skip to main content


Title: Tree convolution for probability distributions with unbounded support
We develop the complex-analytic viewpoint on the tree convolutions studied by the second author and Weihua Liu in Jekel and Liu (2020), which generalize the free, boolean, monotone, and orthogonal convolutions. In particular, for each rooted subtree T of the N-regular tree (with vertices labeled by alternating strings), we define the convolution \boxplus_T (µ1, . . . , µN) for arbitrary probability measures µ1, . . . , µN on R using a certain fixed-point equation for the Cauchy transforms. The convolution operations respect the operad structure of the tree operad from Jekel and Liu (2020). We prove a general limit theorem for iterated T -free convolution similar to Bercovici and Pata’s results in the free case (Bercovici and Pata 1999), and we deduce limit theorems for measures in the domain of attraction of each of the classical stable laws.  more » « less
Award ID(s):
2002826
NSF-PAR ID:
10432681
Author(s) / Creator(s):
; ;
Date Published:
Journal Name:
Alea
Volume:
18
Issue:
2
ISSN:
1980-0436
Page Range / eLocation ID:
1585–1623
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Ever-increasing demands for energy, particularly being environmentally friendly have promoted the transition from fossil fuels to renewable energy.1Lithium-ion batteries (LIBs), arguably the most well-studied energy storage system, have dominated the energy market since their advent in the 1990s.2However, challenging issues regarding safety, supply of lithium, and high price of lithium resources limit the further advancement of LIBs for large-scale energy storage applications.3Therefore, attention is being concentrated on an alternative electrochemical energy storage device that features high safety, low cost, and long cycle life. Rechargeable aqueous zinc-ion batteries (ZIBs) is considered one of the most promising alternative energy storage systems due to the high theoretical energy and power densities where the multiple electrons (Zn2+) . In addition, aqueous ZIBs are safer due to non-flammable electrolyte (e.g., typically aqueous solution) and can be manufactured since they can be assembled in ambient air conditions.4As an essential component in aqueous Zn-based batteries, the Zn metal anode generally suffers from the growth of dendrites, which would affect battery performance in several ways. Second, the led by the loose structure of Zn dendrite may reduce the coulombic efficiency and shorten the battery lifespan.5

    Several approaches were suggested to improve the electrochemical stability of ZIBs, such as implementing an interfacial buffer layer that separates the active Zn from the bulk electrolyte.6However, the and thick thickness of the conventional Zn metal foils remain a critical challenge in this field, which may diminish the energy density of the battery drastically. According to a theretical calculation, the thickness of a Zn metal anode with an areal capacity of 1 mAh cm-2is about 1.7 μm. However, existing extrusion-based fabrication technologies are not capable of downscaling the thickness Zn metal foils below 20 μm.

    Herein, we demonstrate a thickness controllable coating approach to fabricate an ultrathin Zn metal anode as well as a thin dielectric oxide separator. First, a 1.7 μm Zn layer was uniformly thermally evaporated onto a Cu foil. Then, Al2O3, the separator was deposited through sputtering on the Zn layer to a thickness of 10 nm. The inert and high hardness Al2O3layer is expected to lower the polarization and restrain the growth of Zn dendrites. Atomic force microscopy was employed to evaluate the roughness of the surface of the deposited Zn and Al2O3/Zn anode structures. Long-term cycling stability was gauged under the symmetrical cells at 0.5 mA cm-2for 1 mAh cm-2. Then the fabricated Zn anode was paired with MnO2as a full cell for further electrochemical performance testing. To investigate the evolution of the interface between the Zn anode and the electrolyte, a home-developed in-situ optical observation battery cage was employed to record and compare the process of Zn deposition on the anodes of the Al2O3/Zn (demonstrated in this study) and the procured thick Zn anode. The surface morphology of the two Zn anodes after circulation was characterized and compared through scanning electron microscopy. The tunable ultrathin Zn metal anode with enhanced anode stability provides a pathway for future high-energy-density Zn-ion batteries.

    Obama, B., The irreversible momentum of clean energy.Science2017,355(6321), 126-129.

    Goodenough, J. B.; Park, K. S., The Li-ion rechargeable battery: a perspective.J Am Chem Soc2013,135(4), 1167-76.

    Li, C.; Xie, X.; Liang, S.; Zhou, J., Issues and Future Perspective on Zinc Metal Anode for Rechargeable Aqueous Zinc‐ion Batteries.Energy & Environmental Materials2020,3(2), 146-159.

    Jia, H.; Wang, Z.; Tawiah, B.; Wang, Y.; Chan, C.-Y.; Fei, B.; Pan, F., Recent advances in zinc anodes for high-performance aqueous Zn-ion batteries.Nano Energy2020,70.

