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This content will become publicly available on July 1, 2024

Title: Characterizing the fundamental bending vibration of a linear polyatomic molecule for symmetry violation searches
Abstract

Polyatomic molecules have been identified as sensitive probes of charge-parity violating and parity violating physics beyond the Standard Model (BSM). For example, many linear triatomic molecules are both laser-coolable and have parity doublets in the ground electronicX˜2Σ+(010)state arising from the bending vibration, both features that can greatly aid BSM searches. Understanding theX˜2Σ+(010)state is a crucial prerequisite to precision measurements with linear polyatomic molecules. Here, we characterize the fundamental bending vibration of174YbOH using high-resolution optical spectroscopy on the nominally forbiddenX˜2Σ+(010)A˜2Π1/2(000)transition at 588 nm. We assign 39 transitions originating from the lowest rotational levels of theX˜2Σ+(010)state, and accurately model the state’s structure with an effective Hamiltonian using best-fit parameters. Additionally, we perform Stark and Zeeman spectroscopy on theX˜2Σ+(010)state and fit the molecule-frame dipole moment toDmol=2.16(1)Dand the effective electrong-factor togS=2.07(2). Further, we use an empirical model to explain observed anomalous line intensities in terms of interference from spin–orbit and vibronic perturbations in the excitedA˜2Π1/2(000)state. Our work is an essential step toward searches for BSM physics in YbOH and other linear polyatomic molecules.

 
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Award ID(s):
1847550
NSF-PAR ID:
10488857
Author(s) / Creator(s):
; ; ; ; ; ;
Publisher / Repository:
IOP
Date Published:
Journal Name:
New Journal of Physics
Volume:
25
Issue:
7
ISSN:
1367-2630
Page Range / eLocation ID:
073014
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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