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1. Experimental test of the cooling rate effect on blocking temperatures in stepwise thermal demagnetization

   https://doi.org/10.1093/gji/ggaa514  

   Berndt, Thomas A ; Chang, Liao ; Paterson, Greig A ; Cao, Changqian ( November 2020 , Geophysical Journal International)

   null (Ed.)

   SUMMARY Upon cooling, most rocks acquire a thermoremanent magnetization (TRM); the cooling rate at which this happens not only affects palaeointensity estimates, but also their unblocking temperatures in stepwise thermal demagnetization experiments, which is important, for example, to estimate volcanic emplacement temperatures. Traditional single-domain (SD) theory of magnetic remanence relates relaxation times to blocking temperatures— the blocking temperature is the temperature at which the relaxation time becomes shorter than the experimental timescale—and therefore strictly only applies to remanence acquisition mechanisms at constant temperatures (i.e. viscous remanent magnetizations, VRMs). A theoretical framework to relate (constant) blocking temperatures to (time-varying) cooling rates exists, but this theory has very limited experimental verification—partly due to the difficulty of accurately knowing the cooling rates of geological materials. Here we present an experimental test of this ‘cooling rate effect on blocking temperatures’ through a series of demagnetization experiments of laboratory-induced TRMs with controlled cooling rates. The tested cooling rates span about 1 order of magnitude and are made possible through (1) extremely accurate demagnetization experiments using a low-temperature magnetic properties measurement system (MPMS) and (2) the use of a ‘1-step-only’ stepwise thermal demagnetization protocol where the relaxation process is measured over time. In this way the relaxation time corresponding to the blocking temperature is measured, which can be done to much higher accuracy than measuring the blocking temperature directly as done in traditional stepwise thermal demagnetization experiments. Our experiments confirm that the cooling rate relationship holds to high accuracy for ideal magnetic recorders, as shown for a synthetic weakly interacting SD magnetoferritin sample. A SD-dominated low-Ti titanomagnetite Tiva Canyon Tuff sample, however, showed that natural samples are unlikely to be sufficiently ‘ideal’ to meet the theoretical predictions to high accuracy—the experimental data agrees only approximately with the theoretical predictions, which may potentially affect blocking temperature estimates in stepwise thermal demagnetization experiments. Moreover, we find a strongly enhanced cooling rate effect on palaeointensities for even marginally non-ideal samples (up to 43 per cent increase in pTRM for a halving of the cooling rate). 

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2. Primary and Secondary Red Bed Magnetization Constrained by Fluvial Intraclasts

   https://doi.org/10.1029/2018JB017067  

   Swanson‐Hysell, Nicholas L. ; Fairchild, Luke M. ; Slotznick, Sarah P. ( May 2019 , Journal of Geophysical Research: Solid Earth)

   The magnetization of hematite‐bearing sedimentary rocks provides critical records of geomagnetic reversals and paleogeography. However, the timing of hematite remanent magnetization acquisition is typically difficult to constrain. While detrital hematite in sediment can lead to a primary depositional remanent magnetization, alteration of minerals through interaction with oxygen can lead to the postdepositional formation of hematite. In this study, we use exceptionally preserved fluvial sediments within the 1.1‐billion‐year‐old Freda Formation to gain insight into the timing of hematite remanence acquisition and its magnetic properties. This deposit contains siltstone intraclasts that were eroded from a coexisting lithofacies and redeposited within channel sandstone. Thermal demagnetization, petrography, and rock magnetic experiments on these clasts reveal two generations of hematite. One population of hematite demagnetized at the highest unblocking temperatures and records directions that rotated along with the clasts. This component is a primary detrital remanent magnetization. The other component is removed at lower unblocking temperatures and has a consistent direction throughout the intraclasts. This component is held by finer‐grained hematite that grew and acquired a chemical remanent magnetization following deposition resulting in a population that includes superparamagnetic nanoparticles in addition to remanence‐carrying grains. The data support the interpretation that magnetizations of hematite‐bearing sedimentary rocks held by >400‐nm grains that unblock close to the Néel temperature are more likely to record magnetization from the time of deposition. This primary magnetization can be successfully isolated from cooccurring authigenic hematite through high‐resolution thermal demagnetization.

    

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3. Understanding Nonideal Paleointensity Recording in Igneous Rocks: Insights From Aging Experiments on Lava Samples and the Causes and Consequences of “Fragile” Curvature in Arai Plots

   https://doi.org/10.1029/2020GC009423  

   Tauxe, L. ; Santos, C. N. ; Cych, B. ; Zhao, X. ; Roberts, A. P. ; Nagy, L. ; Williams, W. ( January 2021 , Geochemistry, Geophysics, Geosystems)

