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1. The SOFIA Massive (SOMA) Star Formation Q-band follow-up: I. Carbon-chain chemistry of intermediate-mass protostars

   https://doi.org/10.1051/0004-6361/202451499  

   Taniguchi, Kotomi; Gorai, Prasanta; Tan, Jonathan C; Gómez-Garrido, Miguel; Fedriani, Rubén; Yang, Yao-Lun; Tirupati_Kumara, Sridharan; Tanaka, Kei_E I; Saito, Masao; Zhang, Yichen; et al (December 2024, Astronomy & Astrophysics)

   Context. Evidence that the chemical characteristics around low- and high-mass protostars are similar has been found: notably, a variety of carbon-chain species and complex organic molecules (COMs) form around both types. On the other hand, the chemical compositions around intermediate-mass (IM) protostars (2M_⊙<m_*< 8M_⊙) have not been studied with large samples. In particular, it is unclear the extent to which carbon-chain species form around them. Aims. We aim to obtain the chemical compositions of a sample of IM protostars, focusing particularly on carbon-chain species. We also aim to derive the rotational temperatures of HC₅N to confirm whether carbon-chain species are formed in the warm gas around these stars. Methods. We conducted Q-band (31.5–50 GHz) line survey observations toward 11 mainly IM protostars with the Yebes 40 m radio telescope. The target protostars were selected from a subsample of the source list of the SOFIA Massive Star Formation project. Assuming local thermodynamic equilibrium, we derived the column densities of the detected molecules and the rotational temperatures of HC₅N and CH₃OH. Results. Nine carbon-chain species (HC₃N, HC₅N, C₃H, C₄Hlinear-H₂CCC,cyclic-C₃H₂, CCS, C₃S, and CH₃CCH), three COMs (CH₃OH, CH₃CHO, and CH₃CN), H₂CCO, HNCO, and four simple sulfur-bearing species (¹³CS, C³⁴S, HCS⁺, and H₂CS) are detected. The rotational temperatures of HC₅N are derived to be ~20–30 K in three IM protostars (Cepheus E, HH288, and IRAS 20293+3952). The rotational temperatures of CH₃OH are derived in five IM sources and found to be similar to those of HC₅N. Conclusions. The rotational temperatures of HC₅N around the three IM protostars are very similar to those around low- and high-mass protostars. These results indicate that carbon-chain molecules are formed in lukewarm gas (~20–30 K) around IM protostars via the warm carbon-chain chemistry process. Thus, carbon-chain formation occurs ubiquitously in the warm gas around protostars across a wide range of stellar masses. Carbon-chain molecules and COMs coexist around most of the target IM protostars, which is similar to the situation for low- and high-mass protostars. In summary, the chemical characteristics around protostars are the same in the low-, intermediate- and high-mass regimes. 

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2. Cyanopolyyne Chemistry in the L1544 Prestellar Core: New Insights from GBT Observations

   https://doi.org/10.3847/1538-4357/acb5e8  

   Bianchi, Eleonora; Remijan, Anthony; Codella, Claudio; Ceccarelli, Cecilia; Lique, Francois; Spezzano, Silvia; Balucani, Nadia; Caselli, Paola; Herbst, Eric; Podio, Linda; et al (February 2023, The Astrophysical Journal)

   Abstract We report a comprehensive study of the cyanopolyyne chemistry in the prototypical prestellar core L1544. Using the 100 m Robert C. Byrd Green Bank Telescope, we observe three emission lines of HC₃N, nine lines of HC₅N, five lines of HC₇N, and nine lines of HC₉N. HC₉N is detected for the first time toward the source. The high spectral resolution (∼0.05 km s⁻¹) reveals double-peak spectral line profiles with the redshifted peak a factor 3–5 brighter. Resolved maps of the core in other molecular tracers indicate that the southern region is redshifted. Therefore, the bulk of the cyanopolyyne emission is likely associated with the southern region of the core, where free carbon atoms are available to form long chains, thanks to the more efficient illumination of the interstellar field radiation. We perform a simultaneous modeling of the HC₅N, HC₇N, and HC₉N lines to investigate the origin of the emission. To enable this analysis, we performed new calculation of the collisional coefficients. The simultaneous fitting indicates a gas kinetic temperature of 5–12 K, a source size of 80″, and a gas density larger than 100 cm⁻³. The HC₅N:HC₇N:HC₉N abundance ratios measured in L1544 are about 1:6:4. We compare our observations with those toward the well-studied starless core TMC-1 and with the available measurements in different star-forming regions. The comparison suggests that a complex carbon chain chemistry is active in other sources and is related to the presence of free gaseous carbon. Finally, we discuss the possible formation and destruction routes in light of the new observations. 

