skip to main content


Title: Single-pixel reconstructive mid-infrared micro-spectrometer

Miniaturized spectrometers in the mid-infrared (MIR) are critical in developing next-generation portable electronics for advanced sensing and analysis. The bulky gratings or detector/filter arrays in conventional micro-spectrometers set a physical limitation to their miniaturization. In this work, we demonstrate a single-pixel MIR micro-spectrometer that reconstructs the sample transmission spectrum by a spectrally dispersed light source instead of spatially grated light beams. The spectrally tunable MIR light source is realized based on the thermal emissivity engineered via the metal-insulator phase transition of vanadium dioxide (VO2). We validate the performance by showing that the transmission spectrum of a magnesium fluoride (MgF2) sample can be computationally reconstructed from sensor responses at varied light source temperatures. With potentially minimum footprint due to the array-free design, our work opens the possibility where compact MIR spectrometers are integrated into portable electronic systems for versatile applications.

 
more » « less
Award ID(s):
1953803
NSF-PAR ID:
10407229
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ;
Publisher / Repository:
Optical Society of America
Date Published:
Journal Name:
Optics Express
Volume:
31
Issue:
9
ISSN:
1094-4087; OPEXFF
Page Range / eLocation ID:
Article No. 14367
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract

    Thanks to the unique molecular fingerprints in the mid-infrared spectral region, absorption spectroscopy in this regime has attracted widespread attention in recent years. Contrary to commercially available infrared spectrometers, which are limited by being bulky and cost-intensive, laboratory-on-chip infrared spectrometers can offer sensor advancements including raw sensing performance in addition to utilization such as enhanced portability. Several platforms have been proposed in the past for on-chip ethanol detection. However, selective sensing with high sensitivity at room temperature has remained a challenge. Here, we experimentally demonstrate an on-chip ethyl alcohol sensor based on a holey photonic crystal waveguide on silicon on insulator-based photonics sensing platform offering an enhanced photoabsorption thus improving sensitivity. This is achieved by designing and engineering an optical slow-light mode with a high group-index ofng = 73 and a strong localization of the modal power in analyte, enabled by the photonic crystal waveguide structure. This approach includes a codesign paradigm that uniquely features an increased effective path length traversed by the guided wave through the to-be-sensed gas analyte. This PIC-based lab-on-chip sensor is exemplary, spectrally designed to operate at the center wavelength of 3.4 μm to match the peak absorbance for ethanol. However, the slow-light enhancement concept is universal offering to cover a wide design-window and spectral ranges towards sensing a plurality of gas species. Using the holey photonic crystal waveguide, we demonstrate the capability of achieving parts per billion levels of gas detection precision. High sensitivity combined with tailorable spectral range along with a compact form-factor enables a new class of portable photonic sensor platforms when integrated with quantum cascade laser and detectors.

     
    more » « less
  2. We demonstrate a kilohertz frame rate snapshot hyperspectral imaging system suitable for high-speed imaging, which we name snapshot hyperspectral imager for emission and reactions (SHEAR). This system splits the sensor of a single high-speed camera to simultaneously capture a conventional image and a spectrally sheared response of the scene under study. Given the small, point-source-like nature of burning metal micro-particles, the spectral response of the species is captured without the need for a slit, as is needed in conventional imaging spectrometers. We pair robust image registration techniques with sparse reconstruction algorithms to computationally disentangle overlapping spectra associated with many burning particles over the course of a combustion experiment. As a proof-of-concept experiment, representative physical vapor deposited Al:Zr composite particles are ignited, and their burn evolution is recorded at a frame rate of 2 kHz using this method. We demonstrate operation over two distinct wavelength ranges spanning hundreds of nanometers in wavelength and with sub-nanometer resolution. We are able to track hundreds of individual Al:Zr particles in a single high-speed video, providing ample statistics of burn time, temperature, and AlO emission timing in a high-throughput method. The demonstrated technology is high-throughput, flexible in wavelength, inexpensive, and relatively easy to implement, and provides a much needed tool forin situcomposite metal fuel diagnostics.

