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Lyotropic chromonic liquid crystals (LCLCs) represent aqueous dispersions of organic disk-like molecules that form cylindrical aggregates. Despite the growing interest in these materials, their flow behavior is poorly understood. Here, we explore the effect of shear on dynamic structures of the nematic LCLC, formed by 14 wt% water dispersion of disodium cromoglycate (DSCG). We employ in situ polarizing optical microscopy (POM) and small-angle and wide-angle X-ray scattering (SAXS/WAXS) to obtain independent and complementary information on the director structures over a wide range of shear rates. The DSCG nematic shows a shear-thinning behavior with two shear-thinning regions (Region I at < 1 s −1 and Region III at > 10 s −1 ) separated by a pseudo-Newtonian Region II (1 s −1 < < 10 s −1 ). The material is of a tumbling type. In Region I, < 1 s −1 , the director realigns along the vorticity axis. An increase of above 1 s −1 triggers nucleation of disclination loops. The disclinations introduce patches of the director that deviates from the vorticity direction and form a polydomain texture. Extension of the domains along the flow and along the vorticity direction decreases with the increase of the shear rate to 10 s −1 . Above 10 s −1 , the domains begin to elongate along the flow. At > 100 s −1 , the texture evolves into periodic stripes in which the director is predominantly along the flow with left and right tilts. The period of stripes decreases with an increase of . The shear-induced transformations are explained by the balance of the elastic and viscous energies. In particular, nucleation of disclinations is associated with an increase of the elastic energy at the walls separating nonsingular domains with different director tilts. The uncovered shear-induced structural effects would be of importance in the further development of LCLC applications.
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Reconfiguration of Nematic Disclinations in Plane-Parallel Confinements
We study numerically the reconfiguration process of colliding m=1/2 strength disclinations in an achiral nematic liquid crystal (NLC). A Landau–de Gennes approach in terms of tensor nematic-order parameters is used. Initially, different pairs m1,m2 of parallel wedge disclination lines connecting opposite substrates confining the NLC in a plane-parallel cell of a thickness h are imposed: {1/2,1/2}, {−1/2,−1/2} and {−1/2,1/2}. The collisions are imposed by the relative rotation of the azimuthal angle θ of the substrates that strongly pin the defect end points. Pairs {1/2,1/2} and {−1/2,−1/2} “rewire” at the critical angle θc1=3π4 in all cases studied. On the other hand, two qualitatively different scenarios are observed for {−1/2,1/2}. In the thinner film regime hhc, the colliding disclinations at θc2 reconfigure into boojum-like twist disclinations.
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- Award ID(s):
- 1901797
- PAR ID:
- 10418099
- Date Published:
- Journal Name:
- Crystals
- Volume:
- 13
- Issue:
- 6
- ISSN:
- 2073-4352
- Page Range / eLocation ID:
- 904
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.3390/cryst13060904