   The theory for recording of thermally blocked remanences predicts a quasilinear relationship between low fields like the Earth's in which rocks cool and acquire a magnetization. This serves as the foundation for estimating ancient magnetic field strengths. Addressing long‐standing questions concerning Earth's magnetic field requires a global paleointensity data set, but recovering the ancient field strength is complicated because the theory only pertains to uniformly magnetized particles. A key requirement of a paleointensity experiment is that a magnetization blocked at a given temperature should be unblocked by zero‐field reheating to the same temperature. However, failure of this requirement occurs frequently and the causes and consequences of failure are understood incompletely. Recent experiments demonstrate that the remanence in many samples typical of those used in paleointensity experiments is unstable, exhibiting an “aging” effect in which the (un)blocking temperature spectra can change over only a few years resulting in nonideal experimental behavior. While a fresh remanence may conform to the requirement of equality of blocking and unblocking temperatures, aged remanences may not. Blocking temperature spectra can be unstable (fragile), which precludes reproduction of the conditions under which the original magnetization was acquired. This limits our ability to acquire accurate and precise ancient magnetic field strength estimates because differences between known and estimated fields can be significant for individual specimens, with a low field bias. Fragility of unblocking temperature spectra may be related to grain sizes with lower energy barriers and may be detected by features observed in first‐order reversal curves.

    

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4. Absolute Paleointensity Experiments on Aged Thermoremanent Magnetization: Assessment of Reliability of the Tsunakawa‐Shaw and Other Methods With Implications for “Fragile” Curvature

   https://doi.org/10.1029/2022GC010391  

   Yamamoto, Y. ; Tauxe, L. ; Ahn, H. ; Santos, C. ( March 2022 , Geochemistry, Geophysics, Geosystems)

   Absolute paleointensity (API) of the geomagnetic field can be estimated from volcanic rocks by comparing the natural remanent magnetization (NRM) to a laboratory‐induced thermoremanent magnetization (Lab‐TRM). Plots of NRM unblocking versus Lab‐TRM blocking from API experiments often exhibit nonideal curvature, which can result in biased estimates. Previous work showed that curvature can increase with age; however, selection criteria designed to eliminate such behavior yielded accurate estimates for two‐year‐aged specimens (70.3 ± 3.8 μT;N = 96 specimens out of 120 experiments). API can also be estimated in coercivity space. Here, we use the Tsunakawa‐Shaw (TS) method applied to 20 specimens aged in the laboratory field of 70.0 μT for 4 years, after acquisition of zero‐age (fresh) Lab‐TRM in the same field. Selection criteria for the TS experiment also yielded accurate results (68.5 ± 4.5 μT;N = 17 specimens). In thermal API experiments, curvature is related to internal structure with more single domain‐like behavior having the least curvature. Here we show that the fraction of anhysteretic remanent magnetization demagnetized by low‐temperature treatment was larger for samples with larger thermal curvatures suggesting a magnetocrystalline anisotropy source. We also tested experimental remedies that have been proposed to improve the accuracy of paleointensity estimates. In particular, we test the efficacy of the multi‐specimen approach and a strategy pretreating specimens with low field alternating field demagnetization prior to the paleointensity experiment. Neither yielded accurate results.

    

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5. AF demagnetization and ARM acquisition at elevated temperatures in natural titanomagnetite bearing rocks

   https://doi.org/10.1093/gji/ggz269  

   Volk, Michael W ; Eitel, Michael ; Jackson, Mike ( June 2019 , Geophysical Journal International)

   SUMMARY Understanding the temporal changes of the Earth’s magnetic field intensity is one of the main goals of modern palaeomagnetism. For most palaeointensity methods to yield reliable results, the magnetic minerals must obey a set of rules. One of these rules is the additivity of partial thermal (TRM) or anhysteretic remanent magnetizations (ARM). Additivity was previously shown for partial TRM in single-domain particles and more generally for ARMs. Additivity between these two low-field remanences, however, has not been investigated, yet. This paper presents a series of rock magnetic experiments on natural low Ti titanomagnetites (Curie temperature between 534 °C and 561 °C) examining the effects of high temperatures on alternating field (AF) demagnetization and acquisition of an ARM. One of our sample sets comes from a borehole drilled through the impact melt sheet of the Manicouagan crater (Canada), the other from the Rocche Rosse lava flow on the island of Lipari (Italy). Hysteresis parameters indicate the magnetic carriers in the pseudo-single-domain range showing no evidence for oxidation. Thermal demagnetization at 300 °C and 500 °C before AF demagnetization shifts the coercivity spectra towards higher fields. AF demagnetization experiments at 500 °C show a significant (by a factor between 1.4 and >7.6) reduction in median destructive field and a shift towards lower coercivities. A linear relationship was found between the peak magnetic field required to demagnetize a fraction of a full TRM of a sample at a specific temperature and the one necessary to demagnetize the same fraction at room temperature after heating to that temperature. The comparison of full ARM and partial TRM at successively higher temperatures with a hybrid hTARM reveals that combined additivity between the two kinds of remanences is fulfilled. These results open the possibility to demagnetize highly coercive minerals, such as hematite and goethite, which is often not achievable at elevated temperatures. Furthermore, the additivity of TRM and ARM remanences may be used to develop novel hybrid TRM/ARM palaeointensity methods for samples, where heating is problematic (e.g. in meteorites). 

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