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Glacial meltwater contributions to streams depend on watershed characteristics that impact water quantity and quality, with potential changes as glaciers continue to recede. The purpose of our study was to investigate the influence of glacier and bedrock controls on water chemistry in glacial streams, focusing on a range of small to large watersheds in Alaska. Southcentral Alaska provides an ideal study area due to diverse geologic characteristics and varying amounts of glacial coverage across watersheds. To investigate spatial and temporal variability due to glacial coverage and bedrock type, we analyzed water samples (n= 343) from seven watersheds over 2 years for major and trace element concentrations and water stable isotopes. We found variable water chemistry across the glacial rivers related to glacial coverage and the relative amount of metamorphic, sedimentary, and igneous bedrock. Some sites had elevated concentrations of harmful trace elements like As and U from glacier melt or groundwater. Longitudinal (upstream to downstream) variability was apparent within each river, with increasing inputs from tributaries, and groundwater altering the water chemistry relative to glacier meltwater contributions. The water chemistry and isotopic composition of river samples compared with endmember sources suggested a range from glacier-dominated to groundwater-dominated sites along stream transects. For example, water chemistry in the Knik and Matanuska rivers (with large contributing glaciers) was more influenced by glacier meltwater, while water chemistry in the Little Susitna River (with small glaciers) was more influenced by groundwater. Across all rivers, stream chemistry was controlled by glacier inputs near the headwaters and groundwater inputs downstream, with the water chemistry reflecting bedrock type. Our study provides a greater understanding of geochemical and hydrological processes controlling water resources in rapidly changing glacial watersheds.
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Spatial Patterns of Major Ions and Their Relationship to Sediment Concentration in Near Surface Glacier Ice, Taylor Valley Antarctica
Abstract Glaciers form the headwaters of many watersheds and, in arid polar environments, can provide the vast majority of water to downstream systems. Headwater watersheds are critically important for setting the chemistry for downstream systems, yet we know comparatively little about the patterns and processes that generate the geochemical signature of meltwater on glacier surfaces. Here, we focus on glaciers in the McMurdo Dry Valleys of Antarctica, the largest ice‐free area on the continent, characterized by alpine glaciers flowing into broad, rocky valleys. We examine patterns from the coast inland, accumulation to ablation zones, laterally across individual glaciers, and through the zone of meltwater generation. We directly compare solutes to sediment concentrations, a major source of dissolved solutes. Our findings agree with previous work that the overall meltwater chemistry of a given glacier is a product of local sediment sources and regional wind patterns: foehn winds moving from the ice sheet to the coast and on‐shore sea breezes. Further, these patterns hold across an individual glacier. Finally, we find that the ice chemistry and sediment profiles reflect freeze‐thaw and melt processes that occur at depth. This indicates that the transport and weathering of sediment in the ice profile likely has a strong influence on supra‐ and proglacial stream chemistry. This new understanding strengthens connections between physical and geochemical processes in cold‐based polar glacier environments and helps us better understand the processes driving landscape and ecosystem connectivity.
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- Award ID(s):
- 1637708
- PAR ID:
- 10403664
- Publisher / Repository:
- DOI PREFIX: 10.1029
- Date Published:
- Journal Name:
- Journal of Geophysical Research: Earth Surface
- Volume:
- 128
- Issue:
- 3
- ISSN:
- 2169-9003
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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