We present a review of superlubricity: the state of ultra-low friction between surfaces in relative motion. Various approaches to achieving this state are considered in a broad sense, including structural superlubricity, superlubricity via normal force control, and contact actuation, as well as thermolubricity, liquid superlubricity, and quantum lubricity. An overview of the physical fundamentals associated with each approach is presented, with particular emphasis on recent theoretical and experimental developments that constitute milestones in our scientific understanding. The review also includes a discussion of perspectives on future research in the context of existing challenges. It is projected that interest in superlubricity from the basic science and engineering communities will continue to accelerate in the near future, accompanied by a transition from fundamental studies to technologically relevant applications.
more »
« less
Progress in Superlubricity Across Different Media and Material Systems—A Review
Superlubricity is a terminology often used to describe a sliding regime in which the adhesion leading to friction or resistance to sliding literally vanishes. For improved energy security, environmental sustainability, and a decarbonized economy, achieving superlubric sliding surfaces in moving mechanical systems sounds very exciting, since friction adversely impacts the efficiency, durability, and environmental compatibility of many moving mechanical systems used in industrial sectors. Accordingly, scientists and engineers have been exploring new ways to achieve macroscale superlubricity through the use of advanced materials, coatings, and lubricants for many years. As a result of such concerted efforts, recent developments indicate that with the use of the right kinds of solids, liquids, and gases on or in the vicinity of sliding contact interfaces, one can indeed achieve friction coefficients well below 0.01. The friction coefficient below this threshold is commonly termed the superlubric sliding regime. Hopefully, these developments will foster further research in the field of superlubricity and will ultimately give rise to the industrial scale realization of nearly-frictionless mechanical systems consuming far less energy and causing much-reduced greenhouse gas emissions. This will ultimately have a substantial positive impact on the realization of economically and environmentally viable industrial practices supporting a decarbonized energy future. In this paper, we will provide an overview of recent progress in superlubricity research involving solid, liquid, and gaseous media and discuss the prospects for achieving superlubricity in engineering applications leading to greater efficiency, durability, environmental quality, and hence global sustainability.
more »
« less
- Award ID(s):
- 2018132
- PAR ID:
- 10428634
- Date Published:
- Journal Name:
- Frontiers in Mechanical Engineering
- Volume:
- 8
- ISSN:
- 2297-3079
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
null (Ed.)Here, we report the high-temperature superlubricity phenomenon accomplished in coatings produced by burnishing powders of antimony trioxide (Sb 2 O 3 ) and magnesium silicate hydroxide coated with carbon (MSH/C) onto the nickel superalloy substrate. The tribological analysis performed in an open-air experimental setup revealed that with the increase of testing temperature, the coefficient of friction (COF) of the coating gradually decreases, finally reaching the superlubricity regime (the COF of 0.008) at 300°C. The analysis of worn surfaces using in-situ Raman spectroscopy suggested the synergistic effect of the inner Sb 2 O 3 adhesion layer and the top MSH/C layer, which do not only isolate the substrate from the direct exposure to sliding but also protect it from oxidation. The cross-sectional transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS) results indicated the tribochemically-activated formation of an amorphous carbon layer on the surface of the coating during sliding. Formation of the film enables the high-temperature macroscale superlubricity behavior of the material system.more » « less
-
Abstract Van der Waals heterostructures formed by stacked 2D materials show exceptional electronic, mechanical, and optical properties. Superlubricity, a condition where atomically flat, incommensurate planes of atoms result in ultra‐low friction, is a prime example enabling, for example, self‐assembly of optically visible graphene nanostructures in air via a sliding auto‐kirigami process. Here, it is demonstrated that a subtle but ubiquitous adsorbate stripe structure found on graphene and graphitic surfaces in ambient conditions remains stable within the interface between twisted graphene layers as they slide over each other. Despite this contamination, the interface retains an exceptional superlubricious state with an estimated upper bound frictional shear strength of 10 kPa, indicating that direct atomic incommensurate contact is not required to achieve ambient superlubricity for 2D materials. The results suggest that any phenomena depending on 2D heterostructure interfaces such as exotic electronic behavior may need to consider the presence of stripe adsorbate structures that remain intercalated.more » « less
-
Abstract Structural superlubricity (SSL) at layered material interfaces is an exciting and vibrant field of research, offering vast opportunities to achieve ultralow friction and wear with numerous potential technological applications. At increasing length‐scales, new physical and chemical energy dissipation pathways emerge that threaten to push the system out of the superlubric regime. Physical inhibitors of SSL are primarily associated with in‐plane elasticity, out‐of‐plane corrugation, moiré superlattices, grain boundaries, and lattice defects. Chemical mechanisms that may suppress superlubric behavior include interlayer bonding, wear, and external contaminants. In this article, these and other challenges are reviewed facing the scaling‐up of structural superlubricity, as reflected in recent experimental and theoretical studies. Further perspectives are offered on future directions for realizing and manipulating macroscale superlubricity, outlining technological opportunities that it entails.more » « less
-
Lubricated contacts are present in many engineering and biological systems involving soft solids. Typical mechanisms considered for controlling the sliding friction in such lubricated conditions involve bulk material compliance, fluid viscosity, viscoelastic response of the material (hysteretic friction), and breaking of the fluid film where dry contact occurs (adhesive friction). In this work we show that a two-phase periodic structure (TPPS), with a varying modulus across the sliding surface, provides significant enhancement of lubricated sliding friction when the system is in the elastohydrodynamic lubrication (EHL) regime. We propose that the enhanced friction is due to extra energy loss during periodic transitions of the sliding indenter between the compliant and stiff regions during which excess energy is dissipated through the fluid layer. This is a form of elastic hysteresis that provides a novel mechanism for friction enhancement in soft solids under lubricated conditions.more » « less
An official website of the United States government

