We demonstrate unique reflective properties of light from bare and gold-coated InP nanowire (NW) photonic crystal arrays. The undoped wurtzite InP nanowire arrays are grown by selective area epitaxy and coated with a 12-nm thick Al2O3film to suppress atmospheric oxidation. A nominally 10-nm thick gold film is deposited around the NWs to investigate plasmonic effects. The reflectance spectra show pronounced Fabry-Perot oscillations, which are shifted for p- and s-polarized light due to a strong intrinsic birefringence in the NW arrays. Gold-coating of the NW array leads to a significant increase of the reflectance by a factor of two to three compared to the uncoated array, which is partially attributed to a plasmon resonance of the gold caps on top of the NWs and to a plasmonic antenna effect for p-polarized light. These interpretations are supported by finite-difference-time-domain simulations. Our experiments and simulations indicate that NW arrays can be used to design micrometer-sized polarizers, analyzers, and mirrors which are important optical elements in optoelectronic integrated circuits.
more »
« less
Polarization Conversion of Light Diffracted from InP Nanowire Photonic Crystal Arrays
Abstract This work investigates the polarization state of light diffracted from uncoated and gold‐coated InP nanowire photonic crystal arrays grown by selective area epitaxy. Experimental data and finite‐difference time‐domain simulations show that both the intensity and the ellipticity of the polarization state of the diffracted light beam can be controlled by the nanowire dimensions and gold coating, while the diffracted angle remains unchanged with respect to variations of these parameters. A nominally 10 nm‐thick gold film deposited around the nanowires enhances the diffraction intensity by plasmonic effects. These results demonstrate that the controlled conversion of incident linearly polarized light to circularly polarized or rotated linearly polarized diffracted light can find applications in photonic integrated circuits. The high sensitivity of the polarization state with respect to alterations of the nanowire dimension opens new prospects in the areas of semiconductor metrology and microchip inspection as well as for submicron particle detection.
more »
« less
- Award ID(s):
- 2004768
- PAR ID:
- 10414513
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Advanced Optical Materials
- Volume:
- 11
- Issue:
- 8
- ISSN:
- 2195-1071
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
In this paper, AlInN nanowire ultraviolet light-emitting diodes (LEDs) with emission at ∼299 nm have been successfully demonstrated. We have further studied the light extraction properties of these nanowire LEDs using photonic crystal structures with square and hexagonal lattices of nanowires. The light extraction efficiency (LEE) of the periodic nanowire LED arrays was found to be significantly increased as compared to random nanowire LEDs. The LEEs reach ∼ 56%, and ∼ 63% for the square and hexagonal photonic crystal-based nanowire structures, respectively. Moreover, highly transverse-magnetic polarized emission was observed with dominant vertical light emission for the AlInN nanowire ultraviolet LEDs.more » « less
-
Abstract Germanium selenide (GeSe) is a 2D layered material with an anisotropic crystal structure analogous to black phosphorus (BP). But unlike BP, GeSe is stable under ambient conditions and therefore provides more flexibility in building practical nanoscale devices. The in‐plane anisotropic vibrational, electrical, and optical properties of layered GeSe originating from the low symmetry of its crystal structure are being explored mostly for building polarization‐sensitive optoelectronic devices. However, the nonlinear optical properties of layered GeSe have not been investigated yet. Here, the anisotropic polarization‐dependent third‐harmonic generation (THG) from exfoliated thin GeSe flakes due to the low in‐plane lattice symmetry is reported. Furthermore, it is also shown that the intensity and polarization state of TH emission can be controlled by the polarization state of pump beam. Moreover, it is demonstrated that the crystal's symmetry axes can be rapidly determined by characterizing the intensity profile of TH emission upon the excitation from radially or azimuthally polarized vector beam. The results of this study pave the way for realizing anisotropic nonlinear optical devices such as multiplexers, signal processors, and other prototypes for future on‐chip photonic circuits and optical information processing.more » « less
-
Abstract Natural polymers, particularly plant‐derived nanocelluloses, self‐organize into hierarchical structures, enabling mechanical robustness, bright iridescence, emission, and polarized light reflection. These biophotonic properties are facilitated by the assembly of individual components during evaporation, such as cellulose nanocrystals (CNCs), which exhibit a left‐handed helical pitch in a chiral nematic state. This work demonstrates how optically active films with pre‐programmed opposite handedness (left or right) can be constructed via shear‐induced twisted printing with clockwise and counter‐clockwise shearing vectors. The resulting large‐area thin films are transparent yet exhibit pre‐determined mirror‐symmetrical optical activity, enabling the distinction of absorbed and emitted circularly polarized light. This processing method allows for sequential printing of thin and ultrathin films with twisted layered organization and on‐demand helicity. The complex light polarization behavior is due to step‐like changes in linear birefringence within each deposited layer and circular birefringence, different from that of conventional CNC films as revealed with Muller matrix analysis. Furthermore, intercalating an achiral organic dye into printed structures induces circularly polarized luminescence while preserving high transmittance and controlled handedness. These results suggest that twisted sequential printing can facilitate the construction of chiroptical metamaterials with tunable circular polarization, absorption, and emission for optical filters, encryption, photonic coatings, and chiral sensors.more » « less
-
Abstract Ruddleson–Popper (RP) perovskites have emerged as a class of material inheriting the superior optoelectronic properties of two materials: perovskites and 2D materials. The large exciton binding energy and natural quantum well structure not only make these materials ideal platforms to study light–matter interactions but also render them suitable for fabrication of various functional optoelectronic devices. Nanoscale structuring and morphology control have led to semiconductors with enhanced functionalities. Nanowires of semiconducting materials are extensively used for important applications like lasing and sensing. However, catalyst and template‐free scalable growth of nanowires of 2D perovskites has remained elusive. In this paper, a facile approach for morphology‐controlled growth of nanowires of 2D perovskite, (BA)2PbI4, is demonstrated. Additionally, it is shown that the photoluminescence (PL) from the nanowires is highly polarized with a polarization ratio as large as ≈0.73, which is one of the largest reported for perovskites. It is further shown that the photocurrent from the hybrid nanowire/graphene device is also sensitive to the polarization of the incident light with the photocurrent anisotropy ratio of ≈3.62 (much larger than the previously reported value of 2.68 for perovskites), thus demonstrating the potential of these nanowires as highly efficient photodetectors for polarized light.more » « less
An official website of the United States government
