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1. Characterizing the fundamental bending vibration of a linear polyatomic molecule for symmetry violation searches

   https://doi.org/10.1088/1367-2630/ace471  

   Jadbabaie, Arian ; Takahashi, Yuiki ; Pilgram, Nickolas H ; Conn, Chandler J ; Zeng, Yi ; Zhang, Chi ; Hutzler, Nicholas R ( July 2023 , New Journal of Physics)

   Polyatomic molecules have been identified as sensitive probes of charge-parity violating and parity violating physics beyond the Standard Model (BSM). For example, many linear triatomic molecules are both laser-coolable and have parity doublets in the ground electronic$\tilde{X}{}^2{\mathrm{\Sigma }}^{+}(010)$state arising from the bending vibration, both features that can greatly aid BSM searches. Understanding the$\tilde{X}{}^2{\mathrm{\Sigma }}^{+}(010)$state is a crucial prerequisite to precision measurements with linear polyatomic molecules. Here, we characterize the fundamental bending vibration of${}^{174}$YbOH using high-resolution optical spectroscopy on the nominally forbidden$\tilde{X}{}^2{\mathrm{\Sigma }}^{+}(010)$$\to \tilde{A}{}^2{\mathrm{\Pi }}_{1/2}(000)$transition at 588 nm. We assign 39 transitions originating from the lowest rotational levels of the$\tilde{X}{}^2{\mathrm{\Sigma }}^{+}(010)$state, and accurately model the state’s structure with an effective Hamiltonian using best-fit parameters. Additionally, we perform Stark and Zeeman spectroscopy on the$\tilde{X}{}^2{\mathrm{\Sigma }}^{+}(010)$state and fit the molecule-frame dipole moment to$D_{\mathrm{m}\mathrm{o}\mathrm{l}}=2.16(1)$Dand the effective electrong-factor to$g_S=2.07(2)$. Further, we use an empirical model to explain observed anomalous line intensities in terms of interference from spin–orbit and vibronic perturbations in the excited$\tilde{A}{}^2{\mathrm{\Pi }}_{1/2}(000)$state. Our work is an essential step toward searches for BSM physics in YbOH and other linear polyatomic molecules.

    

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2. Intermediate valence state in YbB 4 revealed by resonant x-ray emission spectroscopy

   https://doi.org/10.1088/1361-648X/ac7629  

   Frontini, Felix ; Lebert, Blair W. ; Cho, K. K. ; Song, M. S. ; Cho, B. K. ; Pollock, Christopher J. ; Kim, Young-June ( June 2022 , Journal of Physics: Condensed Matter)

   We report the temperature dependence of the Yb valence in the geometrically frustrated compound${\mathrm{Y}\mathrm{b}\mathrm{B}}_4$from 12 to 300 K using resonant x-ray emission spectroscopy at the Yb$L_{{\alpha }_1}$transition. We find that the Yb valence,v, is hybridized between thev = 2 andv = 3 valence states, increasing from$v=2.61\pm 0.01$at 12 K to$v=2.67\pm 0.01$at 300 K, confirming that${\mathrm{Y}\mathrm{b}\mathrm{B}}_4$is a Kondo system in the intermediate valence regime. This result indicates that the Kondo interaction in${\mathrm{Y}\mathrm{b}\mathrm{B}}_4$is substantial, and is likely to be the reason why${\mathrm{Y}\mathrm{b}\mathrm{B}}_4$does not order magnetically at low temperature, rather than this being an effect of geometric frustration. Furthermore, the zero-point valence of the system is extracted from our data and compared with other Kondo lattice systems. The zero-point valence seems to be weakly dependent on the Kondo temperature scale, but not on the valence change temperature scaleT_v.

    

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3. Deciphering the sensitivity of urban canopy air temperature to anthropogenic heat flux with a forcing-feedback framework

   https://doi.org/10.1088/1748-9326/ace7e0  

   Wang, Linying ; Sun, Ting ; Zhou, Wenyu ; Liu, Maofeng ; Li, Dan ( August 2023 , Environmental Research Letters)

   The sensitivity of urban canopy air temperature ($T_a$) to anthropogenic heat flux ($Q_{AH}$) is known to vary with space and time, but the key factors controlling such spatiotemporal variabilities remain elusive. To quantify the contributions of different physical processes to the magnitude and variability of$\mathrm{\Delta }{T}_a/\mathrm{\Delta }{Q}_{AH}$(where$\mathrm{\Delta }$represents a change), we develop a forcing-feedback framework based on the energy budget of air within the urban canopy layer and apply it to diagnosing$\mathrm{\Delta }{T}_a/\mathrm{\Delta }{Q}_{AH}$simulated by the Community Land Model Urban over the contiguous United States (CONUS). In summer, the median$\mathrm{\Delta }{T}_a/\mathrm{\Delta }{Q}_{AH}$is around 0.01$\text{K\hspace{0.17em}}{\left(\text{W\hspace{0.17em}}{\text{m}}^{-\text{2}}\right)}^{-1}$over the CONUS. Besides the direct effect of$Q_{AH}$on$T_a$, there are important feedbacks through changes in the surface temperature, the atmosphere–canopy air heat conductance ($c_a$), and the surface–canopy air heat conductance. The positive and negative feedbacks nearly cancel each other out and$\mathrm{\Delta }{T}_a/\mathrm{\Delta }{Q}_{AH}$is mostly controlled by the direct effect in summer. In winter,$\mathrm{\Delta }{T}_a/\mathrm{\Delta }{Q}_{AH}$becomes stronger, with the median value increased by about 20% due to weakened negative feedback associated with$c_a$. The spatial and temporal (both seasonal and diurnal) variability of$\mathrm{\Delta }{T}_a/\mathrm{\Delta }{Q}_{AH}$as well as the nonlinear response of$\mathrm{\Delta }{T}_a$to$\mathrm{\Delta }{Q}_{AH}$are strongly related to the variability of$c_a$, highlighting the importance of correctly parameterizing convective heat transfer in urban canopy models.

