An official website of the United States government
We explore the rheology during a startup flow of well-characterized polyelectrolyte microgel suspensions, which form soft glasses above the jamming concentration. We present and discuss results measured using different mechanical histories focusing on the variations of the static yield stress and yield strain. The behavior of the shear stress growth function is affected by long-lived residual stresses and strains that imprint a slowly decaying mechanical memory inside the materials. The startup flow response is not reversible upon flow reversal and the amplitude of the static yield stress increases with the time elapsed after rejuvenation. We propose an experimental protocol that minimizes the directional memory and we analyze the effect of aging. The static yield strain γ p and the reduced static yield stress σ p / σ y , where σ y is the dynamic yield stress measured from steady flow measurements, are in good agreement with our previous simulations [Khabaz et al., “Transient dynamics of soft particle glasses in startup shear flow. Part I: Microstructure and time scales,” J. Rheol. 65, 241 (2021)]. Our results demonstrate the need to consider memory and aging effects in transient measurements on soft particle glasses.
more »
« less
Evolution of flow reversal and flow heterogeneities in high elasticity wormlike micelles (WLMs) with a yield stress
The formation and evolution of a heterogeneous flow and flow reversal are examined in highly elastic, gel-like wormlike micelles (WLMs) formed from an amphiphilic triblock poloxamer P234 in 2M NaCl. A combination of linear viscoelastic, steady shear, and creep rheology demonstrate that these WLMs have a yield stress and exhibit viscoelastic aging, similar to some soft glassy materials. Nonlinear shear rheology and rheoparticle tracking velocimetry reveal that these poloxamer WLMs undergo a period of strong elastic recoil and flow reversal after the onset of shear startup. As flow reversal subsides, a fluidized high shear rate region and a nearly immobile low shear rate region of fluid form, accompanied by wall slip and elastic instabilities. The features of this flow heterogeneity are reminiscent of those for aging yield stress fluids, where the heterogeneous flow forms during the initial stress overshoot and is sensitive to the inherent stress gradient of the flow geometry. Additionally, macroscopic bands that form transiently above a critical shear rate become “trapped” due to viscoelastic aging in the nearly immobile region. This early onset of the heterogeneous flow during the rapidly decreasing portion of the stress overshoot differs from that typically observed in shear banding WLMs and is proposed to be necessary for observing significant flow reversal. Exploring the early-time, transient behavior of this WLM gel with rheology similar to both WLM solutions and soft glassy materials provides new insights into spatially heterogeneous flows in both of these complex fluids.
more »
« less
- Award ID(s):
- 2011401
- PAR ID:
- 10411206
- Date Published:
- Journal Name:
- Journal of Rheology
- Volume:
- 67
- Issue:
- 3
- ISSN:
- 0148-6055
- Page Range / eLocation ID:
- 661 to 681
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
Micro-scale hydrogel particles, known as microgels, are used in industry to control the rheology of numerous different products, and are also used in experimental research to study the origins of jamming and glassy behavior in soft-sphere model systems. At the macro-scale, the rheological behaviour of densely packed microgels has been thoroughly characterized; at the particle-scale, careful investigations of jamming, yielding, and glassy-dynamics have been performed through experiment, theory, and simulation. However, at low packing fractions near jamming, the connection between microgel yielding phenomena and the physics of their constituent polymer chains has not been made. Here we investigate whether basic polymer physics scaling laws predict macroscopic yielding behaviours in packed microgels. We measure the yield stress and cross-over shear-rate in several different anionic microgel systems prepared at packing fractions just above the jamming transition, and show that our data can be predicted from classic polyelectrolyte physics scaling laws. We find that diffusive relaxations of microgel deformation during particle re-arrangements can predict the shear-rate at which microgels yield, and the elastic stress associated with these particle deformations predict the yield stress.more » « less
-
Diverse chemical, energy, environmental, and industrial processes involve the flow of polymer solutions in porous media. The accumulation and dissipation of elastic stresses as the polymers are transported through the tortuous, confined pore space can lead to the development of an elastic flow instability above a threshold flow rate, producing a transition from steady to unsteady flow characterized by strong spatiotemporal fluctuations, despite the low Reynolds number (Re≪1). Furthermore, in 1D ordered arrays of pore constrictions, this unsteady flow can undergo a second transition to multistability, where distinct pores simultaneously exhibit distinct unsteady flow states. Here, we examine how this transition to multistability is influenced by fluid rheology. Through experiments using diverse polymer solutions having systematic variations in fluid shear-thinning or elasticity, in pore constriction arrays of varying geometries, we show that the onset of multistability can be described using a single dimensionless parameter, given sufficient fluid elasticity. This parameter, the streamwise Deborah number, compares the stress relaxation time of the polymer solution to the time required for the fluid to be advected between pore constrictions. Our work thus helps to deepen understanding of the influence of fluid rheology on elastic instabilities, helping to establish guidelines for the rational design of polymeric fluids with desirable flow behaviors.more » « less