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3. ALMA-IMF: IV. A comparative study of the main hot cores in W43-MM1: Detection, temperature, and molecular composition

   https://doi.org/10.1051/0004-6361/202243669  

   Brouillet, N; Despois, D; Molet, J; Nony, T; Motte, F; Gusdorf, A; Louvet, F; Bontemps, S; Herpin, F; Bonfand, M; et al (September 2022, Astronomy & Astrophysics)

   Context.Hot cores are signposts of the protostellar activity of dense cores in star-forming regions. W43-MM1 is a young region that is very rich in terms of high-mass star formation, which is highlighted by the presence of large numbers of high-mass cores and outflows. Aims.We aim to systematically identify the massive cores in W43-MM1 that contain a hot core and compare their molecular composition. Methods.We used Atacama Large Millimeter/sub-millimeter Array (ALMA) high-spatial resolution (~2500 au) data to identify line-rich protostellar cores and carried out a comparative study of their temperature and molecular composition. Here, the identification of hot cores is based on both the spatial distribution of the complex organic molecules and the contribution of molecular lines relative to the continuum intensity. We rely on the analysis of CH₃CN and CH₃CCH to estimate the temperatures of the selected cores. Finally, we rescale the spectra of the different hot cores based on their CH₃OCHO line intensities to directly compare the detections and line intensities of the other species. Results.W43-MM1 turns out to be a region that is rich in massive hot cores. It contains at least one less massive (core #11, 2M_⊙) and seven massive (16−100M_⊙) hot cores. The excitation temperature of CH₃CN, whose emission is centred on the cores, is of the same order for all of them (120–160 K). There is a factor of up to 30 difference in the intensity of the lines of complex organic molecules (COMs). However the molecular emission of the hot cores appears to be the same or within a factor of 2–3. This suggests that these massive cores, which span about an order of magnitude in core mass, have a similar chemical composition and show similar excitation of most of the COMs. In contrast, CH₃CCH emission is found to preferentially trace the envelope, with a temperature ranging from 50 K to 90 K. Lines in core #11 are less optically thick, which makes them proportionally more intense compared to the continuum than lines observed in the more massive hot cores. Core #1, the most massive hot core of W43-MM1, shows a richer line spectrum than the other cores in our sample, in particular in N-bearing molecules and ethylene glycol lines. In core #2, the emission of O-bearing molecules, such as OCS, CH₃OCHO, and CH₃OH, does not peak at the dust continuum core centre; the blueshifted and redshifted emission corresponds to the outflow lobes, suggesting formation via sublimation of the ice mantles through shocks or UV irradiation on the walls of the cavity. These data establish a benchmark for the study of other massive star-formation regions and hot cores. 

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4. On the formation of complex organic molecules in the interstellar medium: untangling the chemical complexity of carbon monoxide–hydrocarbon containing ice analogues exposed to ionizing radiation via a combined infrared and reflectron time-of-flight analysis

   https://doi.org/10.1039/C9CP01793C  

   Abplanalp, Matthew J.; Kaiser, Ralf I. (August 2019, Physical Chemistry Chemical Physics)