    

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4. Electron Heating in 2D Particle-in-cell Simulations of Quasi-perpendicular Low-beta Shocks

   https://doi.org/10.3847/1538-4357/ad1f69  

   Tran, Aaron ; Sironi, Lorenzo ( April 2024 , The Astrophysical Journal)

   We measure the thermal electron energization in 1D and 2D particle-in-cell simulations of quasi-perpendicular, low-beta (β_p= 0.25) collisionless ion–electron shocks with mass ratiom_i/m_e= 200, fast Mach number${\mathcal{M}}_{\mathrm{ms}}=1$–4, and upstream magnetic field angleθ_Bn= 55°–85° from the shock normal$\hat{\mathit{n}}$. It is known that shock electron heating is described by an ambipolar,B-parallel electric potential jump, Δϕ_∥, that scales roughly linearly with the electron temperature jump. Our simulations have$\mathrm{\Delta }{\varphi }_{\parallel }/(0.5m_{\mathrm{i}}{u_{\mathrm{sh}}}^2)\sim 0.1$–0.2 in units of the pre-shock ions’ bulk kinetic energy, in agreement with prior measurements and simulations. Different ways to measureϕ_∥, including the use of de Hoffmann–Teller frame fields, agree to tens-of-percent accuracy. Neglecting off-diagonal electron pressure tensor terms can lead to a systematic underestimate ofϕ_∥in our low-β_pshocks. We further focus on twoθ_Bn= 65° shocks: a${\mathcal{M}}_{\mathrm{s}}=4$(${\mathcal{M}}_{\mathrm{A}}=1.8$) case with a long, 30d_iprecursor of whistler waves along$\hat{\mathit{n}}$, and a${\mathcal{M}}_{\mathrm{s}}=7$(${\mathcal{M}}_{\mathrm{A}}=3.2$) case with a shorter, 5d_iprecursor of whistlers oblique to both$\hat{\mathit{n}}$andB;d_iis the ion skin depth. Within the precursors,ϕ_∥has a secular rise toward the shock along multiple whistler wavelengths and also has localized spikes within magnetic troughs. In a 1D simulation of the${\mathcal{M}}_{\mathrm{s}}=4$,θ_Bn= 65° case,ϕ_∥shows a weak dependence on the electron plasma-to-cyclotron frequency ratioω_pe/Ω_ce, andϕ_∥decreases by a factor of 2 asm_i/m_eis raised to the true proton–electron value of 1836.

    

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5. High-harmonic generation in spin and charge current pumping at ferromagnetic or antiferromagnetic resonance in the presence of spin–orbit coupling

   https://doi.org/10.1088/2515-7639/aceaad  

   Varela-Manjarres, Jalil ; Nikolić, Branislav K. ( August 2023 , Journal of Physics: Materials)

   One of the cornerstone effects in spintronics is spin pumping by dynamical magnetization that is steadily precessing (around, for example, thez-axis) with frequencyω₀due to absorption of low-power microwaves of frequencyω₀under the resonance conditions and in the absence of any applied bias voltage. The two-decades-old ‘standard model’ of this effect, based on the scattering theory of adiabatic quantum pumping, predicts that component$I^{S_z}$of spin current vector$(I^{S_x}(t),I^{S_y}(t),I^{S_z})\propto {\omega }_0$is time-independent while$I^{S_x}(t)$and$I^{S_y}(t)$oscillate harmonically in time with a single frequencyω₀whereas pumped charge current is zero$I\equiv 0$in the same adiabatic$\propto {\omega }_0$limit. Here we employ more general approaches than the ‘standard model’, namely the time-dependent nonequilibrium Green’s function (NEGF) and the Floquet NEGF, to predict unforeseen features of spin pumping: namely precessing localized magnetic moments within a ferromagnetic metal (FM) or antiferromagnetic metal (AFM), whose conduction electrons are exposed to spin–orbit coupling (SOC) of either intrinsic or proximity origin, will pump both spin$I^{S_{\alpha }}(t)$and chargeI(t) currents. All four of these functions harmonically oscillate in time at both even and odd integer multiples$N{\omega }_0$of the driving frequencyω₀. The cutoff order of such high harmonics increases with SOC strength, reaching$N_{\mathrm{m}\mathrm{a}\mathrm{x}}\simeq 11$in the one-dimensional FM or AFM models chosen for demonstration. A higher cutoff$N_{\mathrm{m}\mathrm{a}\mathrm{x}}\simeq 25$can be achieved in realistic two-dimensional (2D) FM models defined on a honeycomb lattice, and we provide a prescription of how to realize them using 2D magnets and their heterostructures.

    

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