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  • Identifying molecular fluorophore impurities in the synthesis of low-oxygen-content, carbon nanodots derived from pyrene
Title: Identifying molecular fluorophore impurities in the synthesis of low-oxygen-content, carbon nanodots derived from pyrene
Carbon dots (C-dots) are a promising class of carbonaceous nanomaterials for bioimaging, catalysis, and optoelectronics. However, their applications are disrupted by recent reports that bright molecular fluorophores are co-produced in the synthesis of C-dots, in particular ones prepared through a bottom-up approach (carbon nanodots (CNDs)), commonly derived from citric acid precursors. The presence of highly emissive molecular fluorophore species obscures the true performance of CNDs and severely challenges the development of CNDs. Here we observe that the issue of molecular fluorophore impurity is still problematic for CNDs which are derived from a different type of precursor, polycylic aromatic hydrocarbons (PAHs). In this study, low-oxygen-content CNDs and small molecular fluorophores are co-produced through hydrothermal condensation of nitropyrene. Extensive and systematic characterization following column chromatographic separation and solvent-induced extraction reveals that molecular fluorophores and CNDs are clearly dissimilar in structure and optical properties. This work highlights that rigorous separation and purification steps need to be taken not only for hydrophilic CNDs but also for low-oxygen-content CNDs.  more » « less
Award ID(s):
1854554
PAR ID:
10430090
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ; ; ;
Date Published:
Journal Name:
New Journal of Chemistry
Volume:
46
Issue:
17
ISSN:
1144-0546
Page Range / eLocation ID:
8324 to 8333
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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