   Recently, over 200 molecules have been detected in the interstellar medium (ISM), with about one third being complex organic molecules (COMs), molecules containing six or more atoms. Over the last few decades, astrophysical laboratory experiments have shown that several COMs are formed via interaction of ionizing radiation within ices deposited on interstellar dust particles at 10 K (H 2 O, CH 3 OH, CO, CO 2 , CH 4 , NH 3 ). However, there is still a lack of understanding of the chemical complexity that is available through individual ice constituents. The present research investigates experimentally the synthesis of carbon, hydrogen, and oxygen bearing COMs from interstellar ice analogues containing carbon monoxide (CO) and methane (CH 4 ), ethane (C 2 H 6 ), ethylene (C 2 H 4 ), or acetylene (C 2 H 2 ) exposed to ionizing radiation. Utilizing online and in situ techniques, such as infrared spectroscopy and tunable photoionization reflectron time-of-flight mass spectrometry (PI-ReTOF-MS), specific isomers produced could be characterized. A total of 12 chemically different groups were detected corresponding to C 2 H n O ( n = 2, 4, 6), C 3 H n O ( n = 2, 4, 6, 8), C 4 H n O ( n = 4, 6, 8, 10), C 5 H n O ( n = 4, 6, 8, 10), C 6 H n O ( n = 4, 6, 8, 10, 12, 14), C 2 H n O 2 ( n = 2, 4), C 3 H n O 2 ( n = 4, 6, 8), C 4 H n O 2 ( n = 4, 6, 8, 10), C 5 H n O 2 ( n = 6, 8), C 6 H n O 2 ( n = 8, 10, 12), C 4 H n O 3 ( n = 4, 6, 8), and C 5 H n O 3 ( n = 6, 8). More than half of these isomer specifically identified molecules have been identified in the ISM, and the remaining COMs detected here can be utilized to guide future astronomical observations. Of these isomers, three groups – alcohols, aldehydes, and molecules containing two of these functional groups – displayed varying degrees of unsaturation. Also, the detection of 1-propanol, 2-propanol, 1-butanal, and 2-methyl-propanal has significant implications as the propyl and isopropyl moieties (C 3 H 7 ), which have already been detected in the ISM via propyl cyanide and isopropyl cyanide, could be detected in our laboratory studies. General reaction mechanisms for their formation are also proposed, with distinct follow-up studies being imperative to elucidate the complexity of COMs synthesized in these ices. 

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5. A deep search for large complex organic species toward IRAS16293-2422 B at 3 mm with ALMA

   https://doi.org/10.1051/0004-6361/202347832  

   Nazari, P; Cheung, J_S Y; Asensio, J Ferrer; Murillo, N M; van_Dishoeck, E F; Jørgensen, J K; Bourke, T L; Chuang, K-J; Drozdovskaya, M N; Fedoseev, G; et al (June 2024, Astronomy & Astrophysics)

   Context.Complex organic molecules (COMs) have been detected ubiquitously in protostellar systems. However, at shorter wavelengths (~0.8 mm), it is generally more difficult to detect larger molecules than at longer wavelengths (~3 mm) because of the increase in millimeter dust opacity, line confusion, and unfavorable partition function. Aims.We aim to search for large molecules (more than eight atoms) in the Atacama Large Millimeter/submillimeter Array (ALMA) Band 3 spectrum of IRAS 16293-2422 B. In particular, the goal is to quantify the usability of ALMA Band 3 for molecular line surveys in comparison to similar studies at shorter wavelengths. Methods.We used deep ALMA Band 3 observations of IRAS 16293-2422 B to search for more than 70 molecules and identified as many lines as possible in the spectrum. The spectral settings were set to specifically target three-carbon species such as i- and n-propanol and glycerol, the next step after glycolaldehyde and ethylene glycol in the hydrogenation of CO. We then derived the column densities and excitation temperatures of the detected species and compared the ratios with respect to methanol between Band 3 (~3 mm) and Band 7 (~1 mm, Protostellar Interferometric Line Survey) observations of this source to examine the effect of the dust optical depth. Results.We identified lines of 31 molecules including many oxygen-bearing COMs such as CH₃OH, CH₂OHCHO, CH₃CH₂OH, and c-C₂H₄O and a few nitrogen- and sulfur-bearing ones such as HOCH₂CN and CH₃SH. The largest detected molecules are gGg-(CH₂OH)₂and CH₃COCH₃. We did not detect glycerol or i- and n-propanol, but we do provide upper limits for them which are in line with previous laboratory and observational studies. The line density in Band 3 is only ~2.5 times lower in frequency space than in Band 7. From the detected lines in Band 3 at a ≳ 6σ level, ~25–30% of them could not be identified indicating the need for more laboratory data of rotational spectra. We find similar column densities and column density ratios of COMs (within a factor ~2) between Band 3 and Band 7. Conclusions.The effect of the dust optical depth for IRAS 16293-2422 B at an off-source location on column densities and column density ratios is minimal. Moreover, for warm protostars, long wavelength spectra (~3 mm) are not only crowded and complex, but they also take significantly longer integration times than shorter wavelength observations (~0.8 mm) to reach the same sensitivity limit. The 3 mm search has not yet resulted in the detection of larger and more complex molecules in warm sources. A full deep ALMA Band 2–3 (i.e., ~3–4 mm wavelengths) survey is needed to assess whether low frequency data have the potential to reveal more complex molecules in warm sources. 

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