-
The thermodynamics of the shear-induced phase transition of soft particle glasses is presented. Jammed suspensions of soft particles transform into a layered phase in a strong shear flow from a stable glassy phase at lower shear rates. The thermodynamics of the two phases can be computed based on the elastic energy and excess entropy of the system. At a critical shear rate, the elastic energy, the excess entropy, the free energy, the temperature, and the shear stress undergo discontinuous jumps at the phase transitions from the glassy to the layered phase. An effective temperature is defined from the derivative of the elastic energy and the excess entropy. The Helmholtz free energy is constructed using the elastic energy, excess entropy, and derived temperature. At a fixed shear rate, there is no equilibrium between the states. However, at a fixed temperature, the glassy and layered states may coexist, as indicated by the equality of their Helmholtz free energies. While this first-order phase transition is possible, it cannot be observed in simple shear because the stress is the same in both phases at the same temperature. Thus, shear banding cannot be observed in this system. Finally, an equation of state, which relates the shear stress to the excess entropy, is presented. This equation of state shows that all dynamical properties (e.g., shear-induced diffusivity and first and second normal stresses) of these jammed non-Brownian suspensions can be determined solely by measuring the shear stress.more » « less
-
The transition from laminar to turbulent flow is of great interest since it is one of the most difficult and unsolved problems in fluids engineering. The transition processes are significantly important because the transition has a huge impact on almost all systems that come in contact with a fluid flow by altering the mixing, transport, and drag properties of fluids even in simple pipe and channel flows. Generally, in most transportation systems, the transition to turbulence causes a significant increase in drag force, energy consumption, and, therefore, operating cost. Thus, understanding the underlying mechanisms of the laminar-to-turbulent transition can be a major benefit in many ways, especially economically. There have been substantial previous studies that focused on testing the stability of laminar flow and finding the critical amplitudes of disturbances necessary to trigger the transition in various wall-bounded systems, including circular pipes and square ducts. However, there is still no fundamental theory of transition to predict the onset of turbulence. In this study, we perform direct numerical simulations (DNS) of the transition flows from laminar to turbulence in a channel flow. Specifically, the effects of different magnitudes of perturbations on the onset of turbulence are investigated. The perturbation magnitudes vary from 0.001 (0.1%) to 0.05 (5%) of a typical turbulent velocity field, and the Reynolds number is from 5,000 to 40,000. Most importantly, the transition behavior in this study was found to be in good agreement with other reported studies performed for fluid flow in pipes and ducts. With the DNS results, a finite amplitude stability curve was obtained. The critical magnitude of perturbation required to cause transition was observed to be inversely proportional to the Reynolds number for the magnitude from 0.01 to 0.05. We also investigated the temporal behavior of the transition process, and it was found that the transition time or the time required to begin the transition process is inversely correlated with the Reynolds number only for the magnitude from 0.02 to 0.05, while different temporal behavior occurs for smaller perturbation magnitudes. In addition to the transition time, the transition dynamics were investigated by observing the time series of wall shear stress. At the onset of transition, the shear stress experiences an overshoot, then decreases toward sustained turbulence. As expected, the average values of the wall shear stress in turbulent flow increase with the Reynolds number. The change in the wall shear stress from laminar to overshoot was, of course, found to increase with the Reynolds number. More interestingly was the observed change in wall shear stress from the overshoot to turbulence. The change in magnitude appears to be almost insensitive to the Reynolds number and the perturbation magnitude. Because the change in wall shear stress is directly proportional to the pumping power, these observations could be extremely useful when determining the required pumping power in certain flow conditions. Furthermore, the stability curve and wall shear stress changes can be considered robust features for future applications, and ultimately interpreted as evidence of progress toward solving the unresolved fluids engineering problem.more » « less
- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1122/8.0000535
