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  • Homogeneous versus MOF-supported catalysis: A direct comparison of catalytic hydroboration at Ni tripodal P 3 E (E = Si, Ge) complexes
Title: Homogeneous versus MOF-supported catalysis: A direct comparison of catalytic hydroboration at Ni tripodal P 3 E (E = Si, Ge) complexes
MOF NU-1000 was employed to host Ni tripodal complexes prepared from new organometallic precursors [HNi(κ4(E,P,P,P)-E(o-C 6 H 4 CH 2 PPh 2 ) 3 ], E = Si (Ni-1), Ge (Ni-2). The new heterogenous catalytic materials, Ni-1@NU-1000 and Ni-2@NU-1000 show the advantages of both homogenous and heterogeneous catalysts. They catalyze the hydroboration of aldehydes and ketones more efficiently than the homogenous Ni-1 and Ni-2, under aerobic conditions, and allowing recyclability of the catalyst.  more » « less
Award ID(s):
2102689
PAR ID:
10417103
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ;
Publisher / Repository:
Royal Society of Chemistry
Date Published:
Journal Name:
Dalton Transactions
Volume:
52
Issue:
26
ISSN:
1477-9226
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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