    Yang, J.; Yin, B.; Sun, Y.; Pan, H.; Sun, W.; Jia, B.; Zhang, S.; Ma, T., Zinc Anode for Mild Aqueous Zinc-Ion Batteries: Challenges, Strategies, and Perspectives.Nanomicro Lett2022,14(1), 42.

    Yang, Q.; Li, Q.; Liu, Z.; Wang, D.; Guo, Y.; Li, X.; Tang, Y.; Li, H.; Dong, B.; Zhi, C., Dendrites in Zn-Based Batteries.Adv Mater2020,32(48), e2001854.

    Acknowledgment

    This work was partially supported by the U.S. National Science Foundation (NSF) Award No. ECCS-1931088. S.L. and H.W.S. acknowledge the support from the Improvement of Measurement Standards and Technology for Mechanical Metrology (Grant No. 22011044) by KRISS.

    Figure 1

     

    more » « less
  2. Deep convolutional neural networks have revolutionized many machine learning and computer vision tasks, however, some remaining key challenges limit their wider use. These challenges include improving the network's robustness to perturbations of the input image and the limited ``field of view'' of convolution operators. We introduce the IMEXnet that addresses these challenges by adapting semi-implicit methods for partial differential equations. Compared to similar explicit networks, such as residual networks, our network is more stable, which has recently shown to reduce the sensitivity to small changes in the input features and improve generalization. The addition of an implicit step connects all pixels in each channel of the image and therefore addresses the field of view problem while still being comparable to standard convolutions in terms of the number of parameters and computational complexity. We also present a new dataset for semantic segmentation and demonstrate the effectiveness of our architecture using the NYU Depth dataset. 
    more » « less
  3. null (Ed.)
    In this paper we continue our analysis of the interplay between the pairing and the non-Fermi liquid behavior in a metal for a set of quantum-critical models with an effective dynamical electron-electron interaction V(Ωm)∝1/|Ωm|γ (the γ model). We analyze both the original model and its extension, in which we introduce an extra parameter N to account for nonequal interactions in the particle-hole and particle-particle channel. In two previous papers [A. Abanov and A. V. Chubukov, Phys. Rev. B 102, 024524 (2020) and Y. Wu et al. Phys. Rev. B 102, 024525 (2020)] we considered the case 0<γ<1 and argued that (i) at T=0, there exists an infinite discrete set of topologically different gap functions Δn(ωm), all with the same spatial symmetry, and (ii) each Δn evolves with temperature and terminates at a particular Tp,n. In this paper we analyze how the system behavior changes between γ<1 and γ>1, both at T=0 and a finite T. The limit γ→1 is singular due to infrared divergence of ∫dωmV(Ωm), and the system behavior is highly sensitive to how this limit is taken. We show that for N=1, the divergencies in the gap equation cancel out, and Δn(ωm) gradually evolve through γ=1 both at T=0 and a finite T. For N≠1, divergent terms do not cancel, and a qualitatively new behavior emerges for γ>1. Namely, the form of Δn(ωm) changes qualitatively, and the spectrum of condensation energies Ec,n becomes continuous at T=0. We introduce different extension of the model, which is free from singularities for γ>1. 
    more » « less
  4. Abstract

    We study three convolutions of polynomials in the context of free probability theory. We prove that these convolutions can be written as the expected characteristic polynomials of sums and products of unitarily invariant random matrices. The symmetric additive and multiplicative convolutions were introduced by Walsh and Szegö in different contexts, and have been studied for a century. The asymmetric additive convolution, and the connection of all of them with random matrices, is new. By developing the analogy with free probability, we prove that these convolutions produce real rooted polynomials and provide strong bounds on the locations of the roots of these polynomials.

     
    more » « less
  5. We introduce a framework to study discrete-variable (DV) quantum systems based on qudits. It relies on notions of a mean state (MS), a minimal stabilizer-projection state (MSPS), and a new convolution. Some interesting consequences are: The MS is the closest MSPS to a given state with respect to the relative entropy; the MS is extremal with respect to the von Neumann entropy, demonstrating a “maximal entropy principle in DV systems.” We obtain a series of inequalities for quantum entropies and for Fisher information based on convolution, giving a “second law of thermodynamics for quantum convolutions.” We show that the convolution of two stabilizer states is a stabilizer state. We establish a central limit theorem, based on iterating the convolution of a zero-mean quantum state, and show this converges to its MS. The rate of convergence is characterized by the “magic gap,” which we define in terms of the support of the characteristic function of the state. We elaborate on two examples: the DV beam splitter and the DV amplifier.

     
    more » « less