastern side of the Andes in South America. Neither δ2Hpnor δ18Op, and therefore δ2Hwax, offer reliable estimates of past elevations in the western flank, due perhaps to water vapor source mixing, evaporation overprint, contrasting plant communities, and/or differences in evapotranspiration. Thus, δ2Hwaxis only reliable for paleohydrology and paleoaltimetry reconstructions on the eastern flank of the Andes, whereas interpretations based on δ2Hpand/or δ18Opwest of the highest point of the Eastern Cordillera need to consider mixing of moisture sources in addition to precipitation amount.
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- Award ID(s):
- 1929199
- PAR ID:
- 10401769
- Publisher / Repository:
- DOI PREFIX: 10.1029
- Date Published:
- Journal Name:
- Journal of Geophysical Research: Biogeosciences
- Volume:
- 127
- Issue:
- 12
- ISSN:
- 2169-8953
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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