This paper examines the influence of biochar on the properties of alkali-activated slag pastes using two activator solutions, namely NaOH and Na2CO3. The biochar demonstrated different absorption kinetics in the mixture of slag and the two activator solutions. The pastes with biochar showed a delay in the heat flow peak, compared to the pastes without biochar, but the cumulative heat release in these pastes at later hours was increased, compared to the pastes without biochar. It was found that the use of biochar reduced autogenous shrinkage in the pastes and the reduction in autogenous shrinkage was more pronounced in the alkali-activated slag with NaOH, compared to Na2CO3. The void structure of the pastes was investigated using x-ray micro-computed tomography. It was found that refined pore structure due to reduced effective solution/slag in the pastes with biochar was able to compensate for the decreasing effect of biochar voids on compressive strength. The electrical resistivity was shown to be lower in the pastes with biochar.
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The Effect of Hydrogels with Different Chemical Compositions on the Behavior of Alkali-Activated Slag Pastes
The effect of in-house synthesized hydrogels with different chemical compositions on the properties of alkali-activated slag pastes was examined. It was found that the teabag test and modified teabag test as a direct method and the flow test as an indirect method showed a similar trend in hydrogel absorption; however, the absorption values differ noticeably between the direct and indirect methods. The alkali-activated slag pastes with hydrogels demonstrated a significant reduction in autogenous shrinkage compared to the pastes without hydrogels. The creation of macrovoids by the hydrogels and change in pore structure resulted in a decrease in compressive strength and electrical resistivity of the pastes with hydrogels. The absorption and desorption of hydrogels in the pastes were tracked using X-ray microcomputed tomography (micro-CT), and it was shown that the onset of hydrogel desorption approximately coincided with the final setting time of the pastes.
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- PAR ID:
- 10424921
- Date Published:
- Journal Name:
- Gels
- Volume:
- 8
- Issue:
- 11
- ISSN:
- 2310-2861
- Page Range / eLocation ID:
- 731
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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