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New U-Pb geochronological, Hf isotopic, heavy mineral, and sandstone petrographic results for Paleozoic clastic deposits of the Falkland/Malvinas Islands help address renewed debates on the plate tectonic history, regional paleogeography, and basin evolution of this geologic enigma prior to Mesozoic breakup of Gondwana. The Falkland/Malvinas Islands have been considered either an autochthonous part of the South American continent or part of an independent microplate displaced from the southeastern corner of Africa. We report detrital zircon U-Pb results (n = 1306 LA-ICPMS ages) for 11 sandstone samples from the Silurian-Devonian West Falkland Group (N = 7 samples, n = 837 grains) and Carboniferous-Permian Lafonia Group (N = 4 samples, n = 469 grains). Detrital zircon age distributions for the West Falkland Group point to consistent contributions from Neoproterozoic-Cambrian (650–520 Ma) and Mesoproterozoic (1100–1000 Ma) sources. Heavy mineral assemblages and sandstone petrographic data from these samples indicate significant input from recycled sediments. A potential shift in sediment sources during deposition of the Lafonia Group is indicated by the appearance of late Paleozoic (350–250 Ma) and Proterozoic (2000–1200 Ma) age populations, decreased proportions of stable heavy minerals, and a shift to juvenile Hf values for < 300 Ma zircons. The provenance change can be attributed to the onset of subduction-related arc magmatism and potential regional shortening and crustal thickening in southwestern Gondwana during the Permian transition of a passive margin into an active, retro-arc foreland basin. The detrital zircon age distributions identified here reflect potential source regions in southern Africa and/or the Transantarctic Mountains in Antarctica. These results are most readily accommodated within a Gondwana reconstruction that includes the Falkland/Malvinas Islands as a rotated microplate originating on the eastern side of southern Africa as part of the Gondwanide fold-thrust belt spanning from the Ventania region of Argentina through the Cape region of South Africa and into the Ellsworth and Pensacola mountains of Antarctica.
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Reconstructing the geological provenance and long-distance movement of rectangular, fishtail, and croisette copper ingots in Iron Age Zambia and Zimbabwe
The southern third of Africa is unusually rich in copper ore deposits. These were exploited by precolonial populations to manufacture wound-wire bangles, other forms of jewelry, and large copper ingots that were used as stores of copper or as forms of prestige. Rectangular, fishtail, and croisette ingots dating between the 5 th and 20 th centuries CE have been found in many locations in the Democratic Republic of the Congo (DRC), Zambia, and Zimbabwe, with isolated finds in Malawi and Mozambique. Molds for casting these ingots have been found mostly in the Central African Copperbelt, but also around the Magondi Belt copper deposits in northern Zimbabwe. For years, scholars have debated whether these ingots were exclusively made in the Copperbelt or if the molds found in Zimbabwe indicate that local copies were produced from Magondi Belt copper ore (Garlake 1970; Bisson 1976). Before the recent application of lead isotopic and chemical methods to provenance copper in central and southern Africa, there was no way to discern between these hypotheses. Rademakers et al. (2019) and Stephens et al. (2020) showed that copper artifacts from southern DRC (mostly from Upemba) and from northwestern Botswana (Tsodilo Hills) match the lead isotope ratios of ores from the Copperbelt. Building upon these previous studies, we present here the first results from a copper provenance project across the southern third of Africa, from the Copperbelt to northern South Africa. We apply lead isotopic analysis (LIA) and chemical analyses to establish the provenance of 29 croisette ingots recovered in Zimbabwe, 2 fishtail and 1 rectangular ingot recovered from sites in Zambia, and an “X” shaped ingot smelted in an experiment in Zambia in the 1970’s. Our chemistry and lead isotopic results indicate that 16 of these objects were smelted with copper from the Copperbelt, 16 objects source more specifically to the Kipushi deposit within this geological district, and only one HXR ingot sources to the Magondi Belt in Zimbabwe. Taken together, we clearly illustrate that croisette ingots were traveling significant distances to reach their eventual sites of deposition, and that there was also local production of these objects in Zimbabwe.
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- Award ID(s):
- 1852958
- PAR ID:
- 10411512
- Editor(s):
- Arikan, Gonca Dardeniz
- Date Published:
- Journal Name:
- PLOS ONE
- Volume:
- 18
- Issue:
- 3
- ISSN:
- 1932-6203
- Page Range / eLocation ID:
- e0282660
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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The Green River Formation of Wyoming, USA, is host to the world’s largest known lacustrine sodium carbonate deposits, which accumulated in a closed basin during the early Eocene greenhouse. Alkaline brines are hypothesized to have been delivered to ancient Gosiute Lake by the Aspen paleoriver that flowed from the Colorado Mineral Belt. To precisely trace fluvial provenance in the resulting deposits, we conducted X-ray fluorescence analyses and petrographic studies across a suite of well-dated sandstone marker beds of the Wilkins Peak Member of the Green River Formation. Principal component analysis reveals strong correlation among elemental abundances, grain composition, and sedimentary lithofacies. To isolate a detrital signal, elements least affected by authigenic minerals, weathering, and other processes were included in a principal component analysis, the results of which are consistent with petrographic sandstone modes and detrital zircon chronofacies of the basin. Sandstone marker beds formed during eccentricity-paced lacustrine lowstands and record the migration of fluvial distributary channel networks from multiple catchments around a migrating depocenter, including two major paleorivers. The depositional topography of these convergent fluvial fans would have inversely defined bathymetric lows during subsequent phases of lacustrine inundation, locations where trona could accumulate below a thermocline. Provenance mapping verifies fluvial connectivity to the Aspen paleoriver and to sources of alkalinity in the Colorado Mineral Belt across Wilkins Peak Member deposition, and shows that the greatest volumes of sediment were delivered from the Aspen paleoriver during deposition of marker beds A, B, D, and I, each of which were deposited coincident with prominent “hyperthermal” isotopic excursions documented in oceanic cores.more » « less
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None (Ed.)Abstract The Green River Formation of Wyoming, USA, is host to the world’s largest known lacustrine sodium carbonate deposits, which accumulated in a closed basin during the early Eocene greenhouse. Alkaline brines are hypothesized to have been delivered to ancient Gosiute Lake by the Aspen paleoriver that flowed from the Colorado Mineral Belt. To precisely trace fluvial provenance in the resulting deposits, we conducted X-ray fluorescence analyses and petrographic studies across a suite of well-dated sandstone marker beds of the Wilkins Peak Member of the Green River Formation. Principal component analysis reveals strong correlation among elemental abundances, grain composition, and sedimentary lithofacies. To isolate a detrital signal, elements least affected by authigenic minerals, weathering, and other processes were included in a principal component analysis, the results of which are consistent with petrographic sandstone modes and detrital zircon chronofacies of the basin. Sandstone marker beds formed during eccentricity-paced lacustrine lowstands and record the migration of fluvial distributary channel networks from multiple catchments around a migrating depocenter, including two major paleorivers. The depositional topography of these convergent fluvial fans would have inversely defined bathymetric lows during subsequent phases of lacustrine inundation, locations where trona could accumulate below a thermocline. Provenance mapping verifies fluvial connectivity to the Aspen paleoriver and to sources of alkalinity in the Colorado Mineral Belt across Wilkins Peak Member deposition, and shows that the greatest volumes of sediment were delivered from the Aspen paleoriver during deposition of marker beds A, B, D, and I, each of which were deposited coincident with prominent “hyperthermal” isotopic excursions documented in oceanic cores.more » « less
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1371/journal.pone.0282660