     
    more » « less
  3. Abstract

    Mid-infrared (MIR) spectrometers are invaluable tools for molecular fingerprinting and hyper-spectral imaging. Among the available spectroscopic approaches, GHz MIR dual-comb absorption spectrometers have the potential to simultaneously combine the high-speed, high spectral resolution, and broad optical bandwidth needed to accurately study complex, transient events in chemistry, combustion, and microscopy. However, such a spectrometer has not yet been demonstrated due to the lack of GHz MIR frequency combs with broad and full spectral coverage. Here, we introduce the first broadband MIR frequency comb laser platform at 1 GHz repetition rate that achieves spectral coverage from 3 to 13 µm. This frequency comb is based on a commercially available 1.56 µm mode-locked laser, robust all-fiber Er amplifiers and intra-pulse difference frequency generation (IP-DFG) of few-cycle pulses inχ(2)nonlinear crystals. When used in a dual comb spectroscopy (DCS) configuration, this source will simultaneously enable measurements with μs time resolution, 1 GHz (0.03 cm−1) spectral point spacing and a full bandwidth of >5 THz (>166 cm−1) anywhere within the MIR atmospheric windows. This represents a unique spectroscopic resource for characterizing fast and non-repetitive events that are currently inaccessible with other sources.

     
    more » « less
  4. Abstract

    The spectral resolution and range of conventional spectrometers are typically limited by optical aberrations of their focusing elements, mainly due to chromatically induced astigmatism and an intrinsically curved focal plane. Traditional approaches to overcome this challenge require additional optical components which introduce significant bulk and design complexity to the system and prevent easy integration with portable devices. Here a single planar off‐axis focusing metalens consisting of subwavelength TiO2nanofins whose focal spots lie along a plane and undergo minimal focal spot broadening for almost 200 nm across the visible spectrum is demonstrated. This allows us to achieve a miniature aberration‐corrected spectrometer with nanometer spectral resolution, while having a beam propagation distance of only 4 cm to the camera plane. This is achieved by dispersion engineering: tailoring the phase, group delay (GD) and GD dispersion of the metalens. This approach is general and can also be used to introduce customized functionalities to the metalens such as a linear dispersion in the frequency domain with minimal additional overhead.

     
    more » « less
  5. Diversity across algal family Symbiodiniaceae contributes to the environmental resilience of certain coral species. Chlorophyll-afluorescence measurements are frequently used to determine symbiont health and resilience, but more work is needed to refine these tools and establish how they relate to underlying cellular traits. We examined trait diversity in symbionts from the generasCladocopiumandDurusdinium,collected from 12 aquacultured coral species. Photophysiological metrics (ΦPSII, σPSII, ρ, τ1, τ2, antenna bed quenching, non-photochemical quenching, and qP) were assessed using a prototype multi-spectral fluorometer over a variable light protocol which yielded a total of 1,360 individual metrics. Photophysiological metrics were then used to establish four unique light-response phenotypic variants. Corals harboring C15 were predominantly found within a single light-response phenotype which clustered separately from all other coral fragments. The majority ofDurusdiniumdominated colonies also formed a separate light-response phenotype which it shared with a few C1 dominated corals. C15 and D1 symbionts appear to differ in which mechanisms they use to dissipate excess light energy. Spectrally dependent variability is also observed across light-response phenotypes that may relate to differences in photopigment utilization. Symbiont cell biochemical and structural traits (atomic C:N:P, cell size, chlorophyll-a, neutral lipid content) was also assessed within each sample and differ across light-response phenotypes, linking photophysiological metrics with underlying primary cellular traits. Strong correlations between first- and second-order traits, such as Quantum Yield and cellular N:P content, or light dissipation pathways (qP and NPQ) and C:P underline differences across symbiont types and may also provide a means for using fluorescence-based metrics as biomarkers for certain primary-cellular traits.

     
    more » « less