Current synthetic pathways for uranyl peroxide materials introduce high initial concentrations of aqueous H2O2that decline over time. Alternatively, in situ generation of organic peroxide would maintain constant concentrations of peroxide over prolonged periods of time and open new pathways to novel uranyl peroxide compounds. Herein, we demonstrate this concept through the synthesis of a nanotube‐like uranyl peroxide phosphate (
Electrospray ionization tandem mass spectrometry with collision‐induced dissociation (ESI‐MS/MS) was utilized to study the gas phase fragmentation of uranyl peroxide nanoclusters with hydroxo, peroxo, oxalate, and pyrophosphate bridging ligands. These nanoclusters fragment into uranium monomers and dimers with mass‐to‐charge (
- NSF-PAR ID:
- 10415096
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Chemistry – A European Journal
- Volume:
- 29
- Issue:
- 39
- ISSN:
- 0947-6539
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Abstract Current synthetic pathways for uranyl peroxide materials introduce high initial concentrations of aqueous H2O2that decline over time. Alternatively, in situ generation of organic peroxide would maintain constant concentrations of peroxide over prolonged periods of time and open new pathways to novel uranyl peroxide compounds. Herein, we demonstrate this concept through the synthesis of a nanotube‐like uranyl peroxide phosphate